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HomeMy WebLinkAbout2016 Jul 29 - Bennett Environmental Assoc. Inspection & Alpha Lab Reports : ., . BE�Tl�E'TT �Ni�IR�I�TMEN'�AL ASSO�IATES� Il�TC. LICENSED SITE PROFESSIONALS,ENVIRONMENTAL SCIENTISTS,GEOLOGISTS,ENGINEERS 1573 Main Street,P.O.Box 1743 (508)896-1706 Brewster,MA 02631 fag(508)896-5109 LETTER OF TRANSMITTAL TO: DATE: JOB NUMBER: Massachusetts Department of Environmental Protection �/29/16 BEA13-10579 � Attention: Title 5 Program �� 1 Winter Street-6th Floor Boston,MA 02108 REGARDING: Drinane Residence 12 Dove's Wing Road SHIPPING METHOD: South Yannouth,MA 02664 Regular Mail Pick Up ��,��� r -" �2 � ❑ ❑ �.���..���,� i ; Priority Mail ❑ Hand Deliver ❑ �, i ❑ ''"i i Express Mail ❑ Other , � Certified Mail � Green Card/RR � H EALTH D��T. i COPIES DATE DESCRIPTION 1 DEP Approved Inspection and O&M Form for Tide 5 UA Treatment and Disposal Systems(December 2015,June 2016) 1 Singulau Service Inspection Checklist(December 2015,June 2016) 1 12/22/15 Alpha Analytical Laboratory Report 1 6/16/16 Alpha Analytical Laboratory Report For review and comment: � For approval: � As requested: � For your use: 0 REMARKS: Please fmd enclosed the DEP Inspection and O&M Forms,Singulair Service Inspection Checklists,and laboratoiy analytical results for operation and maintenance conducted during the reporting period for the above referenced property. If you have any questions or require additional information,please contact us at your earliest convenience. Thank you. cc:Yarmouth Board of Health Lee Drinane,Property Owner Robin Cassidy-Norweco[via email] FROM: David Bennett WWTO#6243/Samantha Farrenkopf WWTO#13265/Joseph Smith WWTO#12529/Greg BrehmWWTO#16149 If enclosures aze not as noted,kindly notify us at once _ � ` Massachusetts Department of Environmental Protection Bureau of Resource Protection -Title 5 DEP Approved Inspection and O&M Form for Title 5 1/A Treatment and Disposal Systems A. Installation Important:When Lee Drinane filling out forms Owner on the computer, use only the tab 12 Dove's Wing Road key to move your Facility Street Address cursor-do not South Yarmouth 02664 use the return City Zip key. � Mailing address of owner, if different: � StreetAddress/PO Box: r�sn City State Zip (508) 398-3280 ext. Telephone Number B. Authorized Service Provider Bennett Environmental Associates, Inc. O&M Firm 1573 Main Street/PO Box 1743 Street Address Brewster MA 02631 City State Zip (508) 896- 1706 ext. 129 Telephone Number Samantha Farrenkopf 13265 Certified Operator Name Certification Number C. Facility/System Information Singulair 960 NR DEP ID Manufacturer ID Model Number 7/2/08 7/8/08 Installation Date Start of Operation Approval Type: ❑ General � Provisional ❑ Piloting ❑ Remedial Seasonal Residence—used less than 6 mo./year: ❑ Yes � No D. Operating Information 12/10/15 6/3/15 Inspection Date Previous Inspection Date 6"sludge, 1"scum Sludge Depth(to be checked yearly) Pumping Recommended ❑ Yes � No t5aiom.doc•rev.04-11-13 Page 1 of 3 . Massachusetts Department of Environmental Protection ' Bureau of Resource Protection - Title 5 DEP Approved Inspection and O&M F'orm for Title 5 I/A Treatment and Disposal Systems E. Field Testing Field Inspection: � Color: ❑ gray ❑ brown � clear ❑ turbid ❑ Other(specify): Odor: � musty ❑ earthy ❑ moldy ❑ offer�sive ❑ turbid Effluent Solids: � no ❑ some pH 7.0 SU p� 3.0 mg/L Turbidity 2.47 NTU 6 to 9 2 or greater 40 or less Should a Remedial or General Use system fail the Field Testing, effluent samples shall be collected per Standard Methods and analyzed for BOD and TSS. F. Sampling Information Samples Taken: ❑ Influent � Efftuent Commercial systems or systems with a design flow of 2000 gpd and greater, and General Use nitrogen reducing systems: gpd Parameters sampled: ❑ pH � BOD ❑ CBOD � TSS� TN � Other(list below) N itrate N itrite TKN Other 1 Other 2 Other 3 G. Inspection and Maintenance Description of any maintenance performed since previous inspection &during this inspection: Conduct an operation and maintenance event. Collect effluent samples for field testing and laboratory analysis. Notes and Comments: All mechanical components of the system are operating correctly. Effluent quality passed field testing parameters. Final dosing pump chamber was inspected and mechanical components are operating correctly. t5aiom.doc•rev.04-11-13 Page 2 of 3 ` Massachusetts Department ofi Environrr�ental Protection Bureau of Resource Protection -Title 5 DEP Approved Inspection and O&M Form for Title 5 I/A Treatment and Disposal Systems H. Certification I certify: 1 have inspected the sewage treatment and disposal system at the address above, have conducted the required Field Testing and/or sample collection in accordance with Standard Methods, have completed this report and the attached technology operation and maintenance checklist, and the information reported is true, accurate, and complete as of the time of the inspection. I am a Massachusett ified operator in accordance with 257 CMR 2.00. _ � � _ �I���lr `Operator Signature D ta e System owner must submit this report, technology O&M checklist, and any required sampling results to the local board of health as follows for each inspection pertormed: Remedial Use—by January 31 St of each year for the previous calendar year Piloting Use-within 45 days of inspection date Provisional Use—by March 31th of each year for the previous 12 months General Use—by September 30t''of each year for the previous 12 months Send to: Department of Environmental Protection Attention: Title 5 Program One Winter Street, 5th Floor Boston, MA 02108 t5aiom.doc•rev.04-11-13 Page 3 of 3 ' Massachusetts Department of Environmental Protection Bureau of Resource Protection -Title 5 DEP Approved Inspection and O&M Form for Title 5 I/A Treatment and Disposal Systems A. I nstallation Important:When Lee Drinane filling out forms Owner on the computer, use only the tab 12 Dove's Wing Road key to move your Facility Street Address cursor-do not South Yarmouth 02664 use the return C�ty Zip key. r� Mailing address of owner, if different: Street AddresslPO Box: terten City State Zip (508) 398-3280 ext. Telephone Number B. Authorized Service Provider Bennett Environmental Associates, Inc. O&M Firm 1573 Main Street/PO Box 1743 Street Address Brewster MA 02631 City State Zip (508)896- 1706 ext. 129 Telephone Number . Samantha Farrenkopf 13265 Certified Operator Name Certiflcation Number C. Facility/System Information Singulair 960 NR DEP ID Manufacturer ID Model Number 7/2/08 7/8/08 Installation Date Start of Operation Approval Type: ❑ General � Provisional ❑ Piloting ❑ Remedial Seasonal Residence—used less than 6 mo./year: ❑ Yes � No D. Operating Information 6/10/16 12/10/15 Inspection Date Previous Inspection Date Sludge Depth(to be checked yearly) Pumping Recommended ❑ Yes � No t5aiom.doc•rev.04-11-13 Page 1 of 3 � Massachusetts Department of Environmental Protection � Bureau of Resource Pro#ection - Title 5 DEP Approved Inspection and O&iVl Forrri for Title 5 I/A Treatment and Disposal Systems E. I�ield T`esting Field Inspection: Color: ❑ gray ❑ brown � clear ❑turbid ❑ Other(specify): Odor: � musty ❑ earthy ❑ moldy ❑ offensive ❑ turbid Effluent Solids: � no ❑ some pH 6.0 SU p� 5.0 mg/L Turbidity 0.56 NTU 6 to 9 2 or greater 40 or less Should a Remedial or General Use system fail the Field Testing, effluent samples shall be collected per Standard Methods and analyzed for BOD and TSS. F. Sampling Information Samples Taken: ❑ Influent � Effluent Commercial systems or systems with a design flow of 2000 gpd and greater, and General Use nitrogen reducing systems: gpd Parameters sampled: ❑ pH � BOD ❑ CBOD � TSS ❑TN� Other(list below) Nitrate Nitrite TKN Other 1 Other 2 Other 3 G. Inspection and Maintenance Description of any maintenance performed since previous inspection &during this inspection: Conduct an operation and maintenance event. Collect effluent samples for field testing and laboratory analysis. Notes and Comments: All mechanical components of the system are operating correctly. Effluent quality passed field testing parameters. t5aiom.doc•rev.04-11-13 Page 2 of 3 c Massachusetts Department of Environmental Protection Bureau of Resource Protection -Title 5 DEP Approvec! Inspection and O&M Form for Title 5 I/A Treatment and Disposal Systems H. Certification I certify: I have inspected the sewage treatment and disposal system at the address above, have conducted the required Field Testing and/or sample collection in accordance with Standard Methods, have completed this report and the attached technology operation and maintenance checklist, and the information reported is true, accurate, and complete as of the time of the inspection. I am a Massachusetts ce � � d operator in accordance with 257 CMR 2.00. �Z�tlt� Opera or Signature Date System owner must submit this report, technology O&M checklist, and any required sampling results to the local board of health as follows for each inspection performed: Remedial Use—by January 31�of each year for the previous calendar year Piloting Use-within 45 days of inspection date Provisional Use—by March 31'h of each year for the previous 12 months General Use—by September 30th of each year for the previous 12 months Send to: Department of Environmental Protection Attention: Title 5 Program One Winter Street, 5th Floor Boston, MA 02108 t5aiom.doc•rev.04-11-13 Page 3 of 3 : SIN��LT�,E��t. 9b� I�1����`I`�+�1-L�I'�I� T��+ ATI�I�T� SYS�'El� ��RVICE INSPECT:I4N CHECKLIST 5 Address: �2. �1�5 �--'�1^� �� Owner: �Y'�1n�'�r� Operatar.�'t-' �Vn��-'�,�• � "j���� L�v�z.. Date: �2��1`�� �� \�"� ��r '� � This checklist summarizes the service procsdures#o be performed during aroutine Singulair 960 NR inspection Rsfez-to the Singuiair Manuat for a detailed expianation of each service procedure and an O&M�roubleshooting guide. CONTROL C�+NTER SERVICE NOTFS/COMII�ENTS �hecic operation o£cflntrol center �� �titr• �f�.•w"' ��,,•f'C, . V�^"''� ) OAdjusttim.eclockwhenrequired t,� -��, ., ��-.\ �u�`� ���.�c>\ L.�-�,r"�. �Check operation of recirculation control panel c .r C_.• W'^=� .n� NR EFFLUEI�IT RECIR�ULATIOI�T SYSTEM Check operation af recircutation pump ���.�C.. -��}v�.,� :� Ct��w'� ����"L• C1 Iiaspect recircula#io:n well&fittings �,Test Operation C7 S et recircula.tion rate rate @ min/hr RAT4R SERVICE Check aerator operation ���1'��CW' w�S C.�f��Z. �-���- C�Check aerator power cansumption {�v�. 'b�-�*-.�`�c7 ��-J'v�st-c�- Check aerator air delivery 1� Clean s#ainless steel aspirator shaft j � ���-�'.�a.r�--�m �, 5����'" �Clean aspirator tip -� �^ t•• SLv^^ �Clean fresh air vent uz concrete cover ��,,,,. �;� ��,,,,�,.�,.. C]�nspect aeration chamber contents � ^ �,`` ��w�,. CLA.RiFICATION CHAMBER SERVICE ` Itemave the Bio-Kinetaa sysbein ��.Q " ��v�-��v ��� � ���=�,� 0 Scrape the clarif'ication charnber r��-.��¢e. �Inspect the Bio-Static sludge reiurn �Inspect oixtl�c�upling �Install a cIean Bio-Kinetic system � �, `,��k:� ..�,. �\� �(' v.r. �.�-- G�F�1 Blue Cxystal feed tube(if installed) �FiIl Biv Neutralizer feed tube{if installed} GENERAL SERVICB � Inspect effiuentpump chamber '� �`�+�.(� G�.�.r-.�rj,�.C' �u S,�..5 L�'� �`'� Inspect effluent qualit}' C.,,}��l'-a-t..�,v� - �Inspect outiet line Q Inspe�t ground water relief point(if install.ed) �ti^•� 5 a� � v SS�`l �Inspect effluent disposal system f. �'-M .�� :`�5 C,�,r'w�.��. �Complete owner service record ❑C�mplete health deparhnent nai'af�ication � ' � �.,v �4��tr:. U,�,t�y �Complete dislribu#or service record �..r,r.t, U ❑Mait health deparfinent notification g� ��'� �� �,�� �`� tic� �.,,r�-`Z,,��1 c� �` �� ?`-^��� °�� Si und Envirorimentat Services Inc. F��'��` i {�� FL IU D THiNKFIVG.CLEAR SOLUTIOI3sh� l ��� � � � •�]G j ,.''� �� �G�-� V �`�`7j�' [� 1'� �vw.sie�nund�roun.com.�J�J�,�J,I�V� L�V c�o•n�� ����-� i „ _i� � �`�t� ����, i ����� i I s ►�.�l�t��� ��� i�F� ��i���.�'i����� ��.�,E�.�'���� ►.��►���� �E]E�.VICE It'�SPE�TI�N CI--�+CKLI�T Address: ��I�'�'�_, �� ��t�-�L�`��wner. ��`j.�"��t.� . Operator. "'�-Yi �_�� 1t� �!�� � Date: �r�11�C3��'� ����� ` ' t / This checklist sum�►arizes the service procedwres to be performed dzuYng a routine Singulair 950 NR insgection.Refex to the Singuiair Manual for a�etailed explanation of each service procedure and an O&M tronbleshooting guide. CONTROL CENTER SERVICE NUTESICOIIIAIENTS �Check operationaf control center `�j'�� ;;�L� ��l"Cr� Gw-�,`�`��.�. �+gry �Adjust time clock w13en required �_c�, ����v�.C.'�-c.`�,. t��z'.�i�,.�'`� . i Check ogeration of xecirculatzon conirol panel ; I EFFLUENT RECIRCi7LATI01�SYSTEM I Check operation ofxecirc�Iation pump ;`�.��i l�f- • �1��N�..� �t ' vw.�. C�'Inspect recirculation well&fittings _�,�f,�.���� �Test Operation C7 Set recirculatiort rate rate @ min/hr RATOR SERVICE Check aeratar aperation � Check aerator power consumption ���C�'a,� c'�� t . � rs�" +��a2�-�'e� Check aerator aix deiivery +�,�� t'��,t�►S-��et-� Ciean seainless stee]aspirator shaft Clean aspirator tip Clean fresh air veut in concxeie cover D Inspect aeration chamber contents C AltIFICATTON CHAMBER SERVICE Remove the Bio-Kineti.c system � ;� ,� �E� ��i�,�r`�'��-- .�V��' �crape the clarification chamber �L��—i,r�-c��p��c�l2-� �[�.�-�-t��G� . �sgect the 8io-Static slutlge return � �ect outlet coupling � U � :��` �`Install a clean Bio-Kinetic system l�Fi11 Blue Ciystal feed tube{if installed) C�Fi31 Bio-Neulralizer feed fube(if inst�lled) '�� ��G N�R.A.L SERVICE � - ... ;�;,:.,_: ...:�.,�`3 Inspect ef�-Iuen#pump chamber �' � �}-�_ ('i 19- ' ; • � Inspect efIluent quality r - ���"'- �.. . ` ,; . ❑Inspect outlet line -�`� -' �- � ; �Inspect ground water reli ef point(if ins#alled} . �,�c � O Inspect effl�tent disposal system i�r t• . �- , . �0 Complete owner service record r j r � ��. ��E�� L�Complete health department notification ��',��.1� � �. �(i.��c�`'� �Y) �3�r�i'��''°� �Ct Complete distributor service record '(• � ; ��c--�����. CI Mail health department noti�catzon p�pq :� �. � �� .` �js� Siegmund Environmental5ervices,Inc. ,,. �}- PT,[JID TFIWI�iVG.CLEAR SOLt3TION8. .. ��'� ��� 1��" � unvwsie�mundtrroup.com �'J � ��r ��� , 1 ; Seriai No:12221513:23 ��� �. �� ~ � �'f� ����„_ �A�1,�.�..T 1 C i4 L ANALYTICAL REPORT Lab Number: L1532813 Client: Bennett Environmental Associates 1573 Main Street Brewster, MA 02631 ATfN: David Bennett Phone: (508)896-1706 Projeat Name: DRINANE RESIDENCE Project Number: BEA13-10579. Report Date: 12/22/15 The original project report/data package is heid by Alpha Analytical.This reportldata package is paginated and should be reproduced only in its entirety.Alpha Analytical holds no responsibility for results and/or data that are not consistent with the original. Certifications&Approvals: MA(M-MA086),NY (11148),CT(PH-0574),NH(2003),NJ NELAP(MA935),RI(LA000065),ME(MA00086), PA(68-03671),VA(460195),MD(348),IL(200077),NC(666)�TX(T104704476),DOD(L2217),USDA(Permit #P-330-11-00240). Eight Walkup Drive,Westborough, MA 01581-1019 508-898-9220 (Fax)508-898-9193 800-624-9220-www.aiphalab.com ��. Page 1 of 16 �' � ��� C��i ; d w � '� N M ❑ C'rj � Lf) 4J � r ' � � ' M N 'd � N N � � N � N � N N -� r � � O Z I (6 L dj N . d N � � � � 0 � � � � � a � � Z O ++•— � -Q Q- �� `o J � � � � O N � V 0 � Q � 2 F— � O � � c � d o = a'� _ c�o o O tA J (n � x W �L I--� � � W U Z W � � W � � � W o I— � Q M 0 W Z Q ,F, � � W d LJi ❑ 0� — LL U W i: . G1 d .Q � � � 7 � Z Z O � � c� �C1 V � r O G� 41 d .O .O S Q M Cy � a a a,� � °' co Q � � �- , Serial_No:12221513:23 Project Name: DRINANE RESIDENCE Lab Number: L1532813 Project Number: BEA13-10579 Report Date: 12/22/15 Case Narrative The samptes were received in accordance with the Chain of Gustody and no significant deviations were encountered during the preparation or analysis unless otherwise noted.Sample Receipt,Container Information,and the Chain of Custody are located at the back of the report. Results contained within this report relate only to the samples submitted under this Aipha Lab Number and meet all of the requirements of NELAC,for ail NELAC accredited parameters.The data presented in this report is organized by parameter(i.e.VOC,SVOC,etc.).Sample specific Quality Control data(i.e.Surrogate Spike Recovery)is reported at the end of the target analyte list for each individual sample, followed by the Laboratory Batch Quality Control at the end of each parameter.Tentatively Identified Compounds(TICs),if requested,are reported for compounds identified to be present and are not par#of the method/program Target Compound List,even if only a subset of the TCL are being reported.If a sample was re-analyzed or re-extracted due to a required qualiry control corrective action and if both sets of data are reported,the Laboratory ID of the re-analysis or re-extraction is designated with an"R"or"RE",respectively.When multiple Batch Quality Control elements are reported(e.g.more than one LCS),the associated samples for each element are noted in the grey shaded header line of each data table.Any Laboratory Batch,Sample Specific%recovery or RPD value that is outside the listed Acceptance Criteria is bolded in the report.All specific QC information is also incorporated in the Data Usability format of our Data Merger tool where it . can be reviewed along with any associated usability implications.Soil/sediments,solids and tissues are reported on a dry weight basis unless otherwise noted.Definitions of ail data qualifiers and acronyms used in this report are provided in the Glossary located at the back of the report. In reference to questions H(CAM)or 4(RCP)when"NO"is checked,the performance criteria for CAM and RCP methods ailow for some quality control failures to occur and still be within method compliance. In these instances the specific failure is not narrated but noted in the associated QC table.The information is also incorporated in the Data Usability format of our Data Merger tooi where it can be reviewed along with any associated usability implications. Please see the associated ADEx data file for a comparison of laboratory reporting limits that were achieved with the regulatory Numerical Standards requested on the Chain of Custody. HOLD POLICY For samples submitted on hold,Alpha's policy is to hold samples(with the exception of Air canisters)free of charge for 21 calendar days from the date the project is completed.After 21 calendar days,we will dispose of all samples submitted including those put on hoid unless you have contacted your Client Service Representative and made arrangements for Alpha to continue to hold the samples.Air canisters wili be disposed after 3 business days from the date the project is compieted. Please contact Client Services at 800-624-9220 with any questions. � Page 3 of 96 =�'�a, �.,, Serial No:12221513:23 Project Name: DRINANE RESIDENCE Lab Number: L1532813 Projeet Number: BEA13-10579 Rep�rt Date: 12/2_2/15 Case Narrative(continued) BOD, 5 day The WG849287-2 LCS recovery(76°/a), associated with L1532813-01, is outside the acceptance criteria. Due to the expiration of the method required holding time, no further action was taken. I,the undersigned, attest under the pains and penalties of perjury that,to the best of my knowledge and belief and based upon my personal inquiry of those responsible for providing the information contained in this analytical report,such information is accurate and complete. This certificate of analysis is not complete unless this page accompanies any and atl pages of this report. �,.,�.���1� Lu ra L Tro1r Authorized Signature• Title: Technical Director/Representative Date: 12/22/15 Page 4 of 16 ���` ; Serial No:12221513:23 INORGANICS & MISCELLANEOUS ��� ���� Paqe5of16 Serial No:12221513:23 - Project Name: DRINANE RESIDENCE Lab Number: L1532813 Project Number: BEA13-10579 Report Date: 12/22/15 SAMPLE RESULTS Lab ID: L1532813-01 Date Collected: 12/10/15 12:25 Client ID: EFF�uENT Date Received: 12/11/45 Sal'ilplB LOCatlOtl: SOUTH YARMOUTH,Ma Field Prep: Not Specified Matrix: Water Dilution Date Date Analytical Parameter Result Qualifier Units RL MDL Factor Prepared Analyzed Method Analyst General Chemistry-Westborough Lab Solids,Total Suspended ND mg/I 5.0 NA 1 - 12/14/15 23:55 30,2540D RP Nitrogen,Nitrite ND mg/I 0.050 - 1 - 12111/1522:54 44,353.2 MR ---._..._._-------...-- -----._..------------------- - ...._..--------..-------------- _- ------ _-------- --------------------- -----._...---------.....------ Nitrogen,Nitrate 3.2 mg/I 0.10 - 1 - 12/11/1523:16 44,353.2 MR Nitrogen,Total Kjetdahl 1.61 mg/I 0.300 - 1 12/14/15 18:45 12/15/15 00:57 30,4500N-C AT BOD,5 day 4.2 mg/I 2.0 NA 1 12/12l15 19�15 12/17/15 23:30 30,52108 RP __�.s Page 6 of 16 Serial No:12221513:23 Project Name: DRINANE RESIDENCE Lab Number: L1532813 Project Number: BEA13-10579 Report Date: 12/22/15 Method Blank Analysis Batch Quality Control Dilution Date Date Analytical Parameter Result Qualifier Units RL MDL Factor Prepared Analyzed Method Analyst General Chemistry-Westborough Lab for sample(s): 01 Batch: WG849135-1 Nitrogen,Nitrate ND mgfl 0.10 — 1 - 12l11/1522:35 44,3532 MR General Chemi"stry-Westborough Lab for sample(s): 01 Batch: WG849136-1' Nitrogen,Nitrite ND mg/I 0.05� — 1 - 12/11/15 22:38 44,3532 MR General Chemistry-Westborough Lab for sample{s): 01 Batch:-WG849287 9' BOD,5 day ND mgA 2.0 NA 1 12/12/15 19:15 12/17/15 23:30 30,5210B RP General Chemistry-Westborough Lab for sample(s): 01 Batch; WG849616-1 Nitrogen,Totai Kjeldahl ND mg/I 0.300 — 1 12/�4/15 18:45 12l15/15 00:35 30,4500N-C AT General Chemistry-Westborough Lab for sample(s): 01 Batch: WG849672-� Solids,Total Suspended ND mgA 5.0 NA 1 - 12/14/15 23:55 30,2540D RP ��L�t�A Page 7 of 16 i i � � ! � � � � .. . . . . . � i N i, i r i �o N i N � � � � '� � : . . . � � �ts1 N - � � _ N � � � r M N -� N � co�l ' � ��'� O N i z� J � � � ; a , � � , j � � i � � � � 0 , ' � � � � Z p ! 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J � � � � � � .� Q R :�:. ! ,`r i ,DO�.� � �L(�': � �. ! �,~�� (( �' '.� - M i M i M � C� � I � � � � T E T� T�� � r � � � � � J : � N (�j '� ' ( � � � dj , � m- � : � � n_ ; �. � a ci N � m i m � m : m � � I � ; � � .� _ -a � � � � � � Q0 0 = , , : � � � a v I �,r' � � �` ' � � Y »= �u.' � ' M � � � Q.� � � � � , rn- rn K v U' C� � :L� >C� . C� •L ++ � � :� :. .{ > �.�� . l9 am � o ' o ' o 0 � cn o c"�i °�' � � ; o `�' o � � � N ' c�0 N ia � m , m � m m � �U' j -� � � � I C : N � C O ^ � O V f O �n p � � v ' N j N � N � N � � N I V �� t ..� f ���. �.: .. � �.�� ( .�� i ��..� � �:. .. G! N v � � N o � m cn � -a I :a � .a a W � �a a� � m a� z a � i �' � � � w o i o �o` o � N ` � N t� � °� Q �, l Q � � Q o Q o : w � > Q- � � � � � M I � o � z . � z W p Z� J � � J , J,. z � L�� � ..0 .�- L � Q � i ..:� L�.. ��. .. . Z � p � O p' p Q �L I ..V L�. L... � m .� j ,:��. ' �.... � ��._ �.�. f ...y.:.. ��' y. ' . . � �.. 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J - -� - -� - -� - -� - •� 'o� o� a�' a� rn. � � � � � � � � � � � � a Q Q Q Q a�_ f�6 (�6 c�0 6 N O [n : fn (� tn ln (� �''., G1 Q U � C.�'J ' � C�'1 : � O Q� �+ � M M M M N � � � rn : �p � I� � ',, �p ❑ CV � l0 ++ M ri c0 0 00 � Z f� �n V 7 V '� � � � � � � � � d' � �� � � � � � � � � � ' .� m � � � o � � J � � c�i � � �. �-. .�-. m m m ca co d m � rn m m m � C� C� C� C� C� � � � � � � I � � M � o r '� � Z � c� > � fl � � � C►. .. :, .. .. :. R y y `v N y Z � N N N N Q O. Q Q Q � ! � � � � W � (A U�j N tq W N a�i N N a�i z m ic m , a m , W .o .o .o _O .Q � w � Q Q Q ; Q Q W O J J J , J J z � t L .0 ' t .� Q M � � � � � z r 7 3 3 � 7 O O O O O � W � m � .n � � .n � � � N N i: � > > > � v � L d � � I ' 1 1 �1. f6 �.1 C �', L L N Q Z Z N � , � � ���. .� � Y N � �..� •� � , •� _ •� •� � •� � cfl � � �' "� ° m z ! m Z m ,, m � a� m ; �- 0 O O .«: U u�i U u�i V � ; U a�i V F' ; � a a � � o': � o � o '' � � � a � a� L m z ' m z m m m z a��i �' a � ,., ,.. ,., ... ... , Seriai No:12221513:23 Project Name: DRINANE RESIDENCE Lab Number: L1532813 Project Number: BEA13-10579 Report Date: 12/22/15 Sample Receipt and Container Information Were project specific reporting limits specified? YES Cooler Information Custody Seal Cooler A Absent Container Information Temp � Container ID Container Type Cooler pH deg C Pres Seal Analysis(*) L1532813-01A Plastic 250m1 H2SO4 preserved A <2 3.7 Y Absent TKN-4500(28) L1532813-01 B Plastic 950m1 unpreserved A 7 3.7 Y Absent NO2-353(2),BOD-5210(2),NO3- 353(2) L1532813-01C Plastic 950mi unpreserved A 7 3.7 Y Absent TSS-2540(7) *Values in parentheses indicate holding time in days � � , Page 11 of 16 =����'MT„"` Serial No:12221513:23 . Project Name: DRINANE RESIDENCE Lab Number: L1532813 Project IVumber: BEA13-10579 Report Date: 12/22/15 GLOSSAI2Y Acronyms EDL -Estimated Detecfion L'unit:This value represents the level to which target analyte concentrations aze reported as estimated values;when those targebanalyte concentraflons aze quantified below the reporting limit(RL).The EDL includes any adjushnents from dilufions,concenhations or moisture content,where applicable.The use of EDLs is specific to the analysis of PAHs using Solid-Phase Microextraction(SPME). EPA. -Environmental Protection Agency. LCS -Laboratory Control Sample:A sample matrix,free from the analytes of interest,spiked with verified lmown awounts of analytes or a material containing known and verified amounts of anal}rtes. LCSD -Laboratory Control Sample Duplicate:Refer to LCS. LFB. -Laboratory Fortified Blank:A sample matrix,free from the analytes of interest,spiked with verified known amounts of analytes or a material containina known and verified amounts of analytes. MDL -Method Detection Limit:This value represents the level to which target analyte concent�ations aze reported as estimated values, when those target analyte concentrations are quantified below the reporting limit(RL).The MDL includes any adjustments from dilutions,concentrations or moisture content,where applicable. MS -Matiiac Spike Sample:A sample prepazed by adding a known mass of target analyte to a specified aznount of matrix sample for which an independent estimate of target analyte concentration is available. MSD -Matrix Spike Sample Duplicate:Refer to MS. NA -Not Applicable. NC -Not Calculated: Term is utilized when one or more of the results utilized in the calculation are non-detect at the pazameter's reporting unit. NI -Not Ignitable. NP -Non-Plastic:Term is utilized for tbe analysis of Atterberg Limits in soil. RL -Reporting Limit: The value at which an instrument can accurately measure an analyte at a spe�ific concentration.The RL includes any adjustments from dilurions,concentrations or moisture content,where applicable. RPD -Relative Percent Difference: The results from matriac and/or matrix spike duplicates are prunarIly designed to assess the precision of analytical results in a given matrix and aze expressed as relative percent difference(RPD). Values which are less than five times Ute reporking limit for any individual pazameter aze evaluated by utilizing the absolute difference between the values; although the RPD value will be provided in the report. SRM -Standard Reference Material:A reference sample of a]mown or certified value that is of the same or similar matrix as the associated field samples. S'IZP -Semi-dynamic Tank Leaching Procedure per EPA Method 1315. TTC -Tentatively Idenrified Compound:A compound that has been identified.to be present and is not part of the target compound list (TCL)for the method and/or program.All TICs are qualitatively idenfified and reported as estimated concentrations. Foofnotes 1 -The reference for ttus aaalyte should be considered modified since this analyte is absent from the tazget analyte list of the original method Terms Total:With respect to Organic analyses,a"Total'result is defined as the summation of results for individual isomers or Aroclors.If a'Total' result is requested,the results of its individual components will also be reported.Tlus is applicable to'Total'results for methods 8260,8081 and 8082. Analytical Method:Bo.th the document from which the method originates and the analytical reference method.(Example:EPA 8260B is shown as 1,8260B.)The codes for the reference method documents are provided in the References secdon of the Addendum. Data Qualifiers A -Spectra identified as"Aldol Condensafion Product". B -The analyte was detected above the reporting limit in the associated method blank.Flaa only applies to associated field samples that have de.tectable concenh�arions of the analyte at less than ten times(10�c)the concentration found in the blank.For MCP-related projects,flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times(lOx) the concentration found in the blank.For DOD-related projects,fla�only applies to associated field samples that have detectable concentrations of the analyte at less than ten times(l Ox)the concentration found in the blank AND the analyte was detected above one-hatf the reporting limit(or above the reporting limit for common lab contaminants)in the associated method blank.For NJ- Air-related projects,flag only applies to associated field samples that have detectable concentrations of the analyte above the reporting limit.For NJ-related projects(excluding Air),flag only applies to associated field samples that have detectable concentrations of the analyte,wluch was detected above the reporting limit in the associated method blank or above five times the reporting limit for common lab contaminants(Phthalates,Acetone,Methylene Chloride,2-Butanone). Report Format: Data Usability Report �h i' a�` Page 12 of 16 � • Serial No:12221513:23 Project Name: DRINANE RESIDENCE Lab Number: L1532813 Project Number: BEA13-10579 Report Date: 12/22/15 Data Qualifiers C -Co-elution:The target analyte co-elutes with a known lab standazd(i.e.surrogate,intemal standazds,etc.)for co-extracted analyses. D -Concentration of analyte was quantified from diluted analysis.Flag only applies to field samples that have detectable concentrations of the analyte. E -Concenfration of analyte exceeds the range of the calibration curve and/or lineaz range of the instrument. G -The concentration may be biased high due to matrix interferences(i.e,co-elution)with non-target compound(s).The result should be considered estimated. H -The analysis of pH was performed beyond the regulatory-required holding time of 15 xninutes from the time of satnple collection. I -The lower value for the tv✓o columns has been reported due to obvious interference. M -Reporting Limit(RL)exceeds the MCP CAM Reporting Limit for tlus analyte. NJ -Presumptive evidence of compound.This represents an estimated concentration for Tentatively Identified Compounds{'I'ICs),where the identification is based on a mass spectral library search. P -The RPD between tlie results for the iwo columns exceeds the method-specified criteria. Q -The quality control sample exceeds the associated acceptance criteria.For DODxelated projects,LCS and/or Continuing Calibration Standaz•d eacceedences are also qualified on all associated sample results. Note:Tlus flag is not applicable for matruc spike recoveries when the sample concentration is greater than 4x the spike added or for batch duplicate RPD when the sample concentrations are less than Sx the RL.(Metals only.) R -Analytical results are from sample re-analysis. RE -Analytical results are from sample re-e�traction. S -Analytical results are from modified screenina analysis. J -Estimated value.Tlus represents an estimated concentration for Tentafively Identified Compounds(TICs). ND -Not detected at the reporting limit(RL)for the sample. Report Format: Data Usability Report � e..,�_. IiA Pana 1�nf 1 R Serial No:12221513:23 - Project Name: DRINANE RESIDENCE Lab Number: L1532813 Projecf Number: BEA13-10579 Report Date: 12/22/15 REFERENCES _ 30 Standard Methods for the Examination of Water and Wastewater.APHA-AWWA- WPCF. 18th Edition. 1992 44 Methods for the Determination of Inorganic Substances in Environmental Samples, EPA/600/R-93/100,August 1993. LIMITATION OF LIABILITIES Alpha Analytical performs services with reasonable care and diGgence normal to the analytical testirig laboratory industry. In the event of an error,the sole and exclusive responsibiliry of Alpha Analytical shall be to re-perForm the work at it's own expense. In no event shall Alpha Analytical be held liable for any incidental, cansequential or special damages, including but not limited to, damages in any way connected with the use of, interpretation of, information or analysis provided by Alpha Analytical. We strongly urge our clients to comply with EPA protocol regarding sample volume, preservation, cooling, containers, sampling procedures, holding time and splitting of samples in the field. ,��a Page 14 of 16 • Serial No:12221513:23 Alpha Analytical, Inc. ID No.:17873 Facility: Company-wide Revision 5 Department:Quality Assurance Published Date: 1 2/9/201 5 3:49:20 PM Title: Certificate/Approval Program Summarv Paqe 1 of 1 Certification Information The following analytes are not included in our Primary NEL.AP Scope of Accreditation: Westborough Facility EPA 524.2: 1,2-Dibromo-3-chloropropane, 1,2-Dibromoethane, m/p-xylene, o-xylene EPA 624: 2-Butanone(MEK), 1,4-Dioxane,tert-Amylmethyl Ether, tert-Butyl Alcohol, m/p-xylene, o-xylene EPA 625: Aniline, Benzoic Acid, Benzyl Alcohol, 4-Chloroaniline, 3-Methylphenol,4-Methylphenol. EPA 1010A: NPW: Ignitability EPA 6010C: NPW:Strontium; SCM: Strontium EPA 8151A: NPW:2,4-DB, Dicamba, Dichloroprop, MCPA, MCPP; SCM: 2,4-DB, Dichloroprop, MCPA, MCPP EPA 8260C: NPW: 1,2,4,5-Tetramethylbenzene;4-Ethyltoluene,Azobenzene, Isopropanol; SCM: lodomethane(methyl iodide), Methyl methacrylate(soil); 1,2,4,5-Tetramethylbenzene;4-Ethyltoluene. EPA 8270D: NPW: Pentachloronitrobenzene, 1-Methylnaphthalene, Dimethylnaphthalene,1,4-Diphenylhydrazine; SCM: Pentachloronitrobenzene, 1-Methylnaphthalene, Dimethylnaphthatene,1,4-Diphenylhydrazine. EPA 9010: NPW: Amenable Cyanide Distillation,Total Cyanide Distillation EPA 9038: NPW: Sulfate EPA 9050A: NPW:Specific Conductance EPA 9056: NPW: Chloride, Nitrate, Sulfate EPA 9065: NPW: Phenols EPA 9251: NPW: Chloride SM3500: NPW: Ferrous Iron SM4500: NPW: Amenable Cyanide, Dissolved Oxygen; SCM:Tbtat Phosphorus, TKN, NO2, NO3. SM5310C: DW: Dissolved Organic Carbon Mansfield Facility EPA 8270D: NPW: Biphenyl;SCM: Biphenyl EPA 2540D: TSS EPATO-15: Halothane,2,4,4-Trimethyl-2-pentene,2,4,4-Trimethyl-1-pentene,Thiophene,2-Methylthiophene, 3-Methylthiophene, 2-Ethylthiophene, 1,2,3-Trimethylbenzene, Indan, Indene, 1,2,4,5-Te�ramethylbenzene, Benzothiophene, 1-Methylnaphthalene. The following analytes are included in our Massachusetts DEP Scope of Accreditation,Westborough Facility: Drinking Water EPA 200.8: Sb,As,Ba,Be,Cd,Cr,Cu,Pb,Ni,Se,TI; EPA 200.7: Ba,Be,Ca,Cd,Cr,Cu,Na; EPA 245.1: Mercury; EPA 300.0: Nitrate-N, Fluoride, Sulfate; EPA.353.2: Nitrate-N, Nitrite-N;SM4500NO3-F: Nitrate-N, Nitrite-N; SM4500.F-C, SM4500CN-CE, EPA 180.1,SM2130B, SM4500C1-D,SM2320B, SM2540C,SM4500H-B EPA 332: Perchlorate. Microbiology:SM9215B; SM9223-P/A,SM9223B-Colilert-QT, Enterolert-QT. Non-Potable Water EPA 200.8:AI,Sb,As,Be,Cd,Cr,Cu,Pb,Mn,Ni,Se,Ag,TI,Zn; � EPA 200.7:AI,Sb,As,Be,Cd,Ca,Cr,Co,Cu,Fe,Pb,Mg,Mn,Mo,Ni,K,Se,Ag,Na,Sr,Ti,TI,V,Zn; EPA 245.1,SM4500H,B, EPA 120.1,SM2510B,SM2540C,SM2340B, SM2320B,SM4500CL-E, SM4500E-BC, SM426C,SM4500NH3-BH, EPA 350.9:Ammonia-N, LACHAT'10-107-06-1-B:Ammonia-N, SM4500NO3-F, EPA 353.2: Nitrate-N,SM4500NH3-BC-NES, EPA 351.1, SM4500P-E, SM4500P-B,E,SM5220D, EPA 410.4, SM5210B,SM5310C,SM4500CL-D, EPA 1664, SI11114 510AC, EPA 420.1,SM4500-CN-CE,SM2540D. EPA 624:Volatile Hafocarbons&Aroma#ics, EPA 608: Chlordane, Toxaphene,Aldrin, alpha-BHC, beta-BHC, gamma-BHC, delta-BHC, Dieldrin, DDD,DDE, DDT, Endosulfan I, Endosulfan II, Endosulfan sulfate, Endrin, Endrin Aldehyde, Heptachlor, Heptachlor Epoxide, PCBs EPA 625: SVOC(Acid/Base/Neutral Extractables), EPA 600/4-81-045: PCB-Oil. Microbiology: SM9223B-Colilert-QT; Enterolert-QT,SM9222D-MF. For a complete listing of analytes and methods, please contact your Alpha Project Manager. Document Type: Form Pre-Qualtrax Document ID: OS-113 Paae 15 of 16 . • "m. �g m�.� o m . '.7.��� �Fa . . a m —n Q. ;� g ai Y 9 � ,_ �Nmo�QA� M �� � �� � �` � m c�mpm't z ��Ci '�O O ''.�0. � �$ �a��'•y m�� N Q � c a 2 �w a :« .a,�o `$ E_�avoa� � -o c � a � a-m �m.� o`,°�o�8 zzssa � -# a � Q'Z � b � m n 'o.E a$�m���y�-m Ln � � � � a, E E m a�.:�Y�q�-,p s � 11-. " W� �L�� � ❑ 4 ❑ ��C �°ilf�7 am�t'��Ti.,na � :.... ; :,��., `<. N = , � � • � _ � � ' . ;.� tt c Z � ,m � � NI �; � _ ❑ � �� Q CI� `��� � C .. . ....:.. . . . ..... . . � �. � . : � .. � � "❑ ❑ ❑ ❑ � a ❑ _ _ . . . � � ❑ ❑ ❑ m � � a .m >_l O � : � � ' ❑ ❑ , m i a W � � �. � 1 � W ' m � N>Il ❑ ❑ , . 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E � � O � � .I,. t m � C � �o� � o LO m � t � (fl �' � °Q °9 Q1 � d `�? � N m n- J � s� r- z, e m m �.s m 3� y: � _ e 4;. � u�i � C d C•j C '� F m � -j. � .s� � ; m _i � y m = KN E � .t.. -�'-� E� ` f0 3 � � . c� �[ m a � w ❑ O ¢ a. • Serial No:06161621:23 � ,; - --- ,�=�, � � �� ,A�l�l A�L�'Y.:�T f C A L � ANALYTICAL REPORT Lab Number: L1617853 Client: Bennett Environmental Associates 1573 Main Street Brewster, MA 02631 ATTN: David Bennett Phone: (508)896-1706 Project Name: DRINANE RESIDENCE Project Number: BEA13-10579 Report Date: 06/16/16 The original project report/data package is held by Alpha Analytical.This report/data package is paginated and should be reproduced only in its enfirety.Alpha Analytical holds no responsibility for results and/or data that are not consistent with the original. Certifications&Approvals: MA(M-MA086),NY (11148),CT(PH-0574),NH{2003);NJ NELAP(MA935),RI(LA000065),ME(MA00086), PA(68-03671),VA(460195),MD(348),IL(200077),NC{666),TX(T104704476),DOD(L2217),USDA(Permit #P-330-11-00240). Eight Walkup Drive,Westborough, MA 01581-1019 508-898-9220 (Fax)508-898-9193 800-624-9220-www.alphalab.com ,-� :�,vi���. P'�fIP 'i nf 1.�'i �; �� a� /�� w M � N M � " tf) CO d � � � � � d .� � � � U � t CD d Cfl � J'� . � � . . . . . . . . . . . O O . Z I � `� ai o0 a� � � � .. � � � c a> � � � o � � � n. � C o J � � � r O R � U ❑ o Q � _ H � O � � c } d o = a'� t- � � o O tn J Cq � >C W �L �- � � W U Z W � � W � � � W o F- Q � 0 W Z Q „r � � W y tj � m - LL U W L . � � � � � � � r Z Z � � Q � T � � � � � � N •� •� ,� �' rr- �. d Q � C� ' (�Q Q � J d • Serial No:06161621:23 Project Name: DRINANE RESIDENCE Lab Number: L1617853 Project Number: BEA13-10579 Report Date: 06/16/16 Case Narrative The samples were received in accordance with the Chain of Custodq and no significant deviations were encountered during the preparation or analysis unless otherwise noted.Sample Receipt,Container Information,and the Chain of Custody are located at the back of the report. Results contained within this report relate only to the samples submitted under this Alpha Lab Number and meet NELAP requirements for all NELAP accredited parameters unless otherwise noted in the following narrative.The data presented in this report is organized by parameter (i.e:VOC,SVOC,etc.).Sample specific Quality Control data(i.e.Surrogate Spike Recovery)is reported at the end of the target analyte list for each individual sample,followed by the Laboratory Batch Quality Control at the end of each parameter.Tentatively Identified Compounds (TICs),if requested,are reported for compounds identified to be present and are not part of the method/program Target Compound List, even if only a subset of the TCL are being reported.If a sample was re-analyzed or re-extracted due to a required quality controi corcective action and if both sets of data are reported,the Laboratory ID of the re-analysis or re-extraction is designated with an"R"or"RE", respectively.When multiple Batch Quality Control elements are reported(e.g.more than one LCS),the associated samples for each element are noted in the grey shaded header line of each data table.Any Laboratory Batch,Sample Specific%recovery or RPD value that is outside the listed Acceptance Criteria is bolded in the report.All specific QC information is also incorporated in the Data Usability forrnat of our Data Merger tool where it can be reviewed along with any associated usability implications.SoiUsediments,solids and tissues are reported on a dry weight basis unless otherwise noted.Definitions of all data qualifiers and acronyms used in this report are provided in the Glossary located at the back of the report. In reference to questions H(CAM)or 4(RCP)when"NO"is checked,the pertormance criteria for CAM and RCP methods allow for some quality control failures to occur and still be within method compliance. In these instances the specfic failure is not narrated but noted in the associated QC table.The information is also incorporated in the Data Usability format of our Data Merger tool where it can be reviewed along with any associated usability implications. Please see the associated ADEx data file for a comparison of laboratory reporting limits that were achieved with the regulatbry Numerical Standards requested on the Chain of Custody. HOLD POLICY For samples submitted on hold,Alpha's policy is to hold samples(with the exception of Air canisters)free of charge for 21 calendar days from the date the project is completed.After 21 calendar days,we will dispose of all samples submitted including those put on hold unless you have contacted your Client Service Representative and made arrangements for Alpha to continue to hold the samples.Air canisters will be disposed after 3 business days from the date the project is completed. Please contact Client Services at 800-&24-9220 with any questions. I,the undersigned, attest under the pains and penalties of perjury that, to the best of my knowledge and belief and based upon my personal inquiry of those responsible for providing the information contained in this analytical report,such information is accurate and complete. This certificate of analysis is not complete unless this page accompanies any and all pages of this report. G��� Cristin Walker Authorized Signature: Title: Technical Director/Representative Date: 06/16/16 Y �......7 ..F�� `��'o/� 4 a Serial No:06161621:23 ` I������ ��� � ��������� ���� � di��-+,'+ Page 4 of 15 ' Serial No:06161621:23 Project Name: DRINANE RESIDENCE Lab Number: L1617853 Project Number: BEA13-10579 Report Date: 06/16/16 SAMPLE RESULTS Lab ID: L1617853-01 Date Collected: 06/10/16 11:00 Client ID: EFF�uENT Date Received: 06/10/16 Sample Location: souTH va,RtwouTH,Mn Field Prep: Not Specified Matrix: Water Dilution Date Date Analytical Parameter Result Qualifer Units RL MDL Factor Prepared Analyzed Method qnalyst General Chemistry-Westborough Lab _ _ Solids,Total Suspended ND mg/I 5.0 NA 1 - 06/13/16 16:35 121,2540D SG - --------------------------.........-------------------._....------..._..._...---------------------__-- -------...-----____---.... Nitrogen,Nitrite 0.081 mgA 0.050 – 1 - 06/10/16 22:08 44,353.2 MR -�-----�---�------...._...---._..__�_—.—..__._�_---------------------...---------------.._�_.__...--------------------------...-------- Nitrogen,Nitrate 3.1 mg/1 0.10 – 1 - 06/10/16 22:08 44,353.2 MR --------------__.___---____----------------------..:__.�—.._._..__..__.._..---------...__..__...--------_-----------------...-------------._...------�— Nitrogen,Total Kjeldahl 2.05 mgA 0.300 – 1 06/13/16 20:00 06/15/16 22:20 121,4500N-C AT -----.�_..---._.._.__._......_.....-----...-------------....-----.._._.�--------.._..__._......_..__..__....._.__...----...._.._._._..._....__------------__------._....—.....---....-----...__--------......_._.._.__.._ BOD,5 day ND mg/l 2.0 NA 1 06/11/16 04:15 06/15/16 23:10 121,52108 TA '�� n..,,.., c ,.f�G Serial No:06161621:23 ' Project Name: DRINANE RESIDENCE Lab Number: L1617853 Project Number: BEA13-10579 Report Date: 06/16/16 Method Blank Analysis Batch f�uality Control Dilution Date Date Analytical Parameter Result Qualifier Units RL IVIDL Factor Prepared Analyzed Method Analyst General Chemistry-Westborough Lab for sample(s): 01 Batch: WG902832-1 Nitrogen,Nitrate ND mgll 0.10 — 1 - 06/10/16 20:58 44,353.2 MR General Chemistry-Westborough Lab for sample(s): 01 Batch: WG902833-1 Nitrogen,Nitrite ND mg/I 0.050 — 1 - 06/10/16 21:00 44,353.2 MR General Chemistry-Westborough Lab for sample(s): 01 Batch: WG902977-1 BOD,5 day ND mgll 2.0 NA 1 06/11/16 04:15 06/15/16 23:10 121,5210B TA General Chemistry-Westborough Lab for sample(s): 01 Batch: WG903365-1 Solids,Total Suspended ND mg/I 5.0 NA 1 - 06/13/16 16:35 121,2540D SG General Chemistry-Westborough Lab for sample(s): 01 Batch: WG903494-1 Nitrogen,Total Kjeldahl ND mgll 0.300 — 1 O6/13/16 20:00 06/15/16 22:07 121,4500N-C AT �. �FiA Page 6 of 15 M N � N �: � y So � � � � �� T � � \ �� O � C.�4 J . N � . N . � �� O CO � 0 z r co a I � � � m •L '�^ vJ L � � �c (Q � � . . . � . G � .. � ... � . .. .� L Z p J � � ' ' ' ' a � Z o � � � `� N N � J rn rn m`� � A � t� ' a ° �.. � � 3 Q.V � � � •� N � ~ � � � � � p p p p: � � U � � � � ' � ' � � Om J� � � � � V � � s t � .Q � � �" .� J m m m m � � (� o 0 0 0 � � � � � � �' °' °' °' °' ! a n fl. � � y o c�n rn ' m � � � m rn ! Jtl y � � N d Q�' � �, � Q o (�6 t�6 N (�-'0 W 'c� U U 'U U N N � N Z y N N y w Q Q Q; Q 0 � W h J J J J � � S . ��. �: L . W p � L71 � � Z � p p p" p z � O O O O Q � -fl � .� � W 1 n c+�n i � m � � � � ..I� .1�� �.�1. .1 L . a� �' �' �' �' � G> .0 UJ �, , W � tn in Y m ' � � � � ., � : � � o ' t0 � � � � �, N Z Z s., �' z � Z .� �° � 1- L!� +, .a� d U � U � U � U � ,� � C� t1 y N o co o c0 � c0 0 0 � O � � z � Z � m � z ~ C C C C � s., � �. � � � U� N tn (II n z N y S. . . . � M Q- � :. � . . N � . m ..� N "'� . c- �� u� � � � � J � r- f` � N N � N CO � ` � �Q� �d ��Q..: �Q� � � � � �� . � .�� � � .. . . O J O � W (6 C4 (0 ZI fn ln [A [n � a � � � � � � � � •� � � i �. � �' � ci � m �'y � �-' � � �_ a� M a� N a� � m Z p C � U M U o V o V � � � � � � � � d � J @�° O O O O tC Cfl C4 � C4 � � r � ti � � ti ti � � � � � ifl Cfl (fl cfl d J J J J 0 � N � N � � � N � N � � � � � � � � � � � � � >,,° a � d a cc = _ ° 0 c � Q �' � ° � �r � � G� �- M c'M') ti rn � � ao m rn � N � � � � � � � x � � � � � � L 'f' R � m �+ p p p p � fn o o rn V � V a V ap � � m U � f�R � m m m m � d Q Q � � r ,d, � r, M � V (q � O �ri O � O �r O � � O %-� %� LL � � � � N N � � fl. a Q d � � � � 'a tD t0 Ri o N G1 � v N v � o � m W � 'a "O '� "� "O U � � N N � � z Q N N N N W O O O O � N y � N W p� > Q- Q � Q 0 Q � Q c° �.' � +-� � � � (�0 z f�6 z (6 N � Z� J J J J W 0 z r' L ...0 � � t Q M � � � � z Q O O O O �' �J.J O O O O ❑ m � � � .n y N � N > � > � d ' ' ' ' c�II d -� �' �.' �' �' a�—i � � �n �n �n �n Y z z E � �E �' �E E � V V L Z t Z � L � L ~ � d � � U � U � U a U � ,� O o y N rn � rn � �' c6 rn � � � � N � N � � � p � � � � � Z � Z � [� � Z � a � � � � � M m N � � �- � �' , � � � �° � .0- � J O � N �° N N � M N N N N ^}�;I � � � � �> � � � �� � Z Q� I � � � � � L d d d d 0.. � � G � Q �, Q Q Q . Z 'C � � ❑ � � n � .� �- c c c c' � J � -a� a� ,g� g a� 0 U � U � U a � o � Z � � ch � c- v� � o 0 o a o ti ti � � � ti � ti ti ti � � � r � CO C4' CO Cfl Cfl aN+ --1 — --� — J — J — J — •= a� o� a� a� a� N = dj � dj � aj � dj, � aj E Q Q d Q d •� � � � � � �—�' O CA (A CA (Q fn � ,F C� U U U U U Q V � � � � � � � � y M M M N o M o V � �p � � �; z � M M r � �n v � U7 V N N N C'� M •�� •� �' � � �: � Gm � � � �` � � � o 0 0 o a c� — — J � � � � � ia c�-a m m m d m m m m m c�o �U' UU' C� UU' � N C° � � N c�o d � � .. Z ..�.� � � N c r � r � > 0 � � 0 � �+ t6 �.� � ..�.. � N .'N.�. N�. Z �: .�: ��� .�. :�. �Q .:Q ��Q .Q Q� �� ���� .� ..�� �.��. .tn �ln� �lU� .(q �.��. W N m N N � Z � N: (�-0 N � W p p p p p Q uJ tA� .tA� tA tn. W � Q Q Q Q Q � f� .� - .� � � ..Q . � m m m ro m W � J J J J J QT t ..C� L L .L� M � a1 � � � z T" � �� .�� � �. . � 'Q O O O O p 11 0 m .�p .�p � � � N � � N � G� � > � � N > L -p dj �/� � � �� �� -o � N � Y � '. .� L L. � L N � � n Z Z fA m � � N � 3 � Y . � . � . . � . � QUi d s. L z r�... z L m L � N �'�' �- �O O Y U c U c U � U I-� U � O IL� IL� � � � ��. � ��. � � � � � O� 4. Y. � L � L. � .L. � L � y_ Oi Q� � � "' � "" N O N O � ." � � C' Z C� Z �C 00 C C4 C Z � � Serial No:06161621:23 ` Project Name: DRINANE RESIDENCE Lab Number: L1617853 Project Number: BEA13-10579 Report Date: 06/16/16 Sample Receipt and Container Information Were project specific reporting limits specified? YES ' Cooler lnformation Custody Seal �ooler A Absent Container Information Temp Container ID Container Type Cooler pH deg C Pres Seal Analysis(*) L1 61 7 853-0 1A Plastic 250m1 H2SO4 preserved A <2 3.3 Y Absent TKN-4500(28) L1617853-01 B Plastic 950m1 unpreserved A 7 3.3 Y Absent NO2�53(2),BOD-5210(2),NO3- 353(2) L1617853-01C Plastic 950m1 unpreserved A 7 3.3 Y Absent TSS-2540(7) *Values in parentheses indicate holding time in days �,a► :�,�.� Page 10 of 15 ' Serial No:06161621:23 Project Name: DRINANE RESIDENCE Lab Number: L1617853 Project Number: BEA13-10579 Report Date: 06/16/16 GLOSSARY Acronyms EDL -Estimated Detection Limit:Tlus value represents the level to which target analyte concentrations aze reported as estimated values,when those target analyte concentrations are quantified below the reporting limit(RL).The EDL includes any adjustrnents from dilutions,concentrations or moisture content,where applicable.The use of EDLs is specific to the analysis of PAHs using Solid-Phase Microextraction(SPME). EPA -Environmental Protection Agency. LCS -Laboratory Control Sample:A sample matrix,free from the analytes of interest,spiked with veiified lmown amounts of analytes or a material containing lmown and verified amounts of analytes. LCSD -Laboratory Control Sample Dupiicate:Refer to LCS. LFB -Laboratory Fortified Blank:A sample matrix,free from the analytes of interest,spiked with verified known amounts of analytes or a materiat confaining known and verified amounts of analytes. IvIDL -Method Detection Limit:This value represents the level to which target analyte concentrations aze reported as estimated values,when those target analyte concentrations aze quantified below the reporting limit(RL).The MDL includes any adjustments from dilutions,concentrations or moisture content,where applicable. MS -Mairix Spike Sample:A sample prepued by adding a known mass of tazget analyte to a specified amount of matrix sample for which an independent estimate of target analyte concentration is available. MSD -Matrix Spike Sample Duplicate:Refer to MS. NA -Not Applicable. NC -Not Calculated: Term is utilized when one or more of the results utilized in the calculation are non-detect at the parameter's I�OI'trIIp U1llL NDPA/DPA -N Nitrosodiphenylamine/Diphenylamine. NI -Not Ignitable. NP -Non-Plastic:Term is utilized for the analysis of Atterberg Limits in soil. RL -Reporting Limit: The value at wlrich an instrument can accurateiy measure an analyte at a specific concentration.The RL inciudes any adjusiments from dilutions,concentrations or moisture content,where applicable. RPD -Relative Percent Difference: The resuits from matr�and/or matrix spike duplicates aze primarily designed to assess the precision of analytical results in a given mah-ix and aze expressed as relative percent difference(RPD). Values which are less than five times the reporting limit for any individual parameter aze evaluated by utilizing the absolute difference between the values;although the RPD value will be provided in the repork SRM -Standard Reference Material:A reference sample of a Imown or certified value that is of the same or similaz mahix as the associated field samples. STLP -Semi-dynamic Tank I.eaching Procedure per EPA Method 1315. TIC -Tentatively Identified Compound:A compound that has been identified to be present and is not part of the target compound list(TCL)for the method and/or program.All TICs are qualitatively identified and reported as estimated concentrations. Footnotes i -The reference for this analyte should be considered modified since this analyte is absent from the target analyte list of the original method. Terms Total:With respect to Organic analyses,a'Total'result is defined as the summation of results for individual isomers or Aroclors.If a Total' result is requested,the results of its individual components will also be reported Tlus is applicable to'Total'results for methods 8260,8081 and 8082. Analytical Method:Both the document from which the method originates and ihe analytical reference method.(Example:EPA 8260B is shown as 1,8260B.)The codes for the reference method documents are provided in The References section of the Addend»m Data Qua/ifters A -Spech�a identified as"Aldol Condensation ProducY'. B -The analyte was detected above the reporting limit in the associated method blank.Flag only applies to associated fieid samples that have detectable concentrations of the analyte at less than ten times(l Ox)the concentration found in the blank.For MCP-related projects,flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times(l Ox) the concentration found in the blanlc For DOD-related projects,flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times(l Ox)the concentration found in the blank AND the analyte was detected above one-half the reporting limit(or above the reporting limit for common lab contaminants)in the associated method blank.For NJ- Air-related projects,flag only applies to associated field sampies that have detectable concentrations of the analyte above the reporting limit For NJ-related projects(excluding Air),flag only applies to associated field samples that have detectabie concenh-ations of the analyte,which was detected above the reporting limit in the associated method blank or above five times the •Report Format: Data Usability Report �,, ���� Serial No:06161621:23 ' Project Name: DRINANE RESIDENCE Lab Number: L1617853 Project Number: BEA13-10579 Report Date: 06/16/16 Data Qualifiers reporting limit for common lab contaminants(Phthalates,Acetone,Methylene Chloride,2-Butanone). C -Co-elurion:The target analyte co-elutes with a known lab standard(i.e.smrogate,intemal standards,etc.)for co-exh�acted analyses. _ _ __ _ D -Concentrarion of analyte was quantified from diluted analysis.Flag only applies to field samples that have detectable concentrations of the analyte. E -Concentration of analyte exceeds the range of the calibration curve and/or linear range of the instrument. G -The conceniration may be biased Irigh due to mahix interferences(i.e,co-elution)with non-target compound(s).The result should be considered estimated. H -The analysis of pFi was performed beyond the regulatory-required holding time of 15 minutes from the tixne of sample collection. I -The lower value for the two columns has been reported due to obvious interference. M -Reporting Limit(RL)exceeds the MCP CAM Reporting Limit for tlus analyte. NJ -Presumptive evidence of compound.This represents an estimated concenh-ation for Tentatively Identified Compounds(TICs),where the identification is based on a mass spectral library search. P -The RPD between the results for the two colmnas exceeds the method-specified criteria. Q -The quality control sample exceeds the associated acceptance criteria.For DOD-related projects,LCS and/or Continuing Calibration Standard exceedences are also qualified on all associated sample results. Note:This flag is not applicable for matrix spike recoveries when the sample concentration is greater than 4x the spike added or for batch duplicate RPD when the saznple concentrations aze less than Sx the RL.(Metals only.) R -Analytical results are from sample re-analysis. RE -Analytical results are from sample re-estraction. S -Analytical results aze fiom modified screening analysis. J -Estimated value.This represents an estimated concentration for Tentatively Identified Compounds(TICs). ND -Not detected at the reporting limit(RL)for the sample. Report Format: Data Usability Report �� _Page 12 of 15 ' Serial No:06161621:23 Project Name: DRINANE RESIDENCE Lab Number: L1617853 Project Number: BEA13-10579 Report Date: 06/16/16 REFERENCES 44 Methods for the Determination of Inorganic Substances in Environmental Sampies, EPA/600/R-93/100, August 1993. 121 Standard Methods for the Examination of Water and Wastewater. APHA-AWWA-WEF. Standard Methods Online. LIMITATION OF LIABILITIES Alpha Analytical performs services with reasonable care and diligence normal to the analytical testing laboratory industry. In the event of an error,the sole and exclusive responsibility of Alpha Analytical shall be to re-perform the work at it's own expense. In no event shall Alpha Analytical be held liable for any incidental, consequential or special damages, including but not limited to, damages in any way connected with the use of, interpretation of, information or analysis provided by Alpha Analytical. We strongly urge our clients to comply with EPA protocol regarding sample volume,preservation,cooling, containers, sampling procedures, holding time and splitting of samples in the field. ,_� �� .sz_-:a,�.. � ; Serial No:06161621:23 Alpha Analytical, Inc. ID No.:17873 Facility: Company-wide Revision 6 Department: Quality Assurance Published Date: 2/3/2016 10:23:10 AM Title: Certificate/Approval Proqram Summarv Paqe 1 of 1 Certification Information The following analytes are not included in our Primary NELAP Seope of Accreditation: Westborough Facility EPA52A.2:1,2-Dibromo-3-chloropropane,1,2-Dibromoethane,m/p-xylene,o-xylene EPA 624:2-Butanone(MEK), 1,4-Dioxane,tert-Amylmethyl Ether,tert-Butyl Alcohol,m/p-xylene,o-xylene EPA 625: Miline,Benzoic Acid,Benzyi Aicohol,4-Chloroaniline,3-Methylphenol,4-Methylphenol. EPA 1010A: NPW: ignitability EPA 6010C: NPW:Strontium;SCM: Strontium EPA8151A: NPW:2,4-DB,Dicamba,Dichloroprop,MCPA,MCPP;SCM: 2,4-DB,Dichloroprop,MCPA,MCPP EPA 8260C:NPW:1,2,4,5-Tetramethylbenzene;4-Ethyitoluene,Azobenzene,Isopropanol;SCM:lodomethane(methyl iodide),Methyl methacrylate (soil);1,2,4,5-Tetramethylbenzene;4-Ethyltoluene. EPA 8270D: NPW:Pentachloronitrobenzene,1-Methylnaphthalene,Dimethylnaphthalene,1,4-Diphenylhydrazine;SCM:Pentachloronitrobenzene,1- Methylnaphthalene,Dimethylnaphthalene,l,4-Diphenylhydrazine. EPA9010: NPW: Amenable Cyanide Distillation,Total Cyanide Distillation EPA 9038: NPW: Sulfate EPA 9050A: NPW:Specific Conductance EPA 9056:NPW:Chloride,Nitrate,Sulfate EPA 9U65: NPW:Phenols EPA 9251: NPW:Chloride SM3500: NPW:Ferrous Iron SM4500:NPW: Amenable Cyanide,Dissolved Oxygen;SCM:Total Phosphorus,TKN,NO2,NO3. SM5310C:DW:Dissolved Organic Carbon Mansfield Facility EPA 8270D:NPW: Biphenyl;SCM: Biphenyi,Caprolactam EPA 8270D-SIM Isotope Dilution: SCM: 1,4Dioxane SM 2540D: TSS SM2540G: SCM:Percent Solids EPA1631E:SCM: Mercury EPA 7474: SCM: Mercury EPA808'IB:NPW and SCM:Mirex,Hexachlorobenzene. EPA8082A: NPW: PCB:1,5,31,87,101,110,141,151,153, 180,183, 187. EPA 8270�SIM: NPW and SCM: Alkylated PAHs. EPATO-15:Halothane,2,4,4-Trimethyl-2-pentene,2,4,4-Trimethyl-1-pentene,Thiophene,2-Methylthiophene, 3-Methyfthiophene,2-Ethylthiophene,1,2,3-Trimethylbenzene,Indan, Indene,1,2,4,5-Tetramethylbenzene,Benzothiophene,1-Methylnaphthalene,n- Butylbenzene,n-Propylbenzene,sec-Butylbenzene,tert-Butylbenzene. Biological Tissue Matrix: 8270D-S1M;30508;3051A;74718;80818;8082A;6020A:Lead;8270D:bis(2-ethylhexyl)phthalate,Butyibenrylphthalate, Diethyl phthalate,Dimethyl phthalate,Di-n-butyl phthalate,Di-n-ocryl phthalate,Fluoranthene,Pentachlorophenol. The following analytes are included in our Massachusetts DEP Scope of Accreditation,Westborough Facility: Drinking Wafer EPA200.8:Sb,As,Ba,Be,Cd,Cr,Cu,Pb,Ni,Se,TI; EPA200.7:Ba,Be,Ca,Cd,Cr,Cu,Na;EPA245.1:Mercury; EPA 300.0:Nitrate-N,Fluoride,Sulfate;EPA 353.2:Nitrate-N,Nitrite-N;SM4500NO3-F:Nitrate-N,Nitrite-N;SM4500E-C,SM4500CN-CE,EPA 180.1, SM2130B,SM4500CI-D,SM23206,SM2540C,SM4500H-B EPA 332:Perchlorate. Microbiology:SM9215B;SM9223-P/A,SM92238-Colilert-QT,Enterolert-QT. Non-Potable Water EPA 200.8:AI,Sb,As,Be,Cd,Cr,Cu,Pb,Mn,Ni,Se,Ag,TI,Zn; EPA200.7:AI,Sb,As,Be,Cd,Ca,Cr,Co,Cu,Fe,Pb,Mg,Mn,Mo,Ni,K,Se,Ag,Na,Sr,Ti,TI,V,Zn; EPA 245.1,SM4500H,B,EPA 120.1,SM2510B,SM2540C,SM23406,SM2320B,SM4500CL-E,SM4500E-BC,SM426C,SM4500NH3-BH,EPA 350.1:Ammonia-N,LACHAT 10-107-06-1-B:Ammonia-N,SM4500NO3-F, EPA 353.2:Nitrate-N,SM4500NH3-BC-NES,EPA 351.1,SM4500P-E,SM4500P-B,E,SM5220D,EPA 410.4,SM5270B,SM5310C,SM4500CL-D, EPA 1664,SM14 510AC,EPA 420.1,SM4500-CN-CE,SM2540D, EPA 6?A:Volatile Halocarbons&Aromatics, EPA608:Chlordane,Toxaphene,Aldrin,alpha-BHC,beta-BHC,gamma-BHC,deita-6HC,Dieldrin,DDD,DDE,DDT,Endosulfan I,Endosulfan II, Endosulfan sulfate,Endrin,Endrin Aldehyde,Heptachlor,Heptachlor Epoxide,PCBs EPA 625:SVOC(Acid/Base/Neutral Extractables),EPA 600/4-81-045:PCB-Oil. Microbiology:SM9223B-Colilert-QT;Enterolert-QT,SM9222D-MF. For a complete listing of analytes and methods,please contact your Alpha Project Manager. Document Type: Form Pre-Qualtrax Document ID: 08-113 Paqe 14 of 15 � e _ .. _ . `" 1 � � " +� C f�S � � � 0 a ;� �N fl a .�. 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