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HomeMy WebLinkAboutSafety Data Sheet Black Lap Sealant Safety Data Sheet Material Name: G300LS Black Lap Sealant Product #: 302174 ____________________________________________________________ Page 1 of 15 Issue date: 2018-06-01 Revision 2.0 Section 1 - PRODUCT AND COMPANY IDENTIFICATION Material Name: G300LS Black Lap Sealant Synonym: Industrial Sealant Chemical Family: Solvent Based Sealant Product Use: Sealant for EPDM Single-Ply Roofing Membranes Restrictions on Use: For industrial use only. Manufacturer Information Versico LLC 1285 Ritner Highway Carlisle, PA 17013 USA Phone: +1-800-992-7663 Emergency Phone #: +1-800-424-9300 (CHEMTREC) Section 2 - HAZARDS IDENTIFICATION Classification in accordance with paragraph (d) of 29 CFR 1910.1200. Flammable Liquids - Category 2 Skin Corrosion/Irritation - Category 2 Serious Eye Damage/Eye Irritation - Category 2A Specific Target Organ Toxicity - Single Exposure - Category 3 Specific Target Organ Toxicity - Repeated Exposure - Category 1 ( lungs,central nervous system ) GHS Label Elements Symbol(s) Signal Word Danger Hazard Statement(s) Highly flammable liquid and vapor Causes skin irritation Causes serious eye irritation May cause respiratory irritation. May cause drowsiness or dizziness Causes damage to organs through prolonged or repeated exposure Safety Data Sheet Material Name: G300LS Black Lap Sealant Product #: 302174 ____________________________________________________________ Page 2 of 15 Issue date: 2018-06-01 Revision 2.0 Precautionary Statement(s) Prevention Keep container tightly closed Keep away from heat/sparks/open flame/hot surfaces - No smoking Ground/Bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting equipment Take precautionary measures against static discharge Use only non-sparking tools Use only outdoors or in a well-ventilated area Wear protective gloves/protective clothing/eye protection/face protection Do not breathe dust/fume/gas/mist/vapours/spray Wash thoroughly after handling Do not eat, drink or smoke when using this product Response In case of fire: Use appropriate media to extinguish IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse Call a POISON CENTER or doctor if you feel unwell Specific treatment (see label) Storage Store in a well-ventilated place. Keep cool Keep container tightly closed Store locked up Disposal Dispose of contents/container in accordance with local/regional/national/international regulations Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS CAS Component Name Percent Not applicable Ground coal 1-5 Trade Secret Silica compound 1-5 Trade Secret Severely hydrotreated paraffinic oil 3-7 1317-65-3 Limestone 10-30 Safety Data Sheet Material Name: G300LS Black Lap Sealant Product #: 302174 ____________________________________________________________ Page 3 of 15 Issue date: 2018-06-01 Revision 2.0 Trade Secret Carbon compound 1-5 Trade Secret Polyphenol antioxidant 0.1-1 64742-89-8 Naphtha, petroleum, light aliphatic 10-30 Trade Secrret Polybutene 1-5 Mixture Terpene phenolic resin 1-5 12001-26-2 Mica 0.1-1 64742-88-7 Solvent naphtha, petroleum, medium aliphatic 10-30 Section 4 - FIRST AID MEASURES Description of Necessary Measures IF exposed or concerned: Get medical advice/attention. Inhalation Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. Skin Remove/Take off immediately all contaminated clothing and wash it before reuse. Rinse skin with water/shower. If skin irritation occurs, get medical advice/attention. Eyes Flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention. Ingestion If swallowed, get medical attention. Do NOT induce vomiting. Indication of any immediate medical attention and special treatment needed Treat symptomatically and supportively. Most Important Symptoms/Effects Acute Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. May cause gastrointestinal irritation. Delayed Causes damage to organs through prolonged or repeated exposure: lungs, central nervous system. Safety Data Sheet Material Name: G300LS Black Lap Sealant Product #: 302174 ____________________________________________________________ Page 4 of 15 Issue date: 2018-06-01 Revision 2.0 Section 5 - FIRE FIGHTING MEASURES Extinguishing Media Suitable Extinguishing Media Dry chemical, foam or carbon dioxide. Water may be ineffective. Use water spray to keep containers cool. Unsuitable Extinguishing Media Do not use high-pressure water streams. Special Hazards Arising from the Chemical Can burn and explode easily when exposed to open flames or high heat. Hazardous Combustion Products Oxides of carbon, oxides of nitrogen Fire Fighting Measures Wear full protective fire fighting gear including self contained breathing apparatus (SCBA) for protection against possible exposure. Section 6 - ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures Wear personal protective clothing and equipment, see Section 8. Methods and Materials for Containment and Cleaning Up Remove all sources of ignition. Avoid breathing vapors. Ventilate affected area. Absorb with earth, sand or other non-combustible material and transfer to container. Use non-sparking tools. Dike for later disposal. Environmental Precautions Avoid release to the environment. Section 7 - HANDLING AND STORAGE Precautions for Safe Handling Keep away from heat/sparks/open flame/hot surfaces - No smoking. Do not eat or drink when using this product. Take precautionary measures against static discharge. Ground/bond container and receiving equipment. Use non-sparking tools. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Do not breathe dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Wash contaminated clothing before reuse. KEEP OUT OF REACH OF CHILDREN. Conditions for Safe Storage, Including any Incompatibilities Safety Data Sheet Material Name: G300LS Black Lap Sealant Product #: 302174 ____________________________________________________________ Page 5 of 15 Issue date: 2018-06-01 Revision 2.0 Store in a well-ventilated place. Keep cool Keep container tightly closed Store locked up Keep away from heat and ignition sources. Keep away from incompatible materials. Do not cut, puncture, or weld on or near this container. Incompatible Materials Strong oxidizing agents, acids, bases Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION Component Exposure Limits Silica compound Trade Secret OSHA (US): 20 mppcf TWA; ((80)/(% SiO2) mg/m3 TWA) Mexico: 10 mg/m3 TWA LMPE-PPT Limestone 1317-65-3 NIOSH: 10 mg/m3 TWA total dust; 5 mg/m3 TWA respirable dust OSHA (US): 15 mg/m3 TWA total dust; 5 mg/m3 TWA respirable fraction Mexico: 10 mg/m3 TWA LMPE-PPT 20 mg/m3 STEL [LMPE-CT] Carbon compound Trade Secret ACGIH: 3 mg/m3 TWA inhalable fraction NIOSH: 3.5 mg/m3 TWA; 0.1 mg/m3 TWA (Carbon black in presence of Polycyclic aromatic hydrocarbons) as PAH 1750 mg/m3 IDLH OSHA (US): 3.5 mg/m3 TWA Mexico: 3.5 mg/m3 TWA LMPE-PPT 7 mg/m3 STEL [LMPE-CT] Mica 12001-26-2 ACGIH: 3 mg/m3 TWA respirable fraction Safety Data Sheet Material Name: G300LS Black Lap Sealant Product #: 302174 ____________________________________________________________ Page 6 of 15 Issue date: 2018-06-01 Revision 2.0 NIOSH: 3 mg/m3 TWA (containing <1% Quartz) respirable dust 1500 mg/m3 IDLH (containing <1% Quartz) OSHA (US): 20 mppcf TWA (<1% Crystalline silica) Mexico: 3 mg/m3 TWA LMPE-PPT respirable fraction Silica, crystalline 14808-60-7 ACGIH: 0.025 mg/m3 TWA respirable fraction NIOSH: 0.05 mg/m3 TWA respirable dust 50 mg/m3 IDLH respirable dust OSHA (US): ((30)/(%SiO2 + 2) mg/m3 TWA) total dust; ((250)/(%SiO2 + 5) mppcf TWA) respirable fraction; ((10)/(%SiO2 + 2) mg/m3 TWA) respirable fraction Mexico: 0.1 mg/m3 TWA LMPE-PPT respirable fraction Biological limit value There are no biological limit values for any of this product's components. Engineering Controls Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. Individual Protection Measures, such as Personal Protective Equipment Eye/face protection Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Skin Protection Wear appropriate work clothing. Wear protective shoes. Recommended material: protective skin cream. Respiratory Protection A NIOSH approved air-purifying respirator with an appropriate cartridge or canister may be appropriate under certain circumstances where airborne concentrations are expected to exceed exposure limits. Glove Recommendations Wear appropriate chemical resistant gloves. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance viscous paste Physical State liquid Odor hydrocarbon Color black Odor Threshold Not available pH Not available Safety Data Sheet Material Name: G300LS Black Lap Sealant Product #: 302174 ____________________________________________________________ Page 7 of 15 Issue date: 2018-06-01 Revision 2.0 Melting Point <18 °C (< 0 °F) Boiling Point 119 - 185 °C (246-365 °F) Freezing point <18 °C Evaporation Rate 3.5 Boiling Point Range Not available Flammability (solid, gas) Not available Autoignition 230 °C (446 °F) Flash Point 4.4 °C [TCC] (40 °F) Lower Explosive Limit 0.8 % Decomposition Not available Upper Explosive Limit 6.7 % Vapor Pressure 8.27 mmHg Vapor Density (air=1) 4 Specific Gravity (water=1) 1.03 - 1.04 Water Solubility negligible Partition coefficient: n- octanol/water Not available Viscosity 1100000 cps Solubility (Other) hydrocarbons Density Not available VOC 390 - 400 g/L Other Information No additional information available. Section 10 - STABILITY AND REACTIVITY Reactivity No reactivity hazard is expected. Chemical Stability Stable under normal conditions of use. Possibility of Hazardous Reactions Hazardous polymerization will not occur. Conditions to Avoid Avoid heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials. Incompatible Materials Strong oxidizing agents, acids, bases Hazardous decomposition products Oxides of carbon, oxides of nitrogen Safety Data Sheet Material Name: G300LS Black Lap Sealant Product #: 302174 ____________________________________________________________ Page 8 of 15 Issue date: 2018-06-01 Revision 2.0 Section 11 - TOXICOLOGICAL INFORMATION Information on Likely Routes of Exposure Inhalation May cause respiratory irritation. Skin Contact Causes skin irritation. Eye Contact Causes serious eye irritation. Ingestion May cause gastrointestinal irritation. Acute and Chronic Toxicity Component Analysis - LD50/LC50 The components of this material have been reviewed in various sources and the following selected endpoints are published: Severely hydrotreated paraffinic oil (Trade Secret) Oral LD50 Rat >5000 mg/kg Dermal LD50 Rabbit >2000 mg/kg Carbon compound (Trade Secret) Oral LD50 Rat >15400 mg/kg Polyphenol antioxidant (Trade Secret) Oral LD50 Rat >200 mg/kg Dermal LD50 Rabbit >5010 mg/kg Naphtha, petroleum, light aliphatic (64742-89-8) Oral LD50 Mouse 5000 mg/kg Dermal LD50 Rabbit 3000 mg/kg Solvent naphtha, petroleum, medium aliphatic (64742-88-7) Oral LD50 Rat >5000 mg/kg Dermal LD50 Rabbit 3000 mg/kg Silica, crystalline (14808-60-7) Oral LD50 Rat 500 mg/kg Immediate Effects Cause skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. May cause gastrointestinal irritation. Delayed Effects Causes damage to organs through prolonged or repeated exposure: lungs, central nervous system. Irritation/Corrosivity Data Safety Data Sheet Material Name: G300LS Black Lap Sealant Product #: 302174 ____________________________________________________________ Page 9 of 15 Issue date: 2018-06-01 Revision 2.0 Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Respiratory Sensitization No data available. Dermal Sensitization It may cause sensitization in some individuals. Component Carcinogenicity Silica compound Trade Secret IARC: Monograph 68 [1997] (Group 3 (not classifiable)) Carbon compound Trade Secret ACGIH: A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans IARC: Monograph 93 [2010]; Monograph 65 [1996] (Group 2B (possibly carcinogenic to humans)) DFG: Category 3B (could be carcinogenic for man, inhalable fraction) OSHA: Present Silica, crystalline 14808-60-7 ACGIH: A2 - Suspected Human Carcinogen IARC: Monograph 100C [2012]; Monograph 68 [1997] (Group 1 (carcinogenic to humans)) NTP: Known Human Carcinogen (respirable size) DFG: Category 1 (causes cancer in man, alveola fraction) OSHA: Present (respirable size) Germ Cell Mutagenicity No data available. Reproductive Toxicity No data available. Specific Target Organ Toxicity - Single Exposure May affect the central nervous nervous system: drowsiness, dizziness. Specific Target Organ Toxicity - Repeated Exposure Safety Data Sheet Material Name: G300LS Black Lap Sealant Product #: 302174 ____________________________________________________________ Page 10 of 15 Issue date: 2018-06-01 Revision 2.0 May cause damage to organs through prolonged or repeated exposure: lungs, central nervous system. Aspiration hazard May cause aspiration hazard. Medical Conditions Aggravated by Exposure May cause allergic skin reaction. Aspiration into the lungs may cause chemical pneumonitis. Additional Data This product contains crystalline silica, which is a known carcinogen. However, this component is bound by the polymer portion of the sealant. The only way this component would be released is through incineration. Therefore, this product is not considered a carcinogen. Section 12 - ECOLOGICAL INFORMATION Ecotoxicity Avoid release to the environment. Component Analysis - Aquatic Toxicity Severely hydrotreated paraffinic oil Trade Secret Fish: LC50 96 h Oncorhynchus mykiss >5000 mg/L Invertebrate: EC50 48 h Daphnia magna >1000 mg/L IUCLID Polyphenol antioxidant Trade Secret Fish: LC50 96 h Oncorhynchus mykiss >0.2 mg/L [semi- static] Algae: EC50 72 h Pseudokirchneriella subcapitata >0.2 mg/L IUCLID Invertebrate: EC50 48 h Daphnia magna >0.2 mg/L IUCLID Naphtha, petroleum, light aliphatic 64742-89-8 Algae: EC50 72 h Pseudokirchneriella subcapitata 4700 mg/L IUCLID Solvent naphtha, petroleum, medium aliphatic 64742-88-7 Safety Data Sheet Material Name: G300LS Black Lap Sealant Product #: 302174 ____________________________________________________________ Page 11 of 15 Issue date: 2018-06-01 Revision 2.0 Fish: LC50 96 h Pimephales promelas 800 mg/L [static] Algae: EC50 96 h Pseudokirchneriella subcapitata 450 mg/L IUCLID Invertebrate: EC50 48 h Daphnia magna >100 mg/L IUCLID Persistence and Degradability No information available for the product. Bioaccumulative Potential No information available for the product. Mobility No information available for the product. Other Toxicity No additional information available. Section 13 - DISPOSAL CONSIDERATIONS Disposal Methods Dispose of contents/container in accordance with local/regional/national/international regulations. Section 14 - TRANSPORT INFORMATION US DOT Information: Shipping Name:ADHESIVES Hazard Class: 3 UN/NA #: UN1133 Packing Group: II Required Label(s): < 0.3 gal (limited quantity) IATA Information: Shipping Name:ADHESIVES Hazard Class: 3 UN#: UN1133 Packing Group: II Required Label(s): < 0.3 gal (limited quantity) TDG Information: Shipping Name:ADHESIVES Hazard Class: 3 UN#: UN1133 Safety Data Sheet Material Name: G300LS Black Lap Sealant Product #: 302174 ____________________________________________________________ Page 12 of 15 Issue date: 2018-06-01 Revision 2.0 Packing Group: II Required Label(s): Section 15 - REGULATORY INFORMATION U.S. Federal Regulations None of this products components are listed under SARA Sections 302/304 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan. SARA Section 311/312 (40 CFR 370 Subparts B and C) Acute Health: Yes Chronic Health: Yes Fire: Yes Pressure: No Reactivity: No U.S. State Regulations The following components appear on one or more of the following state hazardous substances lists: Component CAS CA MA MN NJ PA Silica compound Trade Secret No Yes Yes Yes Yes Limestone 1317-65-3 No Yes Yes Yes Yes Carbon compound Trade Secret Yes Yes Yes Yes Yes Mica 12001-26-2 Yes Yes Yes Yes Yes Solvent naphtha, petroleum, medium aliphatic 64742-88-7 No No No Yes No Silica, crystalline 14808-60-7 No Yes Yes Yes Yes The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): WARNING! This product contains a chemical known to the state of California to cause cancer Carbon compound Trade Secret Carc: carcinogen , initial date 2/21/03 (airborne, unbound particles of respirable size) Silica, crystalline 14808-60-7 Carc: carcinogen , initial date 10/1/88 (airborne particles of respirable size) Canadian WHMIS Ingredient Disclosure List (IDL) Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL Carbon compound Trade Secret Safety Data Sheet Material Name: G300LS Black Lap Sealant Product #: 302174 ____________________________________________________________ Page 13 of 15 Issue date: 2018-06-01 Revision 2.0 1 % Mica 12001-26-2 1 % Silica, crystalline 14808-60-7 1 % Component Analysis - Inventory Silica compound (Trade Secret) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX No DSL No Yes Yes Yes No Yes No Yes Yes Yes Severely hydrotreated paraffinic oil (Trade Secret) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes Yes No No Yes No Yes Yes No Limestone (1317-65-3) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes NSL EIN Yes Yes Yes No Yes No Yes Yes Yes Carbon compound (Trade Secret) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes Yes Yes No Yes No Yes Yes Yes Polyphenol antioxidant (Trade Secret) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes Yes Yes No Yes No Yes Yes No Naphtha, petroleum, light aliphatic (64742-89-8) Safety Data Sheet Material Name: G300LS Black Lap Sealant Product #: 302174 ____________________________________________________________ Page 14 of 15 Issue date: 2018-06-01 Revision 2.0 US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes Yes No No Yes No Yes Yes Yes Polybutene (Trade Secrret) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL No Yes Yes Yes No Yes No Yes Yes Yes Mica (12001-26-2) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX No DSL No Yes Yes No No Yes No Yes Yes Yes Solvent naphtha, petroleum, medium aliphatic (64742-88-7) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes Yes No No Yes No Yes Yes Yes Silica, crystalline (14808-60-7) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes Yes Yes No Yes No Yes Yes Yes Section 16 - OTHER INFORMATION HMIS Rating Health: 1 Fire: 3 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard Safety Data Sheet Material Name: G300LS Black Lap Sealant Product #: 302174 ____________________________________________________________ Page 15 of 15 Issue date: 2018-06-01 Revision 2.0 NFPA Ratings Health: 1 Fire: 3 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe Summary of Changes Revision Date: June 1, 2018 Revision Note: General Update Key / Legend ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CLP - Classification, Labelling, and Packaging; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSD - Dangerous Substance Directive; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LLV - Level Limit Value; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; REACH- Registration, Evaluation, Authorisation, and restriction of Chemicals; RID - European Rail Transport; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States. Other Information Disclaimer: The information contained herein is based upon data and information available to us, and reflects our best professional judgment. This product may be formulated in part with components purchased from other companies. No warranty of merchantability, fitness for any use, or any other warranty is expressed or implied regarding the accuracy of such data or information. The results to be obtained from the use thereof, or that any such use does not infringe any patent, since the information contained herein may be applied under conditions of use beyond our control and with which we may be unfamiliar, we do not assume responsibility for the results of such application. This information is furnished upon the condition that the person receiving it shall make his own determination of the suitability of the material for his particular use.