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Home My WebLink AboutDMR Filing 03 2024 11494Massachusetts Department of Environmental Protection eDEP Transaction Copy Here is the file you requested for your records. To retain a copy of this file you must save and/or print. Username: Transaction ID: Document: Size of File: Status of Transaction: Date and Time Created: Note: This file only includes forms that were part of your transaction as of the date and time indicated above. If you need a more current copy of your transaction, return to eDEP and select to “Download a Copy” from the Current Submittals page. 1711993 4/22/2024:1:55:55 PM 1077.47K SFARRENKOPF Groundwater Discharge Monitoring Report Forms In Process Important:When filling out forms on the computer, use only the tab key to move your cursor do not use the return key. A. Facility Information 1. Facility name, address: THE COVE RESORT HOTEL a. Name 183 MAIN STREET/RTE. 28 b. Street Address YARMOUTH MA 02673 c. City d. State e. Zip Code 2. Contact information: BRIAN FORTIN a. Name of Facility Contact Person 7742302911 bfortin@NSUWater.com b. Telephone Number c. email address 3. Sampling information: 3/1/2024 NOT APPLICABLE a. Date Sampled (mm/dd/yyyy)b. Laboratory Name BEA/NSU PERSONNEL c. Analysis Performed By (Name) B. Form Selection 1. Please select Form Type and Sampling Month & Frequency Daily Log Sheet 2024 Mar Daily All forms for submittal have been completed. 2.This is the last selection. 3.Delete the selected form. gdpdls 20150915.doc • rev. 09/15/15 Groundwater Permit Daily Log Sheet • Page 1 of 1 Massachusetts Department of Environmental Protection Bureau of Resource Protection Groundwater Discharge Program Groundwater Permit DAILY LOG SHEET 162 1. Permit Number 042969095 2. Tax identification Number 2024 MAR DAILY 3. Sampling Month & Frequency C. Daily Readings/Analysis Information Date Effluent Flow GPD Reuse Flow GPD Irrigation Flow GPD Turbidity Influent pH Effluent pH Chlorine Residual (mg/l) UV Intensity (%) 1 15887 7.7 7.2 2 15887 3 15887 4 10379 7.7 7.5 5 10290 7.8 7.6 6 15060 7.9 7.6 7 11546 7.8 7.6 8 18241 7.8 7.7 9 18241 10 18241 11 13910 7.5 7.6 12 10900 7.6 7.5 13 11964 7.5 7.5 14 12768 7.7 7.7 15 17251 7.8 7.6 16 17251 17 17251 18 11524 7.6 7.5 19 13194 7.7 7.6 20 11143 7.8 7.6 21 12449 7.7 7.6 22 18436 7.6 7.5 23 18436 24 18436 25 13371 7.5 7.3 26 9483 7.6 7.6 27 11757 7.1 7.3 28 15852 7.2 7.4 29 15564 7.4 7.5 30 15564 31 15564 gdpdls.doc • rev. 09/15/15 Groundwater Permit Daily Log Sheet • Page 1 of 1 Massachusetts Department of Environmental Protection Bureau of Resource Protection Groundwater Discharge Program Groundwater Permit DAILY LOG SHEET 162 1. Permit Number 042969095 2. Tax identification Number 2024 MAR DAILY 3. Sampling Month & Frequency Important:When filling out forms on the computer, use only the tab key to move your cursor do not use the return key. A. Facility Information 1. Facility name, address: THE COVE RESORT HOTEL a. Name 183 MAIN STREET/RTE. 28 b. Street Address YARMOUTH MA 02673 c. City d. State e. Zip Code 2. Contact information: BRIAN FORTIN a. Name of Facility Contact Person 7742302911 bfortin@NSUWater.com b. Telephone Number c. email address 3. Sampling information: 3/7/2024 ALPHA ANALYTICAL a. Date Sampled (mm/dd/yyyy)b. Laboratory Name ALPHA ANALYTICAL PERSONNEL c. Analysis Performed By (Name) B. Form Selection 1. Please select Form Type and Sampling Month & Frequency Discharge Monitoring Report 2024 Mar Monthly All forms for submittal have been completed. 2.This is the last selection. 3.Delete the selected form. gdpdls 20150915.doc • rev. 09/15/15 Groundwater Permit Daily Log Sheet • Page 1 of 1 Massachusetts Department of Environmental Protection Bureau of Resource Protection Groundwater Discharge Program Groundwater Permit DISCHARGE MONITORING REPORT 162 1. Permit Number 042969095 2. Tax identification Number 2024 MAR MONTHLY 3. Sampling Month & Frequency D. Contaminant Analysis Information For "0", below detection limit, less than (<) value, or not detected, enter "ND" TNTC = too numerous to count. (Fecal results only) NS = Not Sampled 1. Parameter/Contaminant 2. Influent 3. Effluent 4. Effluent Method Units Detection limit BOD 50 25 5.0 MG/L TSS 54 27 10 MG/L TOTAL SOLIDS 420 MG/L NITRATEN ND 0.10 MG/L TOTAL NITROGEN(NO3+NO2+TKN)19.40 6.35 0.050 MG/L OIL & GREASE ND 4.0 MG/L infeffrpblank.doc • rev. 09/15/15 Groundwater Permit Discharge Monitoring Report • Page 1 of 1 Massachusetts Department of Environmental Protection Bureau of Resource Protection Groundwater Discharge Program Groundwater Permit DISCHARGE MONITORING REPORT 162 1. Permit Number 042969095 2. Tax identification Number 2024 MAR MONTHLY 3. Sampling Month & Frequency Important:When filling out forms on the computer, use only the tab key to move your cursor do not use the return key. A. Facility Information 1. Facility name, address: THE COVE RESORT HOTEL a. Name 183 MAIN STREET/RTE. 28 b. Street Address YARMOUTH MA 02673 c. City d. State e. Zip Code 2. Contact information: BRIAN FORTIN a. Name of Facility Contact Person 7742302911 bfortin@NSUWater.com b. Telephone Number c. email address 3. Sampling information: 3/13/2024 NOT APPLICABLE a. Date Sampled (mm/dd/yyyy)b. Laboratory Name BEA/NSU PERSONNEL c. Analysis Performed By (Name) B. Form Selection 1. Please select Form Type and Sampling Month & Frequency Monitoring Well Data Report 2024 Mar Monthly All forms for submittal have been completed. 2.This is the last selection. 3.Delete the selected form. gdpdls 20150915.doc • rev. 09/15/15 Groundwater Permit Daily Log Sheet • Page 1 of 1 Massachusetts Department of Environmental Protection Bureau of Resource Protection Groundwater Discharge Program Groundwater Permit MONITORING WELL DATA REPORT 162 1. Permit Number 042969095 2. Tax identification Number 2024 MAR MONTHLY 3. Sampling Month & Frequency C. Contaminant Analysis Information For "0", below detection limit, less than (<) value, or not detected, enter "ND" TNTC = too numerous to count. (Fecal results only) NS = Not Sampled DRY = Not enough water in well to sample. < Parameter/Contaminant 4A 5 6A 7A Units Well #: 1 Well #: 2 Well #: 3 Well #: 4 Well #: 5 Well #: 6 PH 6.27 6.63 6.94 6.34 S.U. STATIC WATER LEVEL NS NS NS NS FEET SPECIFIC CONDUCTANCE 259 269 966 413 UMHOS/C mwdgwpblank.doc • rev. 09/15/15 Monitoring Well Data for Groundwater Permit • Page 1 of 1 Massachusetts Department of Environmental Protection Bureau of Resource Protection Groundwater Discharge Program Groundwater Permit MONITORING WELL DATA REPORT 162 1. Permit Number 042969095 2. Tax identification Number 2024 MAR MONTHLY 3. Sampling Month & Frequency Important:When filling out forms on the computer, use only the tab key to move your cursor do not use the return key. Any person signing a document under 314 CMR 5.14(1) or (2) shall make the following certification If you are filing electronically and want to attach additional comments, select the check box. Facility Information THE COVE RESORT HOTEL a. Name 183 MAIN STREET/RTE. 28 b. Street Address YARMOUTH MA 02673 c. City d. State e. Zip Code Certification “I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.” SAMANTHA FARRENKOPF 4/22/2024 a. Signature b. Date (mm/dd/yyyy) Reporting Package Comments BENNETT ENVIRONMENTAL ASSOCIATES, LLC. (BEA) HAS COMPLETED THE MARCH 2024 OPERATION OF THE RBC WASTEWATER TREATMENT SYSTEM. MONTHLY WASTEWATER SAMPLING WAS COMPLETED ON 3/7/24. LABORATORY ANALYSIS REPORTED ALL PARAMETERS WITHIN PERMIT LIMITS. EFFLUENT PH WAS REPORTED WITHIN THE 6.58.5 RANGE THROUGHOUT THE MONTH. DAILY FLOW WAS RECORDED BELOW THE 39,900 GPD LIMITATION THROUGHOUT THE MONTH. THE MINIMUM, MAXIMUM, AND AVERAGE GPD FLOWS REPORTED WERE 9,483 GPD, 18,436 GPD, AND 14,572 GPD, RESPECTIVELY. STATIC WATER LEVEL WAS UNABLE TO BE REPORTED FOR MONTHLY GROUNDWATER MONITORING, AS THE FORMER OPERATOR WAS NOT IN POSSESSION OF TOP OF CASING ELEVATION DATA FOR ONSITE MONITORING WELLS, AND THAT INFORMATION WAS ADDITIONALLY NOT ABLE TO BE IDENTIFIED THROUGH RESEARCH OF EXISTING FACILITY DOCUMENTATION. A SURVEYOR WAS CONTRACTED TO COMPLETE A TOP OF CASING ELEVATION SURVEY, WITH COMPLETION OF THAT WORK PENDING AT THE TIME OF THIS REPORTING. GROUNDWATER MONITORING WAS CONDUCTED AND DEPTH TO WATER RECORDED AS REQUIRED. ONCE THE ELEVATION DATA IS AVAILABLE, ANY MISSING STATIC WATER LEVEL DATA WILL BE CALCULATED AND REPORTED. gdpdls 20150915.doc • rev. 09/15/15 Groundwater Permit • Page 1 of 1 Massachusetts Department of Environmental Protection Bureau of Resource Protection Groundwater Discharge Program Groundwater Permit 162 1. Permit Number 042969095 2. Tax identification Number L2412533 Bennett Environmental Associates K11494DA.S.WW.700 THE COVE @ YARMOUTH Client: Project Name: Project Number: 03/14/24 Eight Walkup Drive, Westborough, MA 01581-1019 Lab Number: Report Date: 508-898-9220 (Fax) 508-898-9193 800-624-9220 - www.alphalab.com 1573 Main Street Brewster, MA 02631 Samantha FarrenkopfATTN: ANALYTICAL REPORT Certifications & Approvals: MA (M-MA086), NH NELAP (2064), CT (PH-0826), IL (200077), IN (C-MA-03), KY (KY98045), ME (MA00086), MD (348), NJ (MA935), NY (11148), NC (25700/666), OH (CL108), OR (MA-1316), PA (68-03671), RI (LAO00065), TX (T104704476), VT (VT-0935), VA (460195), USDA (Permit #525-23-122-91930). (508) 896-1706Phone: The original project report/data package is held by Alpha Analytical. This report/data package is paginated and should be reproduced only in its entirety. Alpha Analytical holds no responsibility for results and/or data that are not consistent with the original. Serial_No:03142412:29 Page 1 of 17 L2412533-01 L2412533-02 Alpha Sample ID INFLUENT EFFLUENT Client ID YARMOUTH, MA YARMOUTH, MA Sample Location THE COVE @ YARMOUTH K11494DA.S.WW.700 Project Name: Project Number: Lab Number: Report Date: L2412533 03/14/24 03/07/24 10:15 03/07/24 10:15 Collection Date/TimeMatrix Receive Date WATER WATER 03/07/24 03/07/24 Serial_No:03142412:29 Page 2 of 17 THE COVE @ YARMOUTH K11494DA.S.WW.700 Project Name: Project Number: Lab Number: Report Date: L2412533 03/14/24 Case Narrative I, the undersigned, attest under the pains and penalties of perjury that, to the best of my knowledge and belief and based upon my personal inquiry of those responsible for providing the information contained in this analytical report, such information is accurate and complete. This certificate of analysis is not complete unless this page accompanies any and all pages of this report. Authorized Signature: Title: Technical Director/Representative Date: 03/14/24 The samples were received in accordance with the Chain of Custody and no significant deviations were encountered during the preparation or analysis unless otherwise noted. Sample Receipt, Container Information, and the Chain of Custody are located at the back of the report. Results contained within this report relate only to the samples submitted under this Alpha Lab Number and meet NELAP requirements for all NELAP accredited parameters unless otherwise noted in the following narrative. The data presented in this report is organized by parameter (i.e. VOC, SVOC, etc.). Sample specific Quality Control data (i.e. Surrogate Spike Recovery) is reported at the end of the target analyte list for each individual sample, followed by the Laboratory Batch Quality Control at the end of each parameter. Tentatively Identified Compounds (TICs), if requested, are reported for compounds identified to be present and are not part of the method/program Target Compound List, even if only a subset of the TCL are being reported. If a sample was re-analyzed or re-extracted due to a required quality control corrective action and if both sets of data are reported, the Laboratory ID of the re-analysis or re-extraction is designated with an "R" or "RE", respectively. When multiple Batch Quality Control elements are reported (e.g. more than one LCS), the associated samples for each element are noted in the grey shaded header line of each data table. Any Laboratory Batch, Sample Specific % recovery or RPD value that is outside the listed Acceptance Criteria is bolded in the report. In reference to questions H (CAM) or 4 (RCP) when "NO" is checked, the performance criteria for CAM and RCP methods allow for some quality control failures to occur and still be within method compliance. In these instances, the specific failure is not narrated but noted in the associated QC Outlier Summary Report, located directly after the Case Narrative. QC information is also incorporated in the Data Usability Assessment table (Format 11) of our Data Merger tool, where it can be reviewed in conjunction with the sample result, associated regulatory criteria and any associated data usability implications. Soil/sediments, solids and tissues are reported on a dry weight basis unless otherwise noted. Definitions of all data qualifiers and acronyms used in this report are provided in the Glossary located at the back of the report. HOLD POLICY - For samples submitted on hold, Alpha's policy is to hold samples (with the exception of Air canisters) free of charge for 21 calendar days from the date the project is completed. After 21 calendar days, we will dispose of all samples submitted including those put on hold unless you have contacted your Alpha Project Manager and made arrangements for Alpha to continue to hold the samples. Air canisters will be disposed after 3 business days from the date the project is completed. Please contact Project Management at 800-624-9220 with any questions. Serial_No:03142412:29 Page 3 of 17 INORGANICS & MISCELLANEOUS Serial_No:03142412:29 Page 4 of 17 FF INFLUENTClient ID: 03/07/24 10:15Date Collected: 03/07/24Date Received: Parameter Result Dilution Factor Matrix:Water YARMOUTH, MASample Location: L2412533-01Lab ID: Qualifier Units RL SAMPLE RESULTS Project Name: Project Number: Lab Number: Report Date: THE COVE @ YARMOUTH K11494DA.S.WW.700 L2412533 Field Prep: Date Analyzed Analytical Method Analyst Not Specified General Chemistry - Westborough Lab Solids, Total Solids, Total Suspended Nitrogen, Nitrite Nitrogen, Nitrate Nitrogen, Total Kjeldahl BOD, 5 day 420 54. ND ND 19.4 50 mg/l mg/l mg/l mg/l mg/l mg/l 1.3 2 1 1 1 5 13 10 0.050 0.10 0.300 10 03/07/24 22:42 03/08/24 16:00 03/08/24 02:52 03/08/24 06:20 03/13/24 15:15 03/13/24 08:00 121,2540B 121,2540D 44,353.2 44,353.2 121,4500NH3-H 121,5210B REM REM KAF KAF KEP OCF Date Prepared - - - - 03/12/24 21:06 03/08/24 08:00 03/14/24 MDL NA NA -- -- -- NA Sample Depth: Serial_No:03142412:29 Page 5 of 17 FF EFFLUENTClient ID: 03/07/24 10:15Date Collected: 03/07/24Date Received: Parameter Result Dilution Factor Matrix:Water YARMOUTH, MASample Location: L2412533-02Lab ID: Qualifier Units RL SAMPLE RESULTS Project Name: Project Number: Lab Number: Report Date: THE COVE @ YARMOUTH K11494DA.S.WW.700 L2412533 Field Prep: Date Analyzed Analytical Method Analyst Not Specified General Chemistry - Westborough Lab Solids, Total Suspended Nitrogen, Nitrite Nitrogen, Nitrate Nitrogen, Total Kjeldahl BOD, 5 day Oil & Grease, Hem-Grav 27. 0.14 ND 6.21 25 ND mg/l mg/l mg/l mg/l mg/l mg/l 2 1 1 1 2.5 1 10 0.050 0.10 0.300 5.0 4.0 03/08/24 16:00 03/08/24 02:55 03/08/24 06:23 03/13/24 15:16 03/13/24 08:00 03/10/24 15:53 121,2540D 44,353.2 44,353.2 121,4500NH3-H 121,5210B 140,1664B REM KAF KAF KEP OCF IYM Date Prepared - - - 03/12/24 21:06 03/08/24 08:00 03/10/24 09:48 03/14/24 MDL NA -- -- -- NA -- Sample Depth: Serial_No:03142412:29 Page 6 of 17 FF Parameter Result Dilution FactorQualifierUnitsRL Method Blank Analysis Batch Quality Control Project Name: Project Number: Lab Number: Report Date: THE COVE @ YARMOUTH K11494DA.S.WW.700 L2412533 Date Analyzed Analytical Method Analyst Date Prepared 03/14/24 Solids, Total Nitrogen, Nitrite Nitrogen, Nitrate BOD, 5 day Solids, Total Suspended Oil & Grease, Hem-Grav Nitrogen, Total Kjeldahl ND ND ND ND ND ND ND mg/l mg/l mg/l mg/l mg/l mg/l mg/l 1 1 1 1 1 1 1 10 0.050 0.10 2.0 5.0 4.0 0.300 03/07/24 22:42 03/08/24 02:34 03/08/24 04:51 03/13/24 08:00 03/08/24 16:00 03/10/24 12:07 03/13/24 15:09 121,2540B 44,353.2 44,353.2 121,5210B 121,2540D 140,1664B 121,4500NH3-H REM KAF KAF OCF REM IYM KEP - - - 03/08/24 08:00 - 03/10/24 09:48 03/12/24 21:06 General Chemistry - Westborough Lab for sample(s): 01 Batch: WG1893615-1 General Chemistry - Westborough Lab for sample(s): 01-02 Batch: WG1893653-1 General Chemistry - Westborough Lab for sample(s): 01-02 Batch: WG1893661-1 General Chemistry - Westborough Lab for sample(s): 01-02 Batch: WG1893705-1 General Chemistry - Westborough Lab for sample(s): 01-02 Batch: WG1894019-1 General Chemistry - Westborough Lab for sample(s): 02 Batch: WG1894389-1 General Chemistry - Westborough Lab for sample(s): 01-02 Batch: WG1895239-1 MDL NA -- -- NA NA -- -- Serial_No:03142412:29 Page 7 of 17 Solids, Total Nitrogen, Nitrite Nitrogen, Nitrate BOD, 5 day Solids, Total Suspended Oil & Grease, Hem-Grav Nitrogen, Total Kjeldahl 113 98 96 97 89 92 102 - - - - - - - 80-120 90-110 90-110 85-115 80-120 78-114 78-122 - - - - - - - 20 20 18 Parameter LCS %Recovery LCSD %Recovery %Recovery Limits RPD RPD Limits General Chemistry - Westborough Lab Associated sample(s): 01 Batch: WG1893615-2 General Chemistry - Westborough Lab Associated sample(s): 01-02 Batch: WG1893653-2 General Chemistry - Westborough Lab Associated sample(s): 01-02 Batch: WG1893661-2 General Chemistry - Westborough Lab Associated sample(s): 01-02 Batch: WG1893705-2 General Chemistry - Westborough Lab Associated sample(s): 01-02 Batch: WG1894019-2 General Chemistry - Westborough Lab Associated sample(s): 02 Batch: WG1894389-2 General Chemistry - Westborough Lab Associated sample(s): 01-02 Batch: WG1895239-2 Lab Control Sample Analysis Batch Quality ControlProject Name: Project Number: Lab Number: Report Date: THE COVE @ YARMOUTH K11494DA.S.WW.700 L2412533 03/14/24 Qual Qual Qual Serial_No:03142412:29 Page 8 of 17 Nitrogen, Nitrite Nitrogen, Nitrate BOD, 5 day Oil & Grease, Hem-Grav Nitrogen, Total Kjeldahl ND 3.2 22 ND 0.491 4.3 6.7 200 38 8.12 108 88 88 92 95 - - - - - - - - - - 80-120 83-113 50-145 78-114 77-111 - - - - - 20 6 35 18 24 Parameter Native Sample MS Found MS %Recovery MSD Found MSD %Recovery Recovery Limits RPD RPD Limits General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1893653-4 QC Sample: L2412145-01 Client ID: MS Sample General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1893661-4 QC Sample: L2412145-01 Client ID: MS Sample General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1893705-4 QC Sample: L2412551-01 Client ID: MS Sample General Chemistry - Westborough Lab Associated sample(s): 02 QC Batch ID: WG1894389-4 QC Sample: L2412427-02 Client ID: MS Sample General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1895239-4 QC Sample: L2412653-04 Client ID: MS Sample 4 4 100 40.8 8 MS Added Matrix Spike Analysis Batch Quality Control Project Name: Project Number: Lab Number: Report Date: THE COVE @ YARMOUTH K11494DA.S.WW.700 L2412533 03/14/24 Qual Qual Qual Serial_No:03142412:29 Page 9 of 17 Solids, Total Nitrogen, Nitrite Nitrogen, Nitrate BOD, 5 day Solids, Total Suspended Solids, Total Suspended Oil & Grease, Hem-Grav Nitrogen, Total Kjeldahl 220 ND 3.2 22 59 54 ND 0.491 240 ND 3.2 20 63 57 ND 0.748 mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l 9 NC 0 5 7 5 NC 41 16 20 6 35 32 32 18 24 Units RPDParameterNative Sample Duplicate Sample RPD Limits General Chemistry - Westborough Lab Associated sample(s): 01 QC Batch ID: WG1893615-3 QC Sample: L2412370-01 Client ID: DUP Sample General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1893653-3 QC Sample: L2412145-01 Client ID: DUP Sample General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1893661-3 QC Sample: L2412145-01 Client ID: DUP Sample General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1893705-3 QC Sample: L2412551-01 Client ID: DUP Sample General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1894019-3 QC Sample: L2412495-07 Client ID: DUP Sample General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1894019-4 QC Sample: L2412533-01 Client ID: INFLUENT General Chemistry - Westborough Lab Associated sample(s): 02 QC Batch ID: WG1894389-3 QC Sample: L2412427-02 Client ID: DUP Sample General Chemistry - Westborough Lab Associated sample(s): 01-02 QC Batch ID: WG1895239-3 QC Sample: L2412653-04 Client ID: DUP Sample THE COVE @ YARMOUTH K11494DA.S.WW.700 Project Name: Project Number: L2412533Lab Number: Report Date: Lab Duplicate Analysis Batch Quality Control 03/14/24 Qual Q Serial_No:03142412:29 Page 10 of 17 *Values in parentheses indicate holding time in days L2412533-01A L2412533-01B L2412533-01C L2412533-02A L2412533-02B L2412533-02C L2412533-02D L2412533-02E Plastic 250ml H2SO4 preserved Plastic 950ml unpreserved Plastic 950ml unpreserved Plastic 250ml H2SO4 preserved Plastic 950ml unpreserved Plastic 950ml unpreserved Amber 1000ml HCl preserved Amber 1000ml HCl preserved B B B C C C C C <2 7 7 <2 7 7 NA NA 5.5 5.5 5.5 4.4 4.4 4.4 4.4 4.4 Y Y Y Y Y Y Y Y Absent Absent Absent Absent Absent Absent Absent Absent B C Absent Absent Cooler Custody Seal Cooler Information THE COVE @ YARMOUTH K11494DA.S.WW.700 TKN-4500(28) TSC-2540(7),NO2-353(2),NO3-353(2),BOD- 5210(2) TSS-2540(7) TKN-4500(28) NO2-353(2),BOD-5210(2),NO3-353(2) TSS-2540(7) OG-1664(28) OG-1664(28) Project Name: Project Number: L2412533Lab Number: Report Date: Sample Receipt and Container Information Container ID Container Type Cooler Temp deg C Pres Seal Container Information Analysis(*) 03/14/24 Were project specific reporting limits specified?YES <2 7 7 <2 7 7 Frozen Date/Time Final pH Initial pH Serial_No:03142412:29 Page 11 of 17 Report Format:Data Usability Report GLOSSARY Project Name: Project Number: Lab Number: Report Date: L2412533THE COVE @ YARMOUTH K11494DA.S.WW.700 03/14/24 Acronyms DL EDL EMPC EPA LCS LCSD LFB LOD LOQ MDL MS MSD NA NC NDPA/DPA NI NP NR RL RPD SRM STLP TEF TEQ TIC Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated values, when those target analyte concentrations are quantified below the limit of quantitation (LOQ). The DL includes any adjustments from dilutions, concentrations or moisture content, where applicable. (DoD report formats only.) Estimated Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated values, when those target analyte concentrations are quantified below the reporting limit (RL). The EDL includes any adjustments from dilutions, concentrations or moisture content, where applicable. The use of EDLs is specific to the analysis of PAHs using Solid-Phase Microextraction (SPME). Estimated Maximum Possible Concentration: The concentration that results from the signal present at the retention time of an analyte when the ions meet all of the identification criteria except the ion abundance ratio criteria. An EMPC is a worst-case estimate of the concentration. Environmental Protection Agency. Laboratory Control Sample: A sample matrix, free from the analytes of interest, spiked with verified known amounts of analytes or a material containing known and verified amounts of analytes. Laboratory Control Sample Duplicate: Refer to LCS. Laboratory Fortified Blank: A sample matrix, free from the analytes of interest, spiked with verified known amounts of analytes or a material containing known and verified amounts of analytes. Limit of Detection: This value represents the level to which a target analyte can reliably be detected for a specific analyte in a specific matrix by a specific method. The LOD includes any adjustments from dilutions, concentrations or moisture content, where applicable. (DoD report formats only.) Limit of Quantitation: The value at which an instrument can accurately measure an analyte at a specific concentration. The LOQ includes any adjustments from dilutions, concentrations or moisture content, where applicable. (DoD report formats only.) Limit of Quantitation: The value at which an instrument can accurately measure an analyte at a specific concentration. The LOQ includes any adjustments from dilutions, concentrations or moisture content, where applicable. (DoD report formats only.) Method Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated values, when those target analyte concentrations are quantified below the reporting limit (RL). The MDL includes any adjustments from dilutions, concentrations or moisture content, where applicable. Matrix Spike Sample: A sample prepared by adding a known mass of target analyte to a specified amount of matrix sample for which an independent estimate of target analyte concentration is available. For Method 332.0, the spike recovery is calculated using the native concentration, including estimated values. Matrix Spike Sample Duplicate: Refer to MS. Not Applicable. Not Calculated: Term is utilized when one or more of the results utilized in the calculation are non-detect at the parameter's reporting unit. N-Nitrosodiphenylamine/Diphenylamine. Not Ignitable. Non-Plastic: Term is utilized for the analysis of Atterberg Limits in soil. No Results: Term is utilized when 'No Target Compounds Requested' is reported for the analysis of Volatile or Semivolatile Organic TIC only requests. Reporting Limit: The value at which an instrument can accurately measure an analyte at a specific concentration. The RL includes any adjustments from dilutions, concentrations or moisture content, where applicable. Relative Percent Difference: The results from matrix and/or matrix spike duplicates are primarily designed to assess the precision of analytical results in a given matrix and are expressed as relative percent difference (RPD). Values which are less than five times the reporting limit for any individual parameter are evaluated by utilizing the absolute difference between the values; although the RPD value will be provided in the report. Standard Reference Material: A reference sample of a known or certified value that is of the same or similar matrix as the associated field samples. Semi-dynamic Tank Leaching Procedure per EPA Method 1315. Toxic Equivalency Factors: The values assigned to each dioxin and furan to evaluate their toxicity relative to 2,3,7,8-TCDD. Toxic Equivalent: The measure of a sample's toxicity derived by multiplying each dioxin and furan by its corresponding TEF and then summing the resulting values. Tentatively Identified Compound: A compound that has been identified to be present and is not part of the target compound list (TCL) for the method and/or program. All TICs are qualitatively identified and reported as estimated concentrations. - - - - - - - - - - - - - - - - - - - - - - - - - Serial_No:03142412:29 Page 12 of 17 Report Format:Data Usability Report Project Name: Project Number: Lab Number: Report Date: L2412533THE COVE @ YARMOUTH K11494DA.S.WW.700 03/14/24 Terms Analytical Method: Both the document from which the method originates and the analytical reference method. (Example: EPA 8260B is shown as 1,8260B.) The codes for the reference method documents are provided in the References section of the Addendum. Chlordane: The target compound Chlordane (CAS No. 57-74-9) is reported for GC ECD analyses. Per EPA,this compound "refers to a mixture of chlordane isomers, other chlorinated hydrocarbons and numerous other components." (Reference: USEPA Toxicological Review of Chlordane, In Support of Summary Information on the Integrated Risk Information System (IRIS), December 1997.) Difference: With respect to Total Oxidizable Precursor (TOP) Assay analysis, the difference is defined as the Post-Treatment value minus the Pre-Treatment value. Final pH: As it pertains to Sample Receipt & Container Information section of the report, Final pH reflects pH of container determined after adjustment at the laboratory, if applicable. If no adjustment required, value reflects Initial pH. Frozen Date/Time: With respect to Volatile Organics in soil, Frozen Date/Time reflects the date/time at which associated Reagent Water- preserved vials were initially frozen. Note: If frozen date/time is beyond 48 hours from sample collection, value will be reflected in 'bold'. Gasoline Range Organics (GRO): Gasoline Range Organics (GRO) results include all chromatographic peaks eluting from Methyl tert butyl ether through Naphthalene, with the exception of GRO analysis in support of State of Ohio programs, which includes all chromatographic peaks eluting from Hexane through Dodecane. Initial pH: As it pertains to Sample Receipt & Container Information section of the report, Initial pH reflects pH of container determined upon receipt, if applicable. PAH Total: With respect to Alkylated PAH analyses, the 'PAHs, Total' result is defined as the summation of results for all or a subset of the following compounds: Naphthalene, C1-C4 Naphthalenes, 2-Methylnaphthalene, 1-Methylnaphthalene, Biphenyl, Acenaphthylene, Acenaphthene, Fluorene, C1-C3 Fluorenes, Phenanthrene, C1-C4 Phenanthrenes/Anthracenes, Anthracene, Fluoranthene, Pyrene, C1-C4 Fluoranthenes/Pyrenes, Benz(a)anthracene, Chrysene, C1-C4 Chrysenes, Benzo(b)fluoranthene, Benzo(j)+(k)fluoranthene, Benzo(e)pyrene, Benzo(a)pyrene, Perylene, Indeno(1,2,3-cd)pyrene, Dibenz(ah)+(ac)anthracene, Benzo(g,h,i)perylene. If a 'Total' result is requested, the results of its individual components will also be reported. PFAS Total: With respect to PFAS analyses, the 'PFAS, Total (5)' result is defined as the summation of results for: PFHpA, PFHxS, PFOA, PFNA and PFOS. In addition, the 'PFAS, Total (6)' result is defined as the summation of results for: PFHpA, PFHxS, PFOA, PFNA, PFDA and PFOS. For MassDEP DW compliance analysis only, the 'PFAS, Total (6)' result is defined as the summation of results at or above the RL. Note: If a 'Total' result is requested, the results of its individual components will also be reported. Total: With respect to Organic analyses, a 'Total' result is defined as the summation of results for individual isomers or Aroclors. If a 'Total' result is requested, the results of its individual components will also be reported. This is applicable to 'Total' results for methods 8260, 8081 and 8082. Data Qualifiers A B C D E F G H I J M - - - - - - - - - - - Spectra identified as "Aldol Condensates" are byproducts of the extraction/concentration procedures when acetone is introduced in the process. The analyte was detected above the reporting limit in the associated method blank. Flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank. For MCP-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank. For DOD-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank AND the analyte was detected above one-half the reporting limit (or above the reporting limit for common lab contaminants) in the associated method blank. For NJ- Air-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte above the reporting limit. For NJ-related projects (excluding Air), flag only applies to associated field samples that have detectable concentrations of the analyte, which was detected above the reporting limit in the associated method blank or above five times the reporting limit for common lab contaminants (Phthalates, Acetone, Methylene Chloride, 2-Butanone). Co-elution: The target analyte co-elutes with a known lab standard (i.e. surrogate, internal standards, etc.) for co-extracted analyses. Concentration of analyte was quantified from diluted analysis. Flag only applies to field samples that have detectable concentrations of the analyte. Concentration of analyte exceeds the range of the calibration curve and/or linear range of the instrument. The ratio of quantifier ion response to qualifier ion response falls outside of the laboratory criteria. Results are considered to be an estimated maximum concentration. The concentration may be biased high due to matrix interferences (i.e, co-elution) with non-target compound(s). The result should be considered estimated. The analysis of pH was performed beyond the regulatory-required holding time of 15 minutes from the time of sample collection. The lower value for the two columns has been reported due to obvious interference. Estimated value. This represents an estimated concentration for Tentatively Identified Compounds (TICs). Reporting Limit (RL) exceeds the MCP CAM Reporting Limit for this analyte. 1 The reference for this analyte should be considered modified since this analyte is absent from the target analyte list of the original method. - Footnotes Serial_No:03142412:29 Page 13 of 17 Report Format:Data Usability Report Project Name: Project Number: Lab Number: Report Date: L2412533THE COVE @ YARMOUTH K11494DA.S.WW.700 03/14/24 Data Qualifiers ND NJ P Q R RE S V Z - - - - - - - - - Not detected at the reporting limit (RL) for the sample. Presumptive evidence of compound. This represents an estimated concentration for Tentatively Identified Compounds (TICs), where the identification is based on a mass spectral library search. The RPD between the results for the two columns exceeds the method-specified criteria. The quality control sample exceeds the associated acceptance criteria. For DOD-related projects, LCS and/or Continuing Calibration Standard exceedences are also qualified on all associated sample results. Note: This flag is not applicable for matrix spike recoveries when the sample concentration is greater than 4x the spike added or for batch duplicate RPD when the sample concentrations are less than 5x the RL. (Metals only.) Analytical results are from sample re-analysis. Analytical results are from sample re-extraction. Analytical results are from modified screening analysis. The surrogate associated with this target analyte has a recovery outside the QC acceptance limits. (Applicable to MassDEP DW Compliance samples only.) The batch matrix spike and/or duplicate associated with this target analyte has a recovery/RPD outside the QC acceptance limits. (Applicable to MassDEP DW Compliance samples only.) Serial_No:03142412:29 Page 14 of 17 Alpha Analytical performs services with reasonable care and diligence normal to the analytical testing laboratory industry. In the event of an error, the sole and exclusive responsibility of Alpha Analytical shall be to re-perform the work at it's own expense. In no event shall Alpha Analytical be held liable for any incidental, consequential or special damages, including but not limited to, damages in any way connected with the use of, interpretation of, information or analysis provided by Alpha Analytical. We strongly urge our clients to comply with EPA protocol regarding sample volume, preservation, cooling, containers, sampling procedures, holding time and splitting of samples in the field. LIMITATION OF LIABILITIES 44 121 140 Methods for the Determination of Inorganic Substances in Environmental Samples, EPA/600/R-93/100, August 1993. Standard Methods for the Examination of Water and Wastewater. APHA-AWWA-WEF. Standard Methods Online. Method 1664,Revision B: N-Hexane Extractable Material (HEM; Oil & Grease) and Silica Gel Treated N-Hexane Extractable Material (SGT-HEM; Non-polar Material) by Extraction and Gravimetry, EPA-821-R-10-001, February 2010. Project Name: Project Number: Lab Number: Report Date: L2412533THE COVE @ YARMOUTH K11494DA.S.WW.700 REFERENCES 03/14/24 Serial_No:03142412:29 Page 15 of 17 Alpha Analytical, Inc.ID No.:17873 Facility: Company-wide Revision 20 Department: Quality Assurance Published Date: 6/16/2023 4:52:28 PM Title: Certificate/Approval Program Summary Page 1 of 1 Document Type: Form Pre-Qualtrax Document ID: 08-113 Certification Information The following analytes are not included in our Primary NELAP Scope of Accreditation: Westborough Facility EPA 624.1: m/p-xylene, o-xylene, Naphthalene EPA 625.1: alpha-Terpineol EPA 8260D: NPW: 1,2,4,5-Tetramethylbenzene; 4-Ethyltoluene, Azobenzene; SCM: Iodomethane (methyl iodide), 1,2,4,5-Tetramethylbenzene; 4- Ethyltoluene. EPA 8270E: NPW: Dimethylnaphthalene,1,4-Diphenylhydrazine, alpha-Terpineol; SCM: Dimethylnaphthalene,1,4-Diphenylhydrazine. SM4500: NPW: Amenable Cyanide; SCM: Total Phosphorus, TKN, NO2, NO3. Mansfield Facility SM 2540D: TSS. EPA TO-15: Halothane, 2,4,4-Trimethyl-2-pentene, 2,4,4-Trimethyl-1-pentene, Thiophene, 2-Methylthiophene, 3-Methylthiophene, 2-Ethylthiophene, 1,2,3-Trimethylbenzene, Indan, Indene, 1,2,4,5-Tetramethylbenzene, Benzothiophene, 1-Methylnaphthalene. Biological Tissue Matrix: EPA 3050B The following analytes are included in our Massachusetts DEP Scope of Accreditation Westborough Facility: Drinking Water EPA 300.0: Chloride, Nitrate-N, Fluoride, Sulfate; EPA 353.2: Nitrate-N, Nitrite-N; SM4500NO3-F: Nitrate-N, Nitrite-N; SM4500F-C, SM4500CN-CE, EPA 180.1, SM2130B, SM4500Cl-D, SM2320B, SM2540C, SM4500H-B, SM4500NO2-B EPA 524.2: THMs and VOCs; EPA 504.1: EDB, DBCP. Microbiology: SM9215B; SM9223-P/A, SM9223B-Colilert-QT,SM9222D. Non-Potable Water SM4500H,B, EPA 120.1, SM2510B, SM2540C, SM2320B, SM4500CL-E, SM4500F-BC, SM4500NH3-BH: Ammonia-N and Kjeldahl-N, EPA 350.1: Ammonia-N, LACHAT 10-107-06-1-B: Ammonia-N, EPA 351.1, SM4500NO3-F, EPA 353.2: Nitrate-N, SM4500P-E, SM4500P-B, E, SM4500SO4-E, SM5220D, EPA 410.4, SM5210B, SM5310C, SM4500CL-D, EPA 1664, EPA 420.1, SM4500-CN-CE, SM2540D, EPA 300: Chloride, Sulfate, Nitrate. EPA 624.1: Volatile Halocarbons & Aromatics, EPA 608.3: Chlordane, Toxaphene, Aldrin, alpha-BHC, beta-BHC, gamma-BHC, delta-BHC, Dieldrin, DDD, DDE, DDT, Endosulfan I, Endosulfan II, Endosulfan sulfate, Endrin, Endrin Aldehyde, Heptachlor, Heptachlor Epoxide, PCBs EPA 625.1: SVOC (Acid/Base/Neutral Extractables). Microbiology: SM9223B-Colilert-QT; Enterolert-QT, SM9221E, EPA 1600, EPA 1603, SM9222D. Mansfield Facility: Drinking Water EPA 200.7: Al, Ba, Cd, Cr, Cu, Fe, Mn, Ni, Na, Ag, Ca, Zn. EPA 200.8: Al, Sb, As, Ba, Be, Cd, Cr, Cu, Pb, Mn, Ni, Se, Ag, TL, Zn. EPA 245.1 Hg. EPA 522, EPA 537.1. Non-Potable Water EPA 200.7: Al, Sb, As, Be, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Ag, Na, Sr, TL, Ti, V, Zn. EPA 200.8: Al, Sb, As, Be, Cd, Cr, Cu, Fe, Pb, Mn, Ni, K, Se, Ag, Na, TL, Zn. EPA 245.1 Hg. SM2340B For a complete listing of analytes and methods, please contact your Alpha Project Manager. Serial_No:03142412:29 Page 16 of 17 Serial_No:03142412:29 Page 17 of 17