HomeMy WebLinkAboutDMR Filing 10 2023 11494Massachusetts Department of Environmental Protection
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1638061
11/17/2023:1:42:55 PM
1079.25K
SFARRENKOPF
Groundwater Discharge Monitoring Report Forms
In Process
Important:When
filling out forms on
the computer, use
only the tab key to
move your cursor
do not use the
return key.
A. Facility Information
1. Facility name, address:
THE COVE RESORT HOTEL
a. Name
183 MAIN STREET/RTE. 28
b. Street Address
YARMOUTH MA 02673
c. City d. State e. Zip Code
2. Contact information:
BRIAN FORTIN
a. Name of Facility Contact Person
7742302911 bfortin@NSUWater.com
b. Telephone Number c. email address
3. Sampling information:
10/1/2023 NOT APPLICABLE
a. Date Sampled (mm/dd/yyyy)b. Laboratory Name
BEA/NSU WWTO PERSONNEL
c. Analysis Performed By (Name)
B. Form Selection
1. Please select Form Type and Sampling Month & Frequency
Daily Log Sheet 2023 Oct Daily
All forms for submittal have been completed.
2.This is the last selection.
3.Delete the selected form.
gdpdls 20150915.doc • rev. 09/15/15 Groundwater Permit Daily Log Sheet • Page 1 of 1
Massachusetts Department of Environmental Protection
Bureau of Resource Protection Groundwater Discharge Program
Groundwater Permit
DAILY LOG SHEET
162
1. Permit Number
042969095
2. Tax identification Number
2023 OCT DAILY
3. Sampling Month & Frequency
C. Daily Readings/Analysis Information
Date Effluent
Flow GPD
Reuse
Flow GPD
Irrigation
Flow GPD
Turbidity Influent pH Effluent
pH
Chlorine
Residual
(mg/l)
UV
Intensity
(%)
1 15156
2 13004 7.5 7.3
3 16000 7.6 7.4
4 11198 7.5 7.3
5 12820 7.5 7.3
6 11783 8.0 7.6
7 11783
8 11783
9 14602 7.7 7.6
10 11363 7.6 7.6
11 13445 7.5 7.5
12 15631 7.5 7.5
13 12824 7.5 7.6
14 12824
15 12824
16 13808 7.6 7.3
17 12012 7.4 7.2
18 13512 7.4 7.3
19 13413 7.4 7.3
20 11947 7.5 7.4
21 11947
22 11947
23 15857 7.5 7.5
24 11871 7.4 7.6
25 11694 7.0 7.0
26 15979 7.0 7.1
27 11644 7.4 7.1
28 11644
29 11644
30 15178 7.0 7.0
31 7847 7.0 7.2
gdpdls.doc • rev. 09/15/15 Groundwater Permit Daily Log Sheet • Page 1 of 1
Massachusetts Department of Environmental Protection
Bureau of Resource Protection Groundwater Discharge Program
Groundwater Permit
DAILY LOG SHEET
162
1. Permit Number
042969095
2. Tax identification Number
2023 OCT DAILY
3. Sampling Month & Frequency
Important:When
filling out forms on
the computer, use
only the tab key to
move your cursor
do not use the
return key.
A. Facility Information
1. Facility name, address:
THE COVE RESORT HOTEL
a. Name
183 MAIN STREET/RTE. 28
b. Street Address
YARMOUTH MA 02673
c. City d. State e. Zip Code
2. Contact information:
BRIAN FORTIN
a. Name of Facility Contact Person
7742302911 bfortin@NSUWater.com
b. Telephone Number c. email address
3. Sampling information:
10/12/2023 ALPHA ANALYTICAL
a. Date Sampled (mm/dd/yyyy)b. Laboratory Name
ALPHA ANALYTICAL PERSONNEL
c. Analysis Performed By (Name)
B. Form Selection
1. Please select Form Type and Sampling Month & Frequency
Discharge Monitoring Report 2023 Oct Monthly
All forms for submittal have been completed.
2.This is the last selection.
3.Delete the selected form.
gdpdls 20150915.doc • rev. 09/15/15 Groundwater Permit Daily Log Sheet • Page 1 of 1
Massachusetts Department of Environmental Protection
Bureau of Resource Protection Groundwater Discharge Program
Groundwater Permit
DISCHARGE MONITORING REPORT
162
1. Permit Number
042969095
2. Tax identification Number
2023 OCT MONTHLY
3. Sampling Month & Frequency
D. Contaminant Analysis Information
For "0", below detection limit, less than (<) value, or not detected, enter "ND"
TNTC = too numerous to count. (Fecal results only)
NS = Not Sampled
1. Parameter/Contaminant 2. Influent 3. Effluent 4. Effluent Method
Units Detection limit
BOD 54 3.7 2.0
MG/L
TSS 46 ND 5.0
MG/L
TOTAL SOLIDS 490
MG/L
NITRATEN 10 0.50
MG/L
TOTAL NITROGEN(NO3+NO2+TKN)30.60 12.56 2.05
MG/L
OIL & GREASE ND 3.6
MG/L
infeffrpblank.doc • rev. 09/15/15 Groundwater Permit Discharge Monitoring Report • Page 1 of 1
Massachusetts Department of Environmental Protection
Bureau of Resource Protection Groundwater Discharge Program
Groundwater Permit
DISCHARGE MONITORING REPORT
162
1. Permit Number
042969095
2. Tax identification Number
2023 OCT MONTHLY
3. Sampling Month & Frequency
Important:When
filling out forms on
the computer, use
only the tab key to
move your cursor
do not use the
return key.
A. Facility Information
1. Facility name, address:
THE COVE RESORT HOTEL
a. Name
183 MAIN STREET/RTE. 28
b. Street Address
YARMOUTH MA 02673
c. City d. State e. Zip Code
2. Contact information:
BRIAN FORTIN
a. Name of Facility Contact Person
7742302911 bfortin@NSUWater.com
b. Telephone Number c. email address
3. Sampling information:
10/23/2023 NOT APPLICABLE
a. Date Sampled (mm/dd/yyyy)b. Laboratory Name
BEA/NSU WWTO PERSONNEL
c. Analysis Performed By (Name)
B. Form Selection
1. Please select Form Type and Sampling Month & Frequency
Monitoring Well Data Report 2023 Oct Monthly
All forms for submittal have been completed.
2.This is the last selection.
3.Delete the selected form.
gdpdls 20150915.doc • rev. 09/15/15 Groundwater Permit Daily Log Sheet • Page 1 of 1
Massachusetts Department of Environmental Protection
Bureau of Resource Protection Groundwater Discharge Program
Groundwater Permit
MONITORING WELL DATA REPORT
162
1. Permit Number
042969095
2. Tax identification Number
2023 OCT MONTHLY
3. Sampling Month & Frequency
C. Contaminant Analysis Information
For "0", below detection limit, less than (<) value, or not detected, enter "ND"
TNTC = too numerous to count. (Fecal results only)
NS = Not Sampled
DRY = Not enough water in well to sample.
<
Parameter/Contaminant 4A 5 6A 7A
Units Well #: 1 Well #: 2 Well #: 3 Well #: 4 Well #: 5 Well #: 6
PH 5.86 5.91 6.71 6.03
S.U.
STATIC WATER LEVEL NS NS NS NS
FEET
SPECIFIC CONDUCTANCE 248 503 860 408
UMHOS/C
mwdgwpblank.doc • rev. 09/15/15 Monitoring Well Data for Groundwater Permit • Page 1 of 1
Massachusetts Department of Environmental Protection
Bureau of Resource Protection Groundwater Discharge Program
Groundwater Permit
MONITORING WELL DATA REPORT
162
1. Permit Number
042969095
2. Tax identification Number
2023 OCT MONTHLY
3. Sampling Month & Frequency
Important:When
filling out forms on
the computer, use
only the tab key to
move your cursor
do not use the
return key.
Any person signing
a document under
314 CMR 5.14(1) or
(2) shall make the
following
certification
If you are filing
electronically and
want to attach
additional
comments, select
the check box.
Facility Information
THE COVE RESORT HOTEL
a. Name
183 MAIN STREET/RTE. 28
b. Street Address
YARMOUTH MA 02673
c. City d. State e. Zip Code
Certification
“I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted.
Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the
information, the information submitted is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there
are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.”
SAMANTHA FARRENKOPF 11/17/2023
a. Signature b. Date (mm/dd/yyyy)
Reporting Package Comments
BENNETT ENVIRONMENTAL ASSOCIATES, LLC. (BEA) HAS COMPLETED THE OCTOBER 2023
OPERATION OF THE RBC WASTEWATER TREATMENT SYSTEM. EFFLUENT PH WAS
REPORTED WITHIN THE 6.58.5 RANGE THROUGHOUT THE MONTH. DAILY FLOW WAS
RECORDED BELOW THE 39,900 GPD LIMITATION THROUGHOUT THE MONTH. THE MINIMUM,
MAXIMUM, AND AVERAGE GPD FLOWS REPORTED WERE 7,847 GPD, 16,000 GPD, AND
12,870 GPD, RESPECTIVELY. MONTHLY WASTEWATER SAMPLING WAS COMPLETED ON
10/12/23. LABORATORY ANALYSIS REPORTED TOTAL NITROGEN GREATER THAN
DISCHARGE PERMIT LIMITATIONS. EFFLUENT RESAMPLING COMPLETED ON 10/30/23 FOR
ANALYSIS OF TOTAL NITROGEN REPORTED A CONCENTRATION OF 10.41 MG/L. STATIC
WATER LEVEL WAS UNABLE TO BE REPORTED FOR MONTHLY GROUNDWATER
MONITORING, AS THE FORMER OPERATOR WAS NOT IN POSSESSION OF TOP OF CASING
ELEVATION DATA FOR ONSITE MONITORING WELLS, AND THAT INFORMATION WAS
ADDITIONALLY NOT ABLE TO BE IDENTIFIED THROUGH RESEARCH OF EXISTING FACILITY
DOCUMENTATION. A SURVEYOR WAS CONTRACTED TO COMPLETE A TOP OF CASING
ELEVATION SURVEY, WITH COMPLETION OF THAT WORK PENDING AT THE TIME OF THIS
REPORTING. GROUNDWATER MONITORING WAS CONDUCTED AND DEPTH TO WATER
RECORDED AS REQUIRED. ONCE THE ELEVATION DATA IS AVAILABLE, ANY MISSING STATIC
WATER LEVEL DATA WILL BE CALCULATED AND REPORTED.
gdpdls 20150915.doc • rev. 09/15/15 Groundwater Permit • Page 1 of 1
Massachusetts Department of Environmental Protection
Bureau of Resource Protection Groundwater Discharge Program
Groundwater Permit
162
1. Permit Number
042969095
2. Tax identification Number
L2360570
Bennett Environmental Associates
K11494DA.S.WW.700
THE COVE @ YARMOUTH
Client:
Project Name:
Project Number:
10/20/23
Eight Walkup Drive, Westborough, MA 01581-1019
Lab Number:
Report Date:
508-898-9220 (Fax) 508-898-9193 800-624-9220 - www.alphalab.com
1573 Main Street
Brewster, MA 02631
Samantha FarrenkopfATTN:
ANALYTICAL REPORT
Certifications & Approvals: MA (M-MA086), NH NELAP (2064), CT (PH-0826), IL (200077), IN (C-MA-03), KY (KY98045), ME (MA00086), MD
(348), NJ (MA935), NY (11148), NC (25700/666), OH (CL108), OR (MA-1316), PA (68-03671), RI (LAO00065), TX (T104704476), VT (VT-0935),
VA (460195), USDA (Permit #525-23-122-91930).
(508) 896-1706Phone:
The original project report/data package is held by Alpha Analytical. This report/data package is paginated and should be reproduced only in its
entirety. Alpha Analytical holds no responsibility for results and/or data that are not consistent with the original.
Serial_No:10202317:02
Page 1 of 17
L2360570-01
L2360570-02
Alpha
Sample ID
INFLUENT
EFFLUENT
Client ID
YARMOUTH, MA
YARMOUTH, MA
Sample
Location
THE COVE @ YARMOUTH
K11494DA.S.WW.700
Project Name:
Project Number:
Lab Number:
Report Date:
L2360570
10/20/23
10/12/23 12:35
10/12/23 11:30
Collection
Date/TimeMatrix Receive Date
WATER
WATER
10/12/23
10/12/23
Serial_No:10202317:02
Page 2 of 17
THE COVE @ YARMOUTH
K11494DA.S.WW.700
Project Name:
Project Number:
Lab Number:
Report Date:
L2360570
10/20/23
Case Narrative
I, the undersigned, attest under the pains and penalties of perjury that, to the best of my knowledge and
belief and based upon my personal inquiry of those responsible for providing the information contained
in this analytical report, such information is accurate and complete. This certificate of analysis is not
complete unless this page accompanies any and all pages of this report.
Authorized Signature:
Title: Technical Director/Representative Date: 10/20/23
The samples were received in accordance with the Chain of Custody and no significant deviations were encountered during the preparation
or analysis unless otherwise noted. Sample Receipt, Container Information, and the Chain of Custody are located at the back of the report.
Results contained within this report relate only to the samples submitted under this Alpha Lab Number and meet NELAP requirements for all
NELAP accredited parameters unless otherwise noted in the following narrative. The data presented in this report is organized by parameter
(i.e. VOC, SVOC, etc.). Sample specific Quality Control data (i.e. Surrogate Spike Recovery) is reported at the end of the target analyte list
for each individual sample, followed by the Laboratory Batch Quality Control at the end of each parameter. Tentatively Identified
Compounds (TICs), if requested, are reported for compounds identified to be present and are not part of the method/program Target
Compound List, even if only a subset of the TCL are being reported. If a sample was re-analyzed or re-extracted due to a required quality
control corrective action and if both sets of data are reported, the Laboratory ID of the re-analysis or re-extraction is designated with an "R"
or "RE", respectively.
When multiple Batch Quality Control elements are reported (e.g. more than one LCS), the associated samples for each element are noted in
the grey shaded header line of each data table. Any Laboratory Batch, Sample Specific % recovery or RPD value that is outside the listed
Acceptance Criteria is bolded in the report. In reference to questions H (CAM) or 4 (RCP) when "NO" is checked, the performance criteria
for CAM and RCP methods allow for some quality control failures to occur and still be within method compliance. In these instances, the
specific failure is not narrated but noted in the associated QC Outlier Summary Report, located directly after the Case Narrative. QC
information is also incorporated in the Data Usability Assessment table (Format 11) of our Data Merger tool, where it can be reviewed in
conjunction with the sample result, associated regulatory criteria and any associated data usability implications.
Soil/sediments, solids and tissues are reported on a dry weight basis unless otherwise noted. Definitions of all data qualifiers and acronyms
used in this report are provided in the Glossary located at the back of the report.
HOLD POLICY - For samples submitted on hold, Alpha's policy is to hold samples (with the exception of Air canisters) free of charge for 21
calendar days from the date the project is completed. After 21 calendar days, we will dispose of all samples submitted including those put
on hold unless you have contacted your Alpha Project Manager and made arrangements for Alpha to continue to hold the samples. Air
canisters will be disposed after 3 business days from the date the project is completed.
Please contact Project Management at 800-624-9220 with any questions.
Serial_No:10202317:02
Page 3 of 17
INORGANICS
&
MISCELLANEOUS
Serial_No:10202317:02
Page 4 of 17
FF
INFLUENTClient ID:
10/12/23 12:35Date Collected:
10/12/23Date Received:
Parameter Result
Dilution
Factor
Matrix:Water
YARMOUTH, MASample Location:
L2360570-01Lab ID:
Qualifier Units RL
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
THE COVE @ YARMOUTH
K11494DA.S.WW.700
L2360570
Field Prep:
Date
Analyzed
Analytical
Method Analyst
Not Specified
General Chemistry - Westborough Lab
Solids, Total
Solids, Total Suspended
Nitrogen, Nitrite
Nitrogen, Nitrate
Nitrogen, Total Kjeldahl
BOD, 5 day
490
46.
ND
ND
30.6
54
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
1.3
4
1
1
5
5
13
20
0.050
0.10
1.50
10
10/17/23 05:13
10/14/23 09:41
10/13/23 05:51
10/13/23 05:51
10/19/23 20:27
10/18/23 14:15
121,2540B
121,2540D
44,353.2
44,353.2
121,4500NH3-H
121,5210B
DEW
CVN
KAF
KAF
AVT
JRG
Date
Prepared
-
-
-
-
10/18/23 14:26
10/13/23 18:43
10/20/23
MDL
NA
NA
--
--
--
NA
Sample Depth:
Serial_No:10202317:02
Page 5 of 17
FF
EFFLUENTClient ID:
10/12/23 11:30Date Collected:
10/12/23Date Received:
Parameter Result
Dilution
Factor
Matrix:Water
YARMOUTH, MASample Location:
L2360570-02Lab ID:
Qualifier Units RL
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
THE COVE @ YARMOUTH
K11494DA.S.WW.700
L2360570
Field Prep:
Date
Analyzed
Analytical
Method Analyst
Not Specified
General Chemistry - Westborough Lab
Solids, Total Suspended
Nitrogen, Nitrite
Nitrogen, Nitrate
Nitrogen, Total Kjeldahl
BOD, 5 day
Oil & Grease, Hem-Grav
ND
0.62
10.
1.94
3.7
ND
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
1
1
5
5
1
.9
5.0
0.050
0.50
1.50
2.0
3.6
10/14/23 09:41
10/13/23 05:52
10/13/23 06:27
10/19/23 20:28
10/18/23 14:15
10/20/23 10:50
121,2540D
44,353.2
44,353.2
121,4500NH3-H
121,5210B
140,1664B
CVN
KAF
KAF
AVT
JRG
JGM
Date
Prepared
-
-
-
10/18/23 14:26
10/13/23 18:43
10/20/23 08:27
10/20/23
MDL
NA
--
--
--
NA
--
Sample Depth:
Serial_No:10202317:02
Page 6 of 17
FF
Parameter Result
Dilution
FactorQualifierUnitsRL
Method Blank Analysis
Batch Quality Control
Project Name:
Project Number:
Lab Number:
Report Date:
THE COVE @ YARMOUTH
K11494DA.S.WW.700
L2360570
Date
Analyzed
Analytical
Method Analyst
Date
Prepared
10/20/23
Nitrogen, Nitrite
Nitrogen, Nitrate
BOD, 5 day
Solids, Total Suspended
Solids, Total
Nitrogen, Total Kjeldahl
Oil & Grease, Hem-Grav
ND
ND
ND
ND
ND
ND
ND
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
1
1
1
1
1
1
1
0.050
0.10
2.0
5.0
10
0.300
4.0
10/13/23 03:21
10/13/23 03:26
10/18/23 14:15
10/14/23 09:41
10/17/23 05:13
10/19/23 20:19
10/20/23 10:38
44,353.2
44,353.2
121,5210B
121,2540D
121,2540B
121,4500NH3-H
140,1664B
KAF
KAF
JRG
CVN
DEW
AVT
JGM
-
-
10/13/23 18:43
-
-
10/18/23 14:26
10/20/23 08:27
General Chemistry - Westborough Lab for sample(s): 01-02 Batch: WG1839198-1
General Chemistry - Westborough Lab for sample(s): 01-02 Batch: WG1839201-1
General Chemistry - Westborough Lab for sample(s): 01-02 Batch: WG1839573-1
General Chemistry - Westborough Lab for sample(s): 01-02 Batch: WG1839728-1
General Chemistry - Westborough Lab for sample(s): 01 Batch: WG1840506-1
General Chemistry - Westborough Lab for sample(s): 01-02 Batch: WG1841298-1
General Chemistry - Westborough Lab for sample(s): 02 Batch: WG1842201-1
MDL
--
--
NA
NA
NA
--
--
Serial_No:10202317:02
Page 7 of 17
Nitrogen, Nitrite
Nitrogen, Nitrate
BOD, 5 day
Solids, Total Suspended
Solids, Total
Nitrogen, Total Kjeldahl
Oil & Grease, Hem-Grav
102
98
107
92
105
90
88
-
-
-
-
-
-
-
90-110
90-110
85-115
80-120
80-120
78-122
78-114
-
-
-
-
-
-
-
20
20
18
Parameter
LCS
%Recovery
LCSD
%Recovery
%Recovery
Limits RPD RPD Limits
General Chemistry - Westborough Lab Associated sample(s): 01-02 Batch: WG1839198-2
General Chemistry - Westborough Lab Associated sample(s): 01-02 Batch: WG1839201-2
General Chemistry - Westborough Lab Associated sample(s): 01-02 Batch: WG1839573-2
General Chemistry - Westborough Lab Associated sample(s): 01-02 Batch: WG1839728-2
General Chemistry - Westborough Lab Associated sample(s): 01 Batch: WG1840506-2
General Chemistry - Westborough Lab Associated sample(s): 01-02 Batch: WG1841298-2
General Chemistry - Westborough Lab Associated sample(s): 02 Batch: WG1842201-2
Lab Control Sample Analysis
Batch Quality ControlProject Name:
Project Number:
Lab Number:
Report Date:
THE COVE @ YARMOUTH
K11494DA.S.WW.700
L2360570
10/20/23
Qual Qual Qual
Serial_No:10202317:02
Page 8 of 17
Nitrogen, Nitrite
Nitrogen, Nitrate
BOD, 5 day
Nitrogen, Total Kjeldahl
Oil & Grease, Hem-Grav
ND
15
ND
0.695
ND
4.3
18
110
10.9
34
108
75
106
128
87
-
-
-
-
-
-
-
-
-
-
80-120
83-113
50-145
77-111
78-114
-
-
-
-
-
20
6
35
24
18
Parameter
Native
Sample
MS
Found
MS
%Recovery
MSD
Found
MSD
%Recovery
Recovery
Limits RPD
RPD
Limits
General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1839198-4 QC Sample: L2360557-01 Client ID: MS Sample
General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1839201-4 QC Sample: L2360557-01 Client ID: MS Sample
General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1839573-4 QC Sample: L2360560-01 Client ID: MS Sample
General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1841298-4 QC Sample: L2360566-01 Client ID: MS Sample
General Chemistry - Westborough Lab Associated sample(s): 02 QC Batch ID: WG1842201-4 QC Sample: L2355345-92 Client ID: MS Sample
4
4
100
8
39.2
MS
Added
Matrix Spike Analysis
Batch Quality Control
Project Name:
Project Number:
Lab Number:
Report Date:
THE COVE @ YARMOUTH
K11494DA.S.WW.700
L2360570
10/20/23
Qual
Q
Q
Qual Qual
Serial_No:10202317:02
Page 9 of 17
Nitrogen, Nitrite
Nitrogen, Nitrate
BOD, 5 day
Solids, Total Suspended
Solids, Total
Nitrogen, Total Kjeldahl
Oil & Grease, Hem-Grav
ND
15
ND
52
580
0.695
ND
ND
15
ND
55
510
0.798
ND
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
NC
0
NC
6
13
14
NC
20
6
35
32
16
24
18
Units RPDParameterNative Sample Duplicate Sample RPD Limits
General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1839198-3 QC Sample: L2360557-01 Client ID: DUP Sample
General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1839201-3 QC Sample: L2360557-01 Client ID: DUP Sample
General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1839573-3 QC Sample: L2360560-01 Client ID: DUP Sample
General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1839728-3 QC Sample: L2360511-03 Client ID: DUP Sample
General Chemistry - Westborough Lab Associated sample(s): 01 QC Batch ID: WG1840506-3 QC Sample: L2359754-01 Client ID: DUP Sample
General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1841298-3 QC Sample: L2360566-01 Client ID: DUP Sample
General Chemistry - Westborough Lab Associated sample(s): 02 QC Batch ID: WG1842201-3 QC Sample: L2355345-91 Client ID: DUP Sample
THE COVE @ YARMOUTH
K11494DA.S.WW.700
Project Name:
Project Number:
L2360570Lab Number:
Report Date:
Lab Duplicate Analysis
Batch Quality Control
10/20/23
Qual
Serial_No:10202317:02
Page 10 of 17
*Values in parentheses indicate holding time in days
L2360570-01A
L2360570-01B
L2360570-01C
L2360570-02A
L2360570-02B
L2360570-02C
L2360570-02D
L2360570-02E
L2360570-02F
L2360570-02G
L2360570-02H
Plastic 250ml H2SO4 preserved
Plastic 950ml unpreserved
Plastic 950ml unpreserved
Plastic 250ml H2SO4 preserved
Plastic 950ml unpreserved
Plastic 950ml unpreserved
Amber 1000ml HCl preserved
Amber 1000ml HCl preserved
Plastic 950ml unpreserved
Amber 1000ml HCl preserved
Amber 1000ml HCl preserved
A
A
A
A
A
A
A
A
A
A
A
<2
7
7
<2
7
7
NA
NA
7
<2
<2
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
2.8
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
A Absent
Cooler Custody Seal
Cooler Information
THE COVE @ YARMOUTH
K11494DA.S.WW.700
TKN-4500(28)
TSC-2540(7),NO2-353(2),NO3-353(2),BOD-
5210(2)
TSS-2540(7)
TKN-4500(28)
NO2-353(2),NO3-353(2),BOD-5210(2)
TSS-2540(7)
OG-1664(28)
OG-1664(28)
-
-
-
Project Name:
Project Number:
L2360570Lab Number:
Report Date:
Sample Receipt and Container Information
Container ID Container Type Cooler
Temp
deg C Pres Seal
Container Information
Analysis(*)
10/20/23
Were project specific reporting limits specified?YES
<2
7
7
<2
7
7
7
<2
<2
Frozen
Date/Time
Final
pH
Initial
pH
Serial_No:10202317:02
Page 11 of 17
Report Format:Data Usability Report
GLOSSARY
Project Name:
Project Number:
Lab Number:
Report Date:
L2360570THE COVE @ YARMOUTH
K11494DA.S.WW.700 10/20/23
Acronyms
DL
EDL
EMPC
EPA
LCS
LCSD
LFB
LOD
LOQ
MDL
MS
MSD
NA
NC
NDPA/DPA
NI
NP
NR
RL
RPD
SRM
STLP
TEF
TEQ
TIC
Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated values, when
those target analyte concentrations are quantified below the limit of quantitation (LOQ). The DL includes any adjustments
from dilutions, concentrations or moisture content, where applicable. (DoD report formats only.)
Estimated Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated
values, when those target analyte concentrations are quantified below the reporting limit (RL). The EDL includes any
adjustments from dilutions, concentrations or moisture content, where applicable. The use of EDLs is specific to the analysis
of PAHs using Solid-Phase Microextraction (SPME).
Estimated Maximum Possible Concentration: The concentration that results from the signal present at the retention time of an
analyte when the ions meet all of the identification criteria except the ion abundance ratio criteria. An EMPC is a worst-case
estimate of the concentration.
Environmental Protection Agency.
Laboratory Control Sample: A sample matrix, free from the analytes of interest, spiked with verified known amounts of
analytes or a material containing known and verified amounts of analytes.
Laboratory Control Sample Duplicate: Refer to LCS.
Laboratory Fortified Blank: A sample matrix, free from the analytes of interest, spiked with verified known amounts of
analytes or a material containing known and verified amounts of analytes.
Limit of Detection: This value represents the level to which a target analyte can reliably be detected for a specific analyte in a
specific matrix by a specific method. The LOD includes any adjustments from dilutions, concentrations or moisture content,
where applicable. (DoD report formats only.)
Limit of Quantitation: The value at which an instrument can accurately measure an analyte at a specific concentration. The
LOQ includes any adjustments from dilutions, concentrations or moisture content, where applicable. (DoD report formats
only.)
Limit of Quantitation: The value at which an instrument can accurately measure an analyte at a specific concentration. The
LOQ includes any adjustments from dilutions, concentrations or moisture content, where applicable. (DoD report formats
only.)
Method Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated
values, when those target analyte concentrations are quantified below the reporting limit (RL). The MDL includes any
adjustments from dilutions, concentrations or moisture content, where applicable.
Matrix Spike Sample: A sample prepared by adding a known mass of target analyte to a specified amount of matrix sample for
which an independent estimate of target analyte concentration is available. For Method 332.0, the spike recovery is calculated
using the native concentration, including estimated values.
Matrix Spike Sample Duplicate: Refer to MS.
Not Applicable.
Not Calculated: Term is utilized when one or more of the results utilized in the calculation are non-detect at the parameter's
reporting unit.
N-Nitrosodiphenylamine/Diphenylamine.
Not Ignitable.
Non-Plastic: Term is utilized for the analysis of Atterberg Limits in soil.
No Results: Term is utilized when 'No Target Compounds Requested' is reported for the analysis of Volatile or Semivolatile
Organic TIC only requests.
Reporting Limit: The value at which an instrument can accurately measure an analyte at a specific concentration. The RL
includes any adjustments from dilutions, concentrations or moisture content, where applicable.
Relative Percent Difference: The results from matrix and/or matrix spike duplicates are primarily designed to assess the
precision of analytical results in a given matrix and are expressed as relative percent difference (RPD). Values which are less
than five times the reporting limit for any individual parameter are evaluated by utilizing the absolute difference between the
values; although the RPD value will be provided in the report.
Standard Reference Material: A reference sample of a known or certified value that is of the same or similar matrix as the
associated field samples.
Semi-dynamic Tank Leaching Procedure per EPA Method 1315.
Toxic Equivalency Factors: The values assigned to each dioxin and furan to evaluate their toxicity relative to 2,3,7,8-TCDD.
Toxic Equivalent: The measure of a sample's toxicity derived by multiplying each dioxin and furan by its corresponding TEF
and then summing the resulting values.
Tentatively Identified Compound: A compound that has been identified to be present and is not part of the target compound
list (TCL) for the method and/or program. All TICs are qualitatively identified and reported as estimated concentrations.
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
Serial_No:10202317:02
Page 12 of 17
Report Format:Data Usability Report
Project Name:
Project Number:
Lab Number:
Report Date:
L2360570THE COVE @ YARMOUTH
K11494DA.S.WW.700 10/20/23
Terms
Analytical Method: Both the document from which the method originates and the analytical reference method. (Example: EPA 8260B is
shown as 1,8260B.) The codes for the reference method documents are provided in the References section of the Addendum.
Chlordane: The target compound Chlordane (CAS No. 57-74-9) is reported for GC ECD analyses. Per EPA,this compound "refers to a
mixture of chlordane isomers, other chlorinated hydrocarbons and numerous other components." (Reference: USEPA Toxicological Review
of Chlordane, In Support of Summary Information on the Integrated Risk Information System (IRIS), December 1997.)
Difference: With respect to Total Oxidizable Precursor (TOP) Assay analysis, the difference is defined as the Post-Treatment value minus the
Pre-Treatment value.
Final pH: As it pertains to Sample Receipt & Container Information section of the report, Final pH reflects pH of container determined after
adjustment at the laboratory, if applicable. If no adjustment required, value reflects Initial pH.
Frozen Date/Time: With respect to Volatile Organics in soil, Frozen Date/Time reflects the date/time at which associated Reagent Water-
preserved vials were initially frozen. Note: If frozen date/time is beyond 48 hours from sample collection, value will be reflected in 'bold'.
Gasoline Range Organics (GRO): Gasoline Range Organics (GRO) results include all chromatographic peaks eluting from Methyl tert butyl
ether through Naphthalene, with the exception of GRO analysis in support of State of Ohio programs, which includes all chromatographic
peaks eluting from Hexane through Dodecane.
Initial pH: As it pertains to Sample Receipt & Container Information section of the report, Initial pH reflects pH of container determined upon
receipt, if applicable.
PAH Total: With respect to Alkylated PAH analyses, the 'PAHs, Total' result is defined as the summation of results for all or a subset of the
following compounds: Naphthalene, C1-C4 Naphthalenes, 2-Methylnaphthalene, 1-Methylnaphthalene, Biphenyl, Acenaphthylene,
Acenaphthene, Fluorene, C1-C3 Fluorenes, Phenanthrene, C1-C4 Phenanthrenes/Anthracenes, Anthracene, Fluoranthene, Pyrene, C1-C4
Fluoranthenes/Pyrenes, Benz(a)anthracene, Chrysene, C1-C4 Chrysenes, Benzo(b)fluoranthene, Benzo(j)+(k)fluoranthene, Benzo(e)pyrene,
Benzo(a)pyrene, Perylene, Indeno(1,2,3-cd)pyrene, Dibenz(ah)+(ac)anthracene, Benzo(g,h,i)perylene. If a 'Total' result is requested, the
results of its individual components will also be reported.
PFAS Total: With respect to PFAS analyses, the 'PFAS, Total (5)' result is defined as the summation of results for: PFHpA, PFHxS, PFOA,
PFNA and PFOS. In addition, the 'PFAS, Total (6)' result is defined as the summation of results for: PFHpA, PFHxS, PFOA, PFNA, PFDA
and PFOS. For MassDEP DW compliance analysis only, the 'PFAS, Total (6)' result is defined as the summation of results at or above the
RL. Note: If a 'Total' result is requested, the results of its individual components will also be reported.
Total: With respect to Organic analyses, a 'Total' result is defined as the summation of results for individual isomers or Aroclors. If a 'Total'
result is requested, the results of its individual components will also be reported. This is applicable to 'Total' results for methods 8260, 8081
and 8082.
Data Qualifiers
A
B
C
D
E
F
G
H
I
J
M
-
-
-
-
-
-
-
-
-
-
-
Spectra identified as "Aldol Condensates" are byproducts of the extraction/concentration procedures when acetone is introduced in
the process.
The analyte was detected above the reporting limit in the associated method blank. Flag only applies to associated field samples that
have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank. For MCP-related
projects, flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x)
the concentration found in the blank. For DOD-related projects, flag only applies to associated field samples that have detectable
concentrations of the analyte at less than ten times (10x) the concentration found in the blank AND the analyte was detected above
one-half the reporting limit (or above the reporting limit for common lab contaminants) in the associated method blank. For NJ-
Air-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte above the
reporting limit. For NJ-related projects (excluding Air), flag only applies to associated field samples that have detectable
concentrations of the analyte, which was detected above the reporting limit in the associated method blank or above five times the
reporting limit for common lab contaminants (Phthalates, Acetone, Methylene Chloride, 2-Butanone).
Co-elution: The target analyte co-elutes with a known lab standard (i.e. surrogate, internal standards, etc.) for co-extracted
analyses.
Concentration of analyte was quantified from diluted analysis. Flag only applies to field samples that have detectable concentrations
of the analyte.
Concentration of analyte exceeds the range of the calibration curve and/or linear range of the instrument.
The ratio of quantifier ion response to qualifier ion response falls outside of the laboratory criteria. Results are considered to be an
estimated maximum concentration.
The concentration may be biased high due to matrix interferences (i.e, co-elution) with non-target compound(s). The result should
be considered estimated.
The analysis of pH was performed beyond the regulatory-required holding time of 15 minutes from the time of sample collection.
The lower value for the two columns has been reported due to obvious interference.
Estimated value. This represents an estimated concentration for Tentatively Identified Compounds (TICs).
Reporting Limit (RL) exceeds the MCP CAM Reporting Limit for this analyte.
1 The reference for this analyte should be considered modified since this analyte is absent from the target analyte list of the
original method.
-
Footnotes
Serial_No:10202317:02
Page 13 of 17
Report Format:Data Usability Report
Project Name:
Project Number:
Lab Number:
Report Date:
L2360570THE COVE @ YARMOUTH
K11494DA.S.WW.700 10/20/23
Data Qualifiers
ND
NJ
P
Q
R
RE
S
V
Z
-
-
-
-
-
-
-
-
-
Not detected at the reporting limit (RL) for the sample.
Presumptive evidence of compound. This represents an estimated concentration for Tentatively Identified Compounds (TICs), where
the identification is based on a mass spectral library search.
The RPD between the results for the two columns exceeds the method-specified criteria.
The quality control sample exceeds the associated acceptance criteria. For DOD-related projects, LCS and/or Continuing Calibration
Standard exceedences are also qualified on all associated sample results. Note: This flag is not applicable for matrix spike recoveries
when the sample concentration is greater than 4x the spike added or for batch duplicate RPD when the sample concentrations are less
than 5x the RL. (Metals only.)
Analytical results are from sample re-analysis.
Analytical results are from sample re-extraction.
Analytical results are from modified screening analysis.
The surrogate associated with this target analyte has a recovery outside the QC acceptance limits. (Applicable to MassDEP DW
Compliance samples only.)
The batch matrix spike and/or duplicate associated with this target analyte has a recovery/RPD outside the QC acceptance limits.
(Applicable to MassDEP DW Compliance samples only.)
Serial_No:10202317:02
Page 14 of 17
Alpha Analytical performs services with reasonable care and diligence normal to the analytical testing
laboratory industry. In the event of an error, the sole and exclusive responsibility of Alpha Analytical
shall be to re-perform the work at it's own expense. In no event shall Alpha Analytical be held liable
for any incidental, consequential or special damages, including but not limited to, damages in any way
connected with the use of, interpretation of, information or analysis provided by Alpha Analytical.
We strongly urge our clients to comply with EPA protocol regarding sample volume, preservation, cooling,
containers, sampling procedures, holding time and splitting of samples in the field.
LIMITATION OF LIABILITIES
44
121
140
Methods for the Determination of Inorganic Substances in Environmental Samples,
EPA/600/R-93/100, August 1993.
Standard Methods for the Examination of Water and Wastewater. APHA-AWWA-WEF.
Standard Methods Online.
Method 1664,Revision B: N-Hexane Extractable Material (HEM; Oil & Grease) and
Silica Gel Treated N-Hexane Extractable Material (SGT-HEM; Non-polar Material) by
Extraction and Gravimetry, EPA-821-R-10-001, February 2010.
Project Name:
Project Number:
Lab Number:
Report Date:
L2360570THE COVE @ YARMOUTH
K11494DA.S.WW.700
REFERENCES
10/20/23
Serial_No:10202317:02
Page 15 of 17
Alpha Analytical, Inc.ID No.:17873
Facility: Company-wide Revision 20
Department: Quality Assurance Published Date: 6/16/2023 4:52:28 PM
Title: Certificate/Approval Program Summary Page 1 of 1
Document Type: Form Pre-Qualtrax Document ID: 08-113
Certification Information
The following analytes are not included in our Primary NELAP Scope of Accreditation:
Westborough Facility
EPA 624.1: m/p-xylene, o-xylene, Naphthalene
EPA 625.1: alpha-Terpineol
EPA 8260D: NPW: 1,2,4,5-Tetramethylbenzene; 4-Ethyltoluene, Azobenzene; SCM: Iodomethane (methyl iodide), 1,2,4,5-Tetramethylbenzene; 4-
Ethyltoluene.
EPA 8270E: NPW: Dimethylnaphthalene,1,4-Diphenylhydrazine, alpha-Terpineol; SCM: Dimethylnaphthalene,1,4-Diphenylhydrazine.
SM4500: NPW: Amenable Cyanide; SCM: Total Phosphorus, TKN, NO2, NO3.
Mansfield Facility
SM 2540D: TSS.
EPA TO-15: Halothane, 2,4,4-Trimethyl-2-pentene, 2,4,4-Trimethyl-1-pentene, Thiophene, 2-Methylthiophene,
3-Methylthiophene, 2-Ethylthiophene, 1,2,3-Trimethylbenzene, Indan, Indene, 1,2,4,5-Tetramethylbenzene, Benzothiophene, 1-Methylnaphthalene.
Biological Tissue Matrix: EPA 3050B
The following analytes are included in our Massachusetts DEP Scope of Accreditation
Westborough Facility:
Drinking Water
EPA 300.0: Chloride, Nitrate-N, Fluoride, Sulfate; EPA 353.2: Nitrate-N, Nitrite-N; SM4500NO3-F: Nitrate-N, Nitrite-N; SM4500F-C, SM4500CN-CE,
EPA 180.1, SM2130B, SM4500Cl-D, SM2320B, SM2540C, SM4500H-B, SM4500NO2-B
EPA 524.2: THMs and VOCs; EPA 504.1: EDB, DBCP.
Microbiology: SM9215B; SM9223-P/A, SM9223B-Colilert-QT,SM9222D.
Non-Potable Water
SM4500H,B, EPA 120.1, SM2510B, SM2540C, SM2320B, SM4500CL-E, SM4500F-BC, SM4500NH3-BH: Ammonia-N and Kjeldahl-N, EPA 350.1:
Ammonia-N, LACHAT 10-107-06-1-B: Ammonia-N, EPA 351.1, SM4500NO3-F, EPA 353.2: Nitrate-N, SM4500P-E, SM4500P-B, E, SM4500SO4-E,
SM5220D, EPA 410.4, SM5210B, SM5310C, SM4500CL-D, EPA 1664, EPA 420.1, SM4500-CN-CE, SM2540D, EPA 300: Chloride, Sulfate, Nitrate.
EPA 624.1: Volatile Halocarbons & Aromatics,
EPA 608.3: Chlordane, Toxaphene, Aldrin, alpha-BHC, beta-BHC, gamma-BHC, delta-BHC, Dieldrin, DDD, DDE, DDT, Endosulfan I, Endosulfan II,
Endosulfan sulfate, Endrin, Endrin Aldehyde, Heptachlor, Heptachlor Epoxide, PCBs
EPA 625.1: SVOC (Acid/Base/Neutral Extractables).
Microbiology: SM9223B-Colilert-QT; Enterolert-QT, SM9221E, EPA 1600, EPA 1603, SM9222D.
Mansfield Facility:
Drinking Water
EPA 200.7: Al, Ba, Cd, Cr, Cu, Fe, Mn, Ni, Na, Ag, Ca, Zn. EPA 200.8: Al, Sb, As, Ba, Be, Cd, Cr, Cu, Pb, Mn, Ni, Se, Ag, TL, Zn. EPA 245.1 Hg.
EPA 522, EPA 537.1.
Non-Potable Water
EPA 200.7: Al, Sb, As, Be, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Ag, Na, Sr, TL, Ti, V, Zn.
EPA 200.8: Al, Sb, As, Be, Cd, Cr, Cu, Fe, Pb, Mn, Ni, K, Se, Ag, Na, TL, Zn.
EPA 245.1 Hg.
SM2340B
For a complete listing of analytes and methods, please contact your Alpha Project Manager.
Serial_No:10202317:02
Page 16 of 17
Serial_No:10202317:02
Page 17 of 17
L2364299
Bennett Environmental Associates
K11494DA.S.WW.700
THE COVE @ YARMOUTH
Client:
Project Name:
Project Number:
11/07/23
Eight Walkup Drive, Westborough, MA 01581-1019
Lab Number:
Report Date:
508-898-9220 (Fax) 508-898-9193 800-624-9220 - www.alphalab.com
1573 Main Street
Brewster, MA 02631
Samantha FarrenkopfATTN:
ANALYTICAL REPORT
Certifications & Approvals: MA (M-MA086), NH NELAP (2064), CT (PH-0826), IL (200077), IN (C-MA-03), KY (KY98045), ME (MA00086), MD
(348), NJ (MA935), NY (11148), NC (25700/666), OH (CL108), OR (MA-1316), PA (68-03671), RI (LAO00065), TX (T104704476), VT (VT-0935),
VA (460195), USDA (Permit #525-23-122-91930).
(508) 896-1706Phone:
The original project report/data package is held by Alpha Analytical. This report/data package is paginated and should be reproduced only in its
entirety. Alpha Analytical holds no responsibility for results and/or data that are not consistent with the original.
Serial_No:11072317:57
Page 1 of 16
L2364299-01
Alpha
Sample ID
EFFLUENT RESAMPLE
Client ID
YARMOUTH, MA
Sample
Location
THE COVE @ YARMOUTH
K11494DA.S.WW.700
Project Name:
Project Number:
Lab Number:
Report Date:
L2364299
11/07/23
10/30/23 09:00
Collection
Date/TimeMatrix Receive Date
WATER 10/30/23
Serial_No:11072317:57
Page 2 of 16
THE COVE @ YARMOUTH
K11494DA.S.WW.700
Project Name:
Project Number:
Lab Number:
Report Date:
L2364299
11/07/23
Case Narrative
I, the undersigned, attest under the pains and penalties of perjury that, to the best of my knowledge and
belief and based upon my personal inquiry of those responsible for providing the information contained
in this analytical report, such information is accurate and complete. This certificate of analysis is not
complete unless this page accompanies any and all pages of this report.
Authorized Signature:
Title: Technical Director/Representative Date: 11/07/23
The samples were received in accordance with the Chain of Custody and no significant deviations were encountered during the preparation
or analysis unless otherwise noted. Sample Receipt, Container Information, and the Chain of Custody are located at the back of the report.
Results contained within this report relate only to the samples submitted under this Alpha Lab Number and meet NELAP requirements for all
NELAP accredited parameters unless otherwise noted in the following narrative. The data presented in this report is organized by parameter
(i.e. VOC, SVOC, etc.). Sample specific Quality Control data (i.e. Surrogate Spike Recovery) is reported at the end of the target analyte list
for each individual sample, followed by the Laboratory Batch Quality Control at the end of each parameter. Tentatively Identified
Compounds (TICs), if requested, are reported for compounds identified to be present and are not part of the method/program Target
Compound List, even if only a subset of the TCL are being reported. If a sample was re-analyzed or re-extracted due to a required quality
control corrective action and if both sets of data are reported, the Laboratory ID of the re-analysis or re-extraction is designated with an "R"
or "RE", respectively.
When multiple Batch Quality Control elements are reported (e.g. more than one LCS), the associated samples for each element are noted in
the grey shaded header line of each data table. Any Laboratory Batch, Sample Specific % recovery or RPD value that is outside the listed
Acceptance Criteria is bolded in the report. In reference to questions H (CAM) or 4 (RCP) when "NO" is checked, the performance criteria
for CAM and RCP methods allow for some quality control failures to occur and still be within method compliance. In these instances, the
specific failure is not narrated but noted in the associated QC Outlier Summary Report, located directly after the Case Narrative. QC
information is also incorporated in the Data Usability Assessment table (Format 11) of our Data Merger tool, where it can be reviewed in
conjunction with the sample result, associated regulatory criteria and any associated data usability implications.
Soil/sediments, solids and tissues are reported on a dry weight basis unless otherwise noted. Definitions of all data qualifiers and acronyms
used in this report are provided in the Glossary located at the back of the report.
HOLD POLICY - For samples submitted on hold, Alpha's policy is to hold samples (with the exception of Air canisters) free of charge for 21
calendar days from the date the project is completed. After 21 calendar days, we will dispose of all samples submitted including those put
on hold unless you have contacted your Alpha Project Manager and made arrangements for Alpha to continue to hold the samples. Air
canisters will be disposed after 3 business days from the date the project is completed.
Please contact Project Management at 800-624-9220 with any questions.
Serial_No:11072317:57
Page 3 of 16
INORGANICS
&
MISCELLANEOUS
Serial_No:11072317:57
Page 4 of 16
FF
EFFLUENT RESAMPLEClient ID:
10/30/23 09:00Date Collected:
10/30/23Date Received:
Parameter Result
Dilution
Factor
Matrix:Water
YARMOUTH, MASample Location:
L2364299-01Lab ID:
Qualifier Units RL
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
THE COVE @ YARMOUTH
K11494DA.S.WW.700
L2364299
Field Prep:
Date
Analyzed
Analytical
Method Analyst
Not Specified
General Chemistry - Westborough Lab
Nitrogen, Nitrite
Nitrogen, Nitrate
Nitrogen, Total Kjeldahl
3.2
4.4
2.81
mg/l
mg/l
mg/l
1
1
1
0.050
0.10
0.300
11/01/23 01:07
11/01/23 01:07
11/03/23 18:52
44,353.2
44,353.2
121,4500NH3-H
MRM
MRM
AVT
Date
Prepared
-
-
11/01/23 19:57
11/07/23
MDL
--
--
--
Sample Depth:
Serial_No:11072317:57
Page 5 of 16
FF
Parameter Result
Dilution
FactorQualifierUnitsRL
Method Blank Analysis
Batch Quality Control
Project Name:
Project Number:
Lab Number:
Report Date:
THE COVE @ YARMOUTH
K11494DA.S.WW.700
L2364299
Date
Analyzed
Analytical
Method Analyst
Date
Prepared
11/07/23
Nitrogen, Nitrite
Nitrogen, Nitrate
Nitrogen, Total Kjeldahl
ND
ND
ND
mg/l
mg/l
mg/l
1
1
1
0.050
0.10
0.300
11/01/23 01:02
11/01/23 00:59
11/03/23 18:39
44,353.2
44,353.2
121,4500NH3-H
MRM
MRM
AVT
-
-
11/01/23 19:57
General Chemistry - Westborough Lab for sample(s): 01 Batch: WG1846707-1
General Chemistry - Westborough Lab for sample(s): 01 Batch: WG1846708-1
General Chemistry - Westborough Lab for sample(s): 01 Batch: WG1847069-1
MDL
--
--
--
Serial_No:11072317:57
Page 6 of 16
Nitrogen, Nitrite
Nitrogen, Nitrate
Nitrogen, Total Kjeldahl
96
96
102
-
-
-
90-110
90-110
78-122
-
-
-
20
Parameter
LCS
%Recovery
LCSD
%Recovery
%Recovery
Limits RPD RPD Limits
General Chemistry - Westborough Lab Associated sample(s): 01 Batch: WG1846707-2
General Chemistry - Westborough Lab Associated sample(s): 01 Batch: WG1846708-2
General Chemistry - Westborough Lab Associated sample(s): 01 Batch: WG1847069-2
Lab Control Sample Analysis
Batch Quality ControlProject Name:
Project Number:
Lab Number:
Report Date:
THE COVE @ YARMOUTH
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Qual Qual Qual
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Nitrogen, Nitrite
Nitrogen, Nitrate
Nitrogen, Total Kjeldahl
ND
ND
0.356
3.6
4.1
8.40
90
102
100
-
-
-
-
-
-
80-120
83-113
77-111
-
-
-
20
6
24
Parameter
Native
Sample
MS
Found
MS
%Recovery
MSD
Found
MSD
%Recovery
Recovery
Limits RPD
RPD
Limits
General Chemistry - Westborough Lab Associated sample(s): 01 QC Batch ID: WG1846707-4 QC Sample: L2364428-01 Client ID: MS Sample
General Chemistry - Westborough Lab Associated sample(s): 01 QC Batch ID: WG1846708-4 QC Sample: L2364428-01 Client ID: MS Sample
General Chemistry - Westborough Lab Associated sample(s): 01 QC Batch ID: WG1847069-4 QC Sample: L2364219-01 Client ID: MS Sample
4
4
8
MS
Added
Matrix Spike Analysis
Batch Quality ControlProject Name:
Project Number:
Lab Number:
Report Date:
THE COVE @ YARMOUTH
K11494DA.S.WW.700
L2364299
11/07/23
Qual Qual Qual
Serial_No:11072317:57
Page 8 of 16
Nitrogen, Nitrite
Nitrogen, Nitrate
Nitrogen, Total Kjeldahl
ND
ND
0.356
ND
ND
0.563
mg/l
mg/l
mg/l
NC
NC
45
20
6
24
Units RPDParameterNative Sample Duplicate Sample RPD Limits
General Chemistry - Westborough Lab Associated sample(s): 01 QC Batch ID: WG1846707-3 QC Sample: L2364428-01 Client ID: DUP Sample
General Chemistry - Westborough Lab Associated sample(s): 01 QC Batch ID: WG1846708-3 QC Sample: L2364428-01 Client ID: DUP Sample
General Chemistry - Westborough Lab Associated sample(s): 01 QC Batch ID: WG1847069-3 QC Sample: L2364219-01 Client ID: DUP Sample
THE COVE @ YARMOUTH
K11494DA.S.WW.700
Project Name:
Project Number:
L2364299Lab Number:
Report Date:
Lab Duplicate Analysis
Batch Quality Control
11/07/23
Qual
Q
Serial_No:11072317:57
Page 9 of 16
*Values in parentheses indicate holding time in days
L2364299-01A
L2364299-01B
Plastic 120ml unpreserved
Plastic 250ml H2SO4 preserved
A
A
7
<2
4.0
4.0
Y
Y
Absent
Absent
A Absent
Cooler Custody Seal
Cooler Information
THE COVE @ YARMOUTH
K11494DA.S.WW.700
NO2-353(2),NO3-353(2)
TKN-4500(28)
Project Name:
Project Number:
L2364299Lab Number:
Report Date:
Sample Receipt and Container Information
Container ID Container Type Cooler
Temp
deg C Pres Seal
Container Information
Analysis(*)
11/07/23
Were project specific reporting limits specified?YES
7
<2
Frozen
Date/Time
Final
pH
Initial
pH
Serial_No:11072317:57
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Report Format:Data Usability Report
GLOSSARY
Project Name:
Project Number:
Lab Number:
Report Date:
L2364299THE COVE @ YARMOUTH
K11494DA.S.WW.700 11/07/23
Acronyms
DL
EDL
EMPC
EPA
LCS
LCSD
LFB
LOD
LOQ
MDL
MS
MSD
NA
NC
NDPA/DPA
NI
NP
NR
RL
RPD
SRM
STLP
TEF
TEQ
TIC
Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated values, when
those target analyte concentrations are quantified below the limit of quantitation (LOQ). The DL includes any adjustments
from dilutions, concentrations or moisture content, where applicable. (DoD report formats only.)
Estimated Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated
values, when those target analyte concentrations are quantified below the reporting limit (RL). The EDL includes any
adjustments from dilutions, concentrations or moisture content, where applicable. The use of EDLs is specific to the analysis
of PAHs using Solid-Phase Microextraction (SPME).
Estimated Maximum Possible Concentration: The concentration that results from the signal present at the retention time of an
analyte when the ions meet all of the identification criteria except the ion abundance ratio criteria. An EMPC is a worst-case
estimate of the concentration.
Environmental Protection Agency.
Laboratory Control Sample: A sample matrix, free from the analytes of interest, spiked with verified known amounts of
analytes or a material containing known and verified amounts of analytes.
Laboratory Control Sample Duplicate: Refer to LCS.
Laboratory Fortified Blank: A sample matrix, free from the analytes of interest, spiked with verified known amounts of
analytes or a material containing known and verified amounts of analytes.
Limit of Detection: This value represents the level to which a target analyte can reliably be detected for a specific analyte in a
specific matrix by a specific method. The LOD includes any adjustments from dilutions, concentrations or moisture content,
where applicable. (DoD report formats only.)
Limit of Quantitation: The value at which an instrument can accurately measure an analyte at a specific concentration. The
LOQ includes any adjustments from dilutions, concentrations or moisture content, where applicable. (DoD report formats
only.)
Limit of Quantitation: The value at which an instrument can accurately measure an analyte at a specific concentration. The
LOQ includes any adjustments from dilutions, concentrations or moisture content, where applicable. (DoD report formats
only.)
Method Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated
values, when those target analyte concentrations are quantified below the reporting limit (RL). The MDL includes any
adjustments from dilutions, concentrations or moisture content, where applicable.
Matrix Spike Sample: A sample prepared by adding a known mass of target analyte to a specified amount of matrix sample for
which an independent estimate of target analyte concentration is available. For Method 332.0, the spike recovery is calculated
using the native concentration, including estimated values.
Matrix Spike Sample Duplicate: Refer to MS.
Not Applicable.
Not Calculated: Term is utilized when one or more of the results utilized in the calculation are non-detect at the parameter's
reporting unit.
N-Nitrosodiphenylamine/Diphenylamine.
Not Ignitable.
Non-Plastic: Term is utilized for the analysis of Atterberg Limits in soil.
No Results: Term is utilized when 'No Target Compounds Requested' is reported for the analysis of Volatile or Semivolatile
Organic TIC only requests.
Reporting Limit: The value at which an instrument can accurately measure an analyte at a specific concentration. The RL
includes any adjustments from dilutions, concentrations or moisture content, where applicable.
Relative Percent Difference: The results from matrix and/or matrix spike duplicates are primarily designed to assess the
precision of analytical results in a given matrix and are expressed as relative percent difference (RPD). Values which are less
than five times the reporting limit for any individual parameter are evaluated by utilizing the absolute difference between the
values; although the RPD value will be provided in the report.
Standard Reference Material: A reference sample of a known or certified value that is of the same or similar matrix as the
associated field samples.
Semi-dynamic Tank Leaching Procedure per EPA Method 1315.
Toxic Equivalency Factors: The values assigned to each dioxin and furan to evaluate their toxicity relative to 2,3,7,8-TCDD.
Toxic Equivalent: The measure of a sample's toxicity derived by multiplying each dioxin and furan by its corresponding TEF
and then summing the resulting values.
Tentatively Identified Compound: A compound that has been identified to be present and is not part of the target compound
list (TCL) for the method and/or program. All TICs are qualitatively identified and reported as estimated concentrations.
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
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Report Format:Data Usability Report
Project Name:
Project Number:
Lab Number:
Report Date:
L2364299THE COVE @ YARMOUTH
K11494DA.S.WW.700 11/07/23
Terms
Analytical Method: Both the document from which the method originates and the analytical reference method. (Example: EPA 8260B is
shown as 1,8260B.) The codes for the reference method documents are provided in the References section of the Addendum.
Chlordane: The target compound Chlordane (CAS No. 57-74-9) is reported for GC ECD analyses. Per EPA,this compound "refers to a
mixture of chlordane isomers, other chlorinated hydrocarbons and numerous other components." (Reference: USEPA Toxicological Review
of Chlordane, In Support of Summary Information on the Integrated Risk Information System (IRIS), December 1997.)
Difference: With respect to Total Oxidizable Precursor (TOP) Assay analysis, the difference is defined as the Post-Treatment value minus the
Pre-Treatment value.
Final pH: As it pertains to Sample Receipt & Container Information section of the report, Final pH reflects pH of container determined after
adjustment at the laboratory, if applicable. If no adjustment required, value reflects Initial pH.
Frozen Date/Time: With respect to Volatile Organics in soil, Frozen Date/Time reflects the date/time at which associated Reagent Water-
preserved vials were initially frozen. Note: If frozen date/time is beyond 48 hours from sample collection, value will be reflected in 'bold'.
Gasoline Range Organics (GRO): Gasoline Range Organics (GRO) results include all chromatographic peaks eluting from Methyl tert butyl
ether through Naphthalene, with the exception of GRO analysis in support of State of Ohio programs, which includes all chromatographic
peaks eluting from Hexane through Dodecane.
Initial pH: As it pertains to Sample Receipt & Container Information section of the report, Initial pH reflects pH of container determined upon
receipt, if applicable.
PAH Total: With respect to Alkylated PAH analyses, the 'PAHs, Total' result is defined as the summation of results for all or a subset of the
following compounds: Naphthalene, C1-C4 Naphthalenes, 2-Methylnaphthalene, 1-Methylnaphthalene, Biphenyl, Acenaphthylene,
Acenaphthene, Fluorene, C1-C3 Fluorenes, Phenanthrene, C1-C4 Phenanthrenes/Anthracenes, Anthracene, Fluoranthene, Pyrene, C1-C4
Fluoranthenes/Pyrenes, Benz(a)anthracene, Chrysene, C1-C4 Chrysenes, Benzo(b)fluoranthene, Benzo(j)+(k)fluoranthene, Benzo(e)pyrene,
Benzo(a)pyrene, Perylene, Indeno(1,2,3-cd)pyrene, Dibenz(ah)+(ac)anthracene, Benzo(g,h,i)perylene. If a 'Total' result is requested, the
results of its individual components will also be reported.
PFAS Total: With respect to PFAS analyses, the 'PFAS, Total (5)' result is defined as the summation of results for: PFHpA, PFHxS, PFOA,
PFNA and PFOS. In addition, the 'PFAS, Total (6)' result is defined as the summation of results for: PFHpA, PFHxS, PFOA, PFNA, PFDA
and PFOS. For MassDEP DW compliance analysis only, the 'PFAS, Total (6)' result is defined as the summation of results at or above the
RL. Note: If a 'Total' result is requested, the results of its individual components will also be reported.
Total: With respect to Organic analyses, a 'Total' result is defined as the summation of results for individual isomers or Aroclors. If a 'Total'
result is requested, the results of its individual components will also be reported. This is applicable to 'Total' results for methods 8260, 8081
and 8082.
Data Qualifiers
A
B
C
D
E
F
G
H
I
J
M
-
-
-
-
-
-
-
-
-
-
-
Spectra identified as "Aldol Condensates" are byproducts of the extraction/concentration procedures when acetone is introduced in
the process.
The analyte was detected above the reporting limit in the associated method blank. Flag only applies to associated field samples that
have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank. For MCP-related
projects, flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x)
the concentration found in the blank. For DOD-related projects, flag only applies to associated field samples that have detectable
concentrations of the analyte at less than ten times (10x) the concentration found in the blank AND the analyte was detected above
one-half the reporting limit (or above the reporting limit for common lab contaminants) in the associated method blank. For NJ-
Air-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte above the
reporting limit. For NJ-related projects (excluding Air), flag only applies to associated field samples that have detectable
concentrations of the analyte, which was detected above the reporting limit in the associated method blank or above five times the
reporting limit for common lab contaminants (Phthalates, Acetone, Methylene Chloride, 2-Butanone).
Co-elution: The target analyte co-elutes with a known lab standard (i.e. surrogate, internal standards, etc.) for co-extracted
analyses.
Concentration of analyte was quantified from diluted analysis. Flag only applies to field samples that have detectable concentrations
of the analyte.
Concentration of analyte exceeds the range of the calibration curve and/or linear range of the instrument.
The ratio of quantifier ion response to qualifier ion response falls outside of the laboratory criteria. Results are considered to be an
estimated maximum concentration.
The concentration may be biased high due to matrix interferences (i.e, co-elution) with non-target compound(s). The result should
be considered estimated.
The analysis of pH was performed beyond the regulatory-required holding time of 15 minutes from the time of sample collection.
The lower value for the two columns has been reported due to obvious interference.
Estimated value. This represents an estimated concentration for Tentatively Identified Compounds (TICs).
Reporting Limit (RL) exceeds the MCP CAM Reporting Limit for this analyte.
1 The reference for this analyte should be considered modified since this analyte is absent from the target analyte list of the
original method.
-
Footnotes
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Report Format:Data Usability Report
Project Name:
Project Number:
Lab Number:
Report Date:
L2364299THE COVE @ YARMOUTH
K11494DA.S.WW.700 11/07/23
Data Qualifiers
ND
NJ
P
Q
R
RE
S
V
Z
-
-
-
-
-
-
-
-
-
Not detected at the reporting limit (RL) for the sample.
Presumptive evidence of compound. This represents an estimated concentration for Tentatively Identified Compounds (TICs), where
the identification is based on a mass spectral library search.
The RPD between the results for the two columns exceeds the method-specified criteria.
The quality control sample exceeds the associated acceptance criteria. For DOD-related projects, LCS and/or Continuing Calibration
Standard exceedences are also qualified on all associated sample results. Note: This flag is not applicable for matrix spike recoveries
when the sample concentration is greater than 4x the spike added or for batch duplicate RPD when the sample concentrations are less
than 5x the RL. (Metals only.)
Analytical results are from sample re-analysis.
Analytical results are from sample re-extraction.
Analytical results are from modified screening analysis.
The surrogate associated with this target analyte has a recovery outside the QC acceptance limits. (Applicable to MassDEP DW
Compliance samples only.)
The batch matrix spike and/or duplicate associated with this target analyte has a recovery/RPD outside the QC acceptance limits.
(Applicable to MassDEP DW Compliance samples only.)
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Page 13 of 16
Alpha Analytical performs services with reasonable care and diligence normal to the analytical testing
laboratory industry. In the event of an error, the sole and exclusive responsibility of Alpha Analytical
shall be to re-perform the work at it's own expense. In no event shall Alpha Analytical be held liable
for any incidental, consequential or special damages, including but not limited to, damages in any way
connected with the use of, interpretation of, information or analysis provided by Alpha Analytical.
We strongly urge our clients to comply with EPA protocol regarding sample volume, preservation, cooling,
containers, sampling procedures, holding time and splitting of samples in the field.
LIMITATION OF LIABILITIES
44
121
Methods for the Determination of Inorganic Substances in Environmental Samples,
EPA/600/R-93/100, August 1993.
Standard Methods for the Examination of Water and Wastewater. APHA-AWWA-WEF.
Standard Methods Online.
Project Name:
Project Number:
Lab Number:
Report Date:
L2364299THE COVE @ YARMOUTH
K11494DA.S.WW.700
REFERENCES
11/07/23
Serial_No:11072317:57
Page 14 of 16
Alpha Analytical, Inc.ID No.:17873
Facility: Company-wide Revision 20
Department: Quality Assurance Published Date: 6/16/2023 4:52:28 PM
Title: Certificate/Approval Program Summary Page 1 of 1
Document Type: Form Pre-Qualtrax Document ID: 08-113
Certification Information
The following analytes are not included in our Primary NELAP Scope of Accreditation:
Westborough Facility
EPA 624.1: m/p-xylene, o-xylene, Naphthalene
EPA 625.1: alpha-Terpineol
EPA 8260D: NPW: 1,2,4,5-Tetramethylbenzene; 4-Ethyltoluene, Azobenzene; SCM: Iodomethane (methyl iodide), 1,2,4,5-Tetramethylbenzene; 4-
Ethyltoluene.
EPA 8270E: NPW: Dimethylnaphthalene,1,4-Diphenylhydrazine, alpha-Terpineol; SCM: Dimethylnaphthalene,1,4-Diphenylhydrazine.
SM4500: NPW: Amenable Cyanide; SCM: Total Phosphorus, TKN, NO2, NO3.
Mansfield Facility
SM 2540D: TSS.
EPA TO-15: Halothane, 2,4,4-Trimethyl-2-pentene, 2,4,4-Trimethyl-1-pentene, Thiophene, 2-Methylthiophene,
3-Methylthiophene, 2-Ethylthiophene, 1,2,3-Trimethylbenzene, Indan, Indene, 1,2,4,5-Tetramethylbenzene, Benzothiophene, 1-Methylnaphthalene.
Biological Tissue Matrix: EPA 3050B
The following analytes are included in our Massachusetts DEP Scope of Accreditation
Westborough Facility:
Drinking Water
EPA 300.0: Chloride, Nitrate-N, Fluoride, Sulfate; EPA 353.2: Nitrate-N, Nitrite-N; SM4500NO3-F: Nitrate-N, Nitrite-N; SM4500F-C, SM4500CN-CE,
EPA 180.1, SM2130B, SM4500Cl-D, SM2320B, SM2540C, SM4500H-B, SM4500NO2-B
EPA 524.2: THMs and VOCs; EPA 504.1: EDB, DBCP.
Microbiology: SM9215B; SM9223-P/A, SM9223B-Colilert-QT,SM9222D.
Non-Potable Water
SM4500H,B, EPA 120.1, SM2510B, SM2540C, SM2320B, SM4500CL-E, SM4500F-BC, SM4500NH3-BH: Ammonia-N and Kjeldahl-N, EPA 350.1:
Ammonia-N, LACHAT 10-107-06-1-B: Ammonia-N, EPA 351.1, SM4500NO3-F, EPA 353.2: Nitrate-N, SM4500P-E, SM4500P-B, E, SM4500SO4-E,
SM5220D, EPA 410.4, SM5210B, SM5310C, SM4500CL-D, EPA 1664, EPA 420.1, SM4500-CN-CE, SM2540D, EPA 300: Chloride, Sulfate, Nitrate.
EPA 624.1: Volatile Halocarbons & Aromatics,
EPA 608.3: Chlordane, Toxaphene, Aldrin, alpha-BHC, beta-BHC, gamma-BHC, delta-BHC, Dieldrin, DDD, DDE, DDT, Endosulfan I, Endosulfan II,
Endosulfan sulfate, Endrin, Endrin Aldehyde, Heptachlor, Heptachlor Epoxide, PCBs
EPA 625.1: SVOC (Acid/Base/Neutral Extractables).
Microbiology: SM9223B-Colilert-QT; Enterolert-QT, SM9221E, EPA 1600, EPA 1603, SM9222D.
Mansfield Facility:
Drinking Water
EPA 200.7: Al, Ba, Cd, Cr, Cu, Fe, Mn, Ni, Na, Ag, Ca, Zn. EPA 200.8: Al, Sb, As, Ba, Be, Cd, Cr, Cu, Pb, Mn, Ni, Se, Ag, TL, Zn. EPA 245.1 Hg.
EPA 522, EPA 537.1.
Non-Potable Water
EPA 200.7: Al, Sb, As, Be, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Ag, Na, Sr, TL, Ti, V, Zn.
EPA 200.8: Al, Sb, As, Be, Cd, Cr, Cu, Fe, Pb, Mn, Ni, K, Se, Ag, Na, TL, Zn.
EPA 245.1 Hg.
SM2340B
For a complete listing of analytes and methods, please contact your Alpha Project Manager.
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