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HomeMy WebLinkAboutFireworks SDSPage: 1 /10 Safety Data Sheet ace. to OSHA FICS (29 CFR 1910.1200) Printing date: 01/06/2017 Revision: 01/06/2017 ide-n—tit, cation Product identifier Trade name: Fireworks, Display Product code: Fireworks, 1.3G UN0335 Recommended use and restriction on use Recommended use: Explosive product for professional use for entertainment and technical purposes Restrictions on use: Contact man ufacturer/supplier Details of the supplier of the Safety Data Sheet Man ufacturer/Supplier: Hop Kee Pyrotechnics Ltd. Unit D, 9th Floor, Dragon Industrial Building, 93 King Lam Street, Cheung Sha Wan, Kowloon, Hong Kong Tel: +852 2545-0755 Emergency telephone number: ChemTel Inc. (800)255-3924, +1 (813)248-0585 2 Hazard(s) identification Classification of the substance or mixture Expl. 1.3 H203 Explosive; fire, blast or projection hazard. Label elements GK5 label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms: GHS01 Signal word: Danger Hazard statements: H203 Explosive; fire, blast or projection hazard. Precautionary statements: P21 0 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P250 Do not subject to grinding/shock/friction. P280 Wear protective gloves/protective clothing/eye protection/face protection. P373 DO NOT fight fire when fire reaches explosives. P370+P380 In case of fire: Evacuate area. P372 Explosion risk in case of fire. Page: 2/10 Safety Data Sheet ace. to OSHA HCS (29 CFR 1910.1200) Printing date: 01/06/2017 Revision: 01/06/2017 Trade name: Fireworks, Display P401 Store in accordance with local/regional/national/international regulations. (Cont'd. of page 1) P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Other hazards There are no other hazards not otherwise classified that have been identified. Explosive Product Notice PREVENTION OF ACCIDENTS IN THE USE OF EXPLOSIVES - The prevention of accidents in the use of explosives is a result of careful planning and observance of the best known practices. The explosives user must remember that he is dealing with a powerful force and that various devices and methods have been developed to assist him in directing this force. He should realize that this force, if misdirected, may either kill or injure both him and his fellow workers. WARNING - All explosives are dangerous and must be carefully handled and used following approved safety procedures either by or under the direction of competent, experienced persons in accordance with all applicable federal, state, and local laws, regulations, or ordinances. If you have any questions or doubts as to how to use any explosive product, DO NOT USE IT before consulting with your supervisor, or the manufacturer, if you do not have a supervisor. If your supervisor has any questions or doubts, he should consult the manufacturer before use. 3 Composition/information on ingredients --- - - -- -- _------------ - - ----- - - ---- .._ __ -. - .. -- - - --- ------ -- - Chemical characterization: Mixtures Components: Components for product possesing only physical hazards do not require reporting. These components are considered proprietary. 4 First -aid measures Description of first aid measures General information: Information is only applicable to product contents, and not to product as normally supplied. This information is applicable to damaged, leaking, or spilled product as contact with contents is possible under these conditions. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Wash with soap and water. In case of minor burns, flush with cool water. If skin irritation is experienced, consult a doctor. After eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing: Unlikely route of exposure. Do not induce vomiting; immediately call for medical help. (Cont'd. on page 3) Page: 3/10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date: 01/06/2017 Revision: 01/06/2017 Trade name: Fireworks, Display (Cont'd, of page 2) Most important symptoms and effects, both acute and delayed: Blast injury if mishandled. Thermal burns, if mishandled. Danger: Danger of blast or crush -type injuries. Indication of any immediate medical attention and special treatment needed: Product may produce physical injury if mishandled. Treatment of these injuries should be based on the clinical presentation. 5 f lre tight�ng measures Extinguishing media Suitable extinguishing agents: DO NOT fight fire when fire reaches explosives. Flood area with water. If no water is available, carbon dioxide, dry chemical or earth may be used. If the fire reaches the cargo, withdraw and let fire burn. For safety reasons unsuitable extinguishing agents: None. Special hazards arising from the substance or mixture Explosive; fire, blast or projection hazard. During heating or in case of fire poisonous gases are produced. Advice for firefighters Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. Additional information: Eliminate all ignition sources if safe to do so. In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. Cool endangered receptacles with water spray. Flammability Classification: (defined by 29 CFR 1910.1200) Explosive. Can explode under fire conditions. Individual devices will randomly explode. Mass explosion of multiple devices is possible under certain conditions. Burning material may produce toxic and irritating vapors. In unusual cases, shrapnel may be thrown from exploding devices under containment. See 2012 Emergency response Guidebook for further information. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Remove persons from danger area. Ensure adequate ventilation. Isolate area and prevent access. Environmental precautions Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Methods and material for containment and cleaning up Pick up mechanically. (Cont'd. on page 4) Page: 4/10 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date: 01/06/2017 Revision: 01/06/2017 Trade name: Fireworks, Display Send for recovery or disposal in suitable receptacles. (Cont'd. of page 3) Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handiing and storage Handling Precautions for safe handling: Handle with care. Avoid jolting, friction and impact. Restrict the quantity stored at the work place. Keep out of reach of children. Information about protection against explosions and fires: In case of fire: Evacuate area. Explosion risk in case of fire. Keep away from sparks and open flames. - No smoking. Emergency cooling must be available in case of nearby fire. Conditions for safe storage, including any incompatibilities Storage Requirements to be met by storerooms and receptacles: Avoid storage near extreme heat, ignition sources or open flame. Information about storage in one common storage facility: Store in accordance with local/regional/national/international regulations. Store away from foodstuffs. Store away from flammable substances. Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles - Store locked tap. Specific end use(s) No relevant information available. 8 Exposure controls/personal protection Control parameters Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Exposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Engineering controls: Provide adequate ventilation. Safety Data Sheet ace. to OSHA HCS (29 CFR 1910.1200) Printing date: 01/06/2017 Trade name: Fireworks, Display Page: 5/10 Revision: 01 /06/2017 (Cont'd. of page 4) Breathing equipment: Not required under normal conditions of use. Protection of hands: When needed, wear gloves for protection against mechanical hazards. Eye protection: 0 Safety glasses Fallow relevant national guidelines concerning the use of protective eyewear. Body protection: When needed, wear protective clothing for protection against mechanical hazards. Limitation and supervision of exposure into the environment No relevant information available. Risk management measures Organizational measures should be in place for all activities involving this product. 9 Physical and chemical properties Information on basic physical and chemical properties Appearance: Form: Outer shell containing powder, granular, or solid materials. Color: According to product specification Odor: Odorless Odor threshold: Not determined. pH value: Not applicable. Melting point/Melting range: Not determined. Boiling point/Boiling range: Not determined. Flash point: Not applicable. Flammability (solid, gaseous): Fire or projection hazard - Auto -ignition temperature: Not determined. Decomposition temperature: Not determined. Danger of explosion: Heating may cause an explosion. Explosion limits Lower: Not determined. Upper: Not determined. Vapor pressure: Not applicable. Density: Not determined. Relative density: Not determined. Vapor density: Not applicable. Evaporation rate: Not applicable. (Cont'd. on page 6) Safety Data Sheet ace. to OSHA HCS (29 CFR 1910.1200) Printing date: 01/06/2017 Trade name: Fireworks, Display Page: 6/10 Revision: 01/06/2017 (Cont'd. of page 5) Solubility in / Miscibility with Water: Insoluble. Partition coefficient (n-octanollwater): Not determined. Viscosity Dynamic: Not applicable. Kinematic: Not applicable. Other information No relevant information available. 10 Stability and reactivity Reactivity: No relevant information available. Chemical stability: Thermal decomposition / conditions to be avoided: Risk of explosion if heated under confinement. Possibility of hazardous reactions Explosive; fire, blast or projection hazard. Toxic fumes may be released if heated above the decomposition point. Reacts with strong acids and alkali. Conditions to avoid Excessive heat. Sources of ignition: sparks, open flame, incompatible materials Incompatible materials Oxidizers, strong bases, strong acids Hazardous decomposition products Carbon monoxide and carbon dioxide Nitrogen oxides Sulfur oxides (SOx) 11 Taxecolog�rlcal �nfcrrnat�an Information on toxicological effects Acute toxicity: LD/LC60 values that are relevant for classification: None. Primary irritant effect: On the skin: Not a skin irritant in unused form. Vapors/particles from used product are possibly irritating to skin. On the eye: Not an eye irritant in unused form. Vapors/particles from used product are possibly irritating to eyes. Sensitization: Based on available data, the classification criteria are not met. Carcinogenic categories F :NonCe R(International Agency for Research on Cancer): of the ingredients are listed. (Contd. on page 7) Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date: 01/06/2017 Trade name: Fireworks, Display Page: 7/10 Revision: 01/06/2017 (Cont'd. of page 6) NTP (National Toxicology Program): None of the ingredients are listed. OSHA -Ca (Occupational Safety & Health Administration): None of the ingredients are listed. Probable route(s) of exposure: Skin contact. Eye contact. Inhalation. Acute effects (acute toxicity, irritation and corrosivity): Danger of blast or crush -type injuries. Risk of thermal burns. Repeated dose toxicity: From product as supplied: None. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Germ cell mutagenicity: Based on available data, the classification criteria are not met. Carcinogenicity: Based on available data, the classification criteria are not met. Reproductive toxicity: Based on available data, the classification criteria are not met. STOT-single exposure: Based on available data, the classification criteria are not met. STOT-repeated exposure: Based on available data, the classification criteria are not met. Aspiration hazard: Based on available data, the classification criteria are not met. 12 Ecological information Toxicity Aquatic toxicity No relevant information available. Persistence and degradability No relevant information available. Bioaccumulative potential: May be accumulated in organism Mobility in coil: No relevant information available. Other adverse effects No relevant information available. 13 Disposal considerations • Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Incinerate in accordance with local, state and federal regulations. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and disposal for hazardous and nonhazardous wastes. Residual materials should be treated as hazardous. (Cont'd. on page 8) Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date: 01/06/2017 Trade name: Fireworks, Display Page: 8/10 Revision: 01/0612017 (Contd. of page 7) Uncleaned packagings Recommendation: Disposal must be made according to official regulations. 14 Transport UN -Number DOT, ADR, 1MDG UN0335 IATA FORBIDDEN UN proper shipping name DOT, ADR, IMDG Fireworks IATA FORBIDDEN Transport hazard class(es) DOT Class 1.3 Label 1.3G ADR ------------ --------- Class 1.3 Label 1.3G • IMDG ------------------ X" 14"\e Class 1.1 Label I-3G IATA Class FORBIDDEN Packing group DOT 11 Environmental hazards Marine pollutant: No Special precautions for user Not applicable. (ConVd. on page 9) Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date: 01/06/2017 Trade name: Fireworks, Display EMS Number: F-S,B-X Transport in bulk according to Annex 11 of MARPOL73178 and the IBC Code Not applicable. Page: 9/10 Revision: 01/06/2017 (Cont'd. of page 8) 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture United States (USA) SARA Section 302 (extremely hazardous substances): None of the ingredients are listed. Section 304 (emergency release notification): None of the ingredients are listed. 1 Section 366 (extremely hazardous substances): None of the ingredients are listed. Section 313 (Specific toxic chemical listings): Contact manufacturer. TSCA (Toxic Substances Control Act) All ingredients are listed. Proposition 66 (California) Chemicals known to cause cancer: Contact manufacturer. Chemicals known to cause reproductive toxicity for females: Contact manufacturer. Chemicals known to cause reproductive toxicity for males: Contact manufacturer. Chemicals known to cause developmental toxicity: Contact manufacturer. Carcinogenic categories EPA (Environmental Protection Agency): None of the ingredients are listed. IARC (International Agency for Research on Cancer): 1 Contact manufacturer. (Cont'd. on page 10) Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date: 01/06/2017 Trade name: Fireworks, Display Page: 10/10 Revision: 01 /06/2017 (Cont'd. of page 9) O ther information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation ! last revision 01/06/2017 / - Abbreviations and acronyms: ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit LDLo: Lowest Lethal Dose Observed Expl. 1.3: Explosives —Division 1.3 Sources Website, European Chemicals Agency (echa.europa.eu) Website, US EPA Substance Registry Services (ofmpub.epa.gov/sor internet/registry/substreg/home/ overview/home.do) Website, Chemical Abstracts Registry, American Chemical Society (www.cas.org) Patty's Industrial Hygiene, 6th ed., Rose, Vernon, ed. ISBN: 978-0-470-07488-6 Casarett and Doull's Toxicology: The Basic Science of Poisons, 8th Ed., Klaasen, Curtis D., ed., ISBN: 978-0•-07-176923-5. Safety Data Sheets, Individual Manufacturers SIDS Prepared by: ChemTel Inc. 1305 North Florida Avenue Tampa, Florida USA 33602-2902 Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573 Website: www.chemtelinc.com Liuyang Sunwing Import & Export Co. L td. MATERIAL SAFETY DATA SHEET : FIREWORKS PAGE: 01 OF 05 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : Fireworks FORMULA : KCIOa, S, Ba(NO3)2,,, AI -Mg, (C2H3CI)n SYNONYMS : Oxidiser agents typically used are potassium perchlorate and copper oxide. Fuels typically used may be Sulfur and Mg/Al alloy. Polyvinyl chlorate is usually used as kind of bond. MSDS NUMBER : NA EPA Reg. No. : - DATE: NA Liuyang Sunwing Import & Export Co. L td. 475 Sitong Village, Hehua District, Liuyang 410300, China TEL:0731-83705699 FOR MEDICAL EMERGENCY AND CHEMICAL EMERGENCY, SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT CALL: 2. COMPOSITION / INFORMATION ON INGREDIENTS COMPONENT CAS NO. ACTIVE CONTENT PATASSIUM PERCHLORATE 34% SULFUR 13% Barium Nitrate 15 % Mg/AI alloy 25% POLYVINYL CHLORIDE 13% 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW APPERANCE AND ODOUR : All chemical composition is contained in a cardboard casing WARNING STATEMENTS : No Smoking, Keep away from fire! Handle with care. Do not drop or throw. Place upright. If exposed to fire, articles will explode. POTENTIAL HEALTH EFFECTS LIKELY ROUTES OF EXPOSURE : NA EYE CONTACT :NA SKIN CONTACT : NA INGESTION : NA INHALATION : NA 4. FIRST AID MEASURES AND ANTIDOTE If swallowed, wash out mouth with water provided person is conscious. Call a physician. If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. In case of contact immediately wash skin with soap and water. Liuyang Sunwing Import & Export Co. L td. MATERIAL SAFETY DATA SHEET : FIREWORKS PAGE: 02 OF 05 ANTIDOTE: NA 5. FIRE FIGHTING MEASURES FLASH POINT : NA AUTOIGNITION TEMPERATURE : NA HAZARDOUS PRODUCTS OF COMBUSTION : NA EXTINGUISHING MEDIA : DO NOT attempt to fight fire in the vicinity of other fireworks. UNUSUAL FIRE AND EXPLOSION HAZARDS : If exposed to fire, articles will explode and propel burning projectiles. There is a risk of explosion if large quantities of fireworks are involved in a fire. FIRE FIGHTING EQUIPMENT: In the case of a small amount on fire apply as much water as possible from as much distance as practical. Larger fires involving more than one carton require large volumes of water and extra care from fumes and debris. Evacuate fire area IMMEDIATELY and seek shelter. Follow emergency evacuation plan. 6. ACCIDENTAL RELEASE MEASURE NA 7. HANDLING AND STORAGE No Smoking, Keep away from fire! Handle with care. Do not drop or throw. Place upright. If exposed to fire, articles will explode. 8.EXPOSURE CONTROLS/PERSONAL PROTECTION EYE PROTECTION : NA SKIN PROTECTION : NA RESPIRATORY PROTECTION None required when handling finished fireworks VENTILATION : NA Liuyang Sunwing Import & Export Co. L td. MATERIAL SAFETY DATA SHEET : FIREWORKS PAGE: 03 OF OS 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : All chemical composition is contained in a cardboard casing Odour All chemical composition is contained in a cardboard casing Density : NA Vapour Pressure : NA Vapour Density (Air--1) : NA Melting Point : NA Solubility in Water : Slight 10. STABILITY AND REACTIVITY STABILITY : Stable MATERIALS TO AVOID : Do not store with any other Dangerous Goods except articles (not substances) of class 1, Compatibility Groups C,D,E,G and S. DO NOT allow fireworks to get soaking wet. HAZARDOUS DECOMPOSITION PRODUCTS : When ignited the following major decomposition products may form: carbon dioxide, carbon monoxide, oxides of nitrogen, oxides of sulfur, heavy metal compounds and other toxic substances. Avoid breathing smoke from fireworks. HAZARDOUS POLYMERIZATION Will not Occur 11. TOXICOLOGICAL INFORMATION 11.1. Acute oral toxicity NA 11.2. Acute dermal toxicity NA 11.3. Chronic Toxicity NA Liuyang Sunwing Import & Export Co. L td. MATERIAL SAFETY DATA SHEET YHLEWORKS PAGE: 04 OF 05 11.4 Inhalation toxicity NA 11.5 Eye irritation NA 11.6 Toxicity to birds NA 11.7 Fish toxicity NA 11.8 Toxicity to bees NA 12. ECOLOGICAL INFORMATION ENVIRONMENTAL HAZARDS: NA 13. DISPOSAL CONSIDERTIONS Cleanup and disposal in accordance to local environmental regulations Metal Drums: NA Plastic / HDPE Bags: NA 14. TRANSPORT INFORMATION DOT (Department Of Transportation) DOT Proper Shipping Name Fireworks DOT Hazard Class / I.D. No. I AG DOT Label Class I HAZCHEM NO. UN NO. 0336 TREM CARD. NA 17420 S. AVALON BLVD., SUITE#204, CARSON, CA 90746 TEL: 310-515-4862 / 310-515-0982 MOB: 310-502-8537 FAX: 310-515-4902 EMAIL: FAYE_LI@FIRSTRANS.NET D) The Freight will be released within 24 hours after receipt of the TOTAL shown above and the properly endorsed Original Bill of Lading. E) Please call the terminal or warehouse to ensure the availability of your freight prior to arrangement of pick-up. F) To avoid any additional charges, please pick up the freight within the free time limited in accordance with terminal/warehouse tariff. G) For personal effects, please issue us a Cashier's check or money order payable to: FIRSTRANS INTERNATIONAL CO Page 2 Liuyang Sunwing Import & Export Co. L td. MATERIAL SAFETY DATA SHEET : FIREWORKS PAGE: 05 OF 05 15. REGULATORY INFORMATION INGREDIENT: Complies with EN Standard and BS7114. PRODUCT CLASSIFICATION: Acute = No Chronic =No Fire = No Reactivity = No Pressure Generating =No NFPA CODES : HEALTH : NA FLAMMABILITY : NA REACTIVITY : NA 16. OTHER INFORMATION MANUFACTURER / SUPPLIERS DATA: - NAME OF FIRM : Liuyang Sunwing Import & Export Co. L td. - MAILING ADDRESS Puhua,shangli pingxiang,jiangxi,JX337011,China - TELEPHONE : 0731-83705699 - FAX NO. - E-mail CONTACT PERSON IN EMERGENCY Ms Mao LOCAL BODIES INVOLVED STANDARD PACKING DISCLAIMER: Information contained in this M.S.D.S. is believed to be reliable but no representation, guarantee or warranties of any kind are made as to its accuracy, suitability for a particular application or results to be obtained for them. It is up to the user to ensure that the information contained in the Material Safety Data Sheet is relevant to the product manufactured/handled or used by him as the case may be JIANGXI PROVINCE LIDU FIREWORKS CORPORATION LTD. 2015.11.11 MATERIAL SAFETY DATA SHEET : FIREWORKS PAGE: 01 OF 05 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : Fireworks FORMULA : KC104, S, Ba(NO3)2,,, AI —Mg, (C2H3C1)n SYNONYMS : Oxidiser agents typically used are potassium perchlorate and copper oxide. Fuels typically used may be Sulfur and Mg/AI alloy. Polyvinyl chlorate is usually used as kind of bond. MSDS NUMBER : NA EPA Reg. No. : -- DATE: NA JIANGXI PROVINCE LIDU FIREWORKS CORPORATION LTD. NO.2 LIDU ROAD LIDU TOWN JINXIAN COUNTY JIANGXI PROVINCE CHINA Tel: 0791-8396 1780 2. COMPOSITION / INFORMATION ON INGREDIENTS COMPONENT CAS NO, ACTIVE CONTENT PATASSIUM PERCHLORATE 38 % SULFUR 11 % Barium Nitrate 16.5 % Mg/Al alloy 22.5% POLYVINYL CHLORIDE 12 % 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW APPERANCE AND ODOUR All chemical composition is contained in a cardboard casing WARNING STATEMENTS : No Smoking, Keep away from fire! Handle with care. Do not drop or throw. Place upright. If exposed to fire, articles will explode. POTENTIAL HEALTH EFFECTS LIKELY ROUTES OF EXPOSURE :NA EYE CONTACT :NA SKIN CONTACT : NA INGESTION :NA INHALATION : NA 4. FIRST AID MEASURES AND ANTIDOTE If swallowed, wash out mouth with water provided person is conscious. Call a physician. If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. In case of contact immediately wash skin with soap and water. JIANGXI PROVINCE LIDU FIREWORKS CORPORATION LTD. MATERIAL SAFETY DATA SHEET : FIREWORKS PAGE: 02 OF 05 ANTIDOTE: NA 5. FIRE FIGHTING MEASURES FLASH POINT NA AUTOIGNITION TEMPERATURE NA HAZARDOUS PRODUCTS OF COMBUSTION : NA EXTINGUISHING MEDIA : DO NOT attempt to fight fire in the vicinity of other fireworks. UNUSUAL FIRE AND EXPLOSION HAZARDS : If exposed to fire, articles will explode and propel burning projectiles. There is a risk of explosion if large quantities of fireworks are involved in a fire. FIRE FIGHTING EQUIPMENT: In the case of a small amount on fire apply as much water as possible from as much distance as practical. Larger fires involving more than one carton require large volumes of water and extra care from fumes and debris. Evacuate fire area IMMEDIATELY and seek shelter. Follow emergency evacuation plan. 6. ACCIDENTAL RELEASE MEASURE NA 7. HANDLING AND STORAGE No Smoking, Keep away from fire! Handle with care. Do not drop or throw. Place upright. If exposed to fire, articles will explode. 8.EXPOSURE CONTROLS/PERSONAL PROTECTION EYE PROTECTION NA SKIN PROTECTION : NA RESPIRATORY PROTECTION None required when handling finished fireworks VENTILATION : NA JIANGXI PROVINCE LIDU FIREWORKS CORPORATION LTD. MATERIAL SAFETY DATA SHEET : FIREWORKS PAGE: 03 OF 05 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance All chemical composition is contained in a cardboard casing Odour All chemical composition is contained in a cardboard casing Density NA Vapour Pressure NA Vapour Density (Air--1) : NA Melting Point ; NA Solubility in Water Slight 10. STABILITY AND REACTIVITY STABILITY : Stable MATERIALS TO AVOID : Do not store with any other Dangerous Goods except articles (not substances) of class 1, Compatibility Groups C,D,E,G and S. DO NOT allow fireworks to get soaking wet. HAZARDOUS DECOMPOSITION PRODUCTS : When ignited the following major decomposition products may form: carbon dioxide, carbon monoxide, oxides of nitrogen, oxides of sulfur, heavy metal compounds and other toxic substances. Avoid breathing smoke from fireworks. HAZARDOUS POLYMERIZATION Will not Occur 11. TOXICOLOGICAL INFORMATION 11.1. Acute oral toxicity NA 11.2. Acute dermal toxicity NA 11.3. Chronic Toxicity NA JIANGXI PROVINCE LIDU FIREWORKS CORPORATION LTD. MATERIAL SAFETY DATA SHEET :FIREWORKS PAGE: 04 OF 05 11.4 Inhalation toxicity NA 11.5 Eye irritation NA 11.6 Toxicity to birds NA 11.7 Fish toxicity NA 11.8 Toxicity to bees NA 12. ECOLOGICAL INFORMATION ENVIRONMENTAL HAZARDS: NA 13. DISPOSAL CONSIDERTIONS Cleanup and disposal in accordance to local environmental regulations Metal Drums: NA Plastic / HDPE Bads: NA 14. TRANSPORT INFORMATION DOT (Department Of Transportation) DOT Proper Shipping Name Fireworks DOT Hazard Class / I.D. No. : 1.3G DOT Label Class 1 HAZCHEM NO, UN NO. 0335 TREM CARD. NA JIANGXI PROVINCE LIDU FIREWORKS CORPORATION LTD. MATERIAL SAFETY DATA SHEET : FIREWORKS PAGE: 05 OF 05 15. REGULATORY INFORMATION INGREDIENT: Complies with EN Standard and BS7114. PRODUCT CLASSIFICATION: Acute = No Chronic =No Fire = No Reactivity = No Pressure Generating =No NFPA CODES : HEALTH : NA FLAMMABILITY : NA REACTIVITY : NA 16. OTHER INFORMATION MANUFACTURER / SUPPLIERS DATA: - NAME OF FIRM JIANGXI PROVINCE LIDU FIREWORKS CORPORATION LTD. . MAILING ADDRESS : Rm. 1118, Bldg. A, International Finance Center, Honggutan District, Nanchang, Jiangxi, China 330008 TELEPHONE 0791-83961780 FAX NO. 0791-8851 8088 E-mail :. Iidugz@126.com CONTACT PERSON IN EMERGENCY Ada Jin LOCAL BODIES INVOLVED STANDARD PACKING DISCLAIMER: Information contained in this M.S.D.S. is believed to be reliable but no representation, guarantee or warranties of any kind are made as to its accuracy, suitability for a particular application or results to be obtained for them. It is up to the user to ensure that the information contained in the Material Safety Data Sheet is relevant to the product manufactured/handled or used by him as the case may be