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Home My WebLink AboutSafety Data Sheet Low VOC EPDM.TPO Primer Safety Data Sheet Material Name: Low VOC EPDM/TPO Primer Product #: 329161 ____________________________________________________________ Page 1 of 16 Issue date: 2017-08-18 Revision New Print date: 2017-08-21 Section 1 - PRODUCT AND COMPANY IDENTIFICATION Material Name Low VOC EPDM/TPO Primer Synonyms Primer Chemical Family Primer, mixture Product Use Solvent primer Restrictions on Use For industrial use only. Manufacturer Information Versico Roofing System 1285 Ritner Highway Carlisle, PA 17013 USA Phone: +1-800-992-7663 Emergency Phone #: +1-800-424-9300 (CHEMTREC) Section 2 - HAZARDS IDENTIFICATION Classification in accordance with paragraph (d) of 29 CFR 1910.1200. Flammable Liquids - Category 3 Skin Corrosion/Irritation - Category 2 Serious Eye Damage/Eye Irritation - Category 2A Skin Sensitization - Category 1A Carcinogenicity - Category 2 Specific Target Organ Toxicity - Single Exposure - Category 3 Specific Target Organ Toxicity - Repeated Exposure - Category 2 ( liver,kidneys ) GHS Label Elements Symbol(s) Safety Data Sheet Material Name: Low VOC EPDM/TPO Primer Product #: 329161 ____________________________________________________________ Page 2 of 16 Issue date: 2017-08-18 Revision New Print date: 2017-08-21 Signal Word Warning Hazard Statement(s) Flammable liquid and vapor Causes skin irritation Causes serious eye irritation May cause allergic skin reaction Suspected of causing cancer May cause drowsiness or dizziness May cause damage to organs through prolonged or repeated exposure Precautionary Statement(s) Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Keep container tightly closed Keep away from heat/sparks/open flame/hot surfaces - No smoking Ground/Bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting equipment Take precautionary measures against static discharge Use only non-sparking tools Use only outdoors or in a well-ventilated area Wear protective gloves/protective clothing/eye protection/face protection Do not breathe dust/fume/gas/mist/vapours/spray Wash thoroughly after handling Contaminated work clothing must not be allowed out of the workplace Response In case of fire: Use appropriate media to extinguish IF exposed or concerned: Get medical advice/attention IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor if you feel unwell IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower If skin irritation or rash occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse Specific treatment (see label) Storage Keep container tightly closed Store in a well-ventilated place. Keep cool Store locked up Safety Data Sheet Material Name: Low VOC EPDM/TPO Primer Product #: 329161 ____________________________________________________________ Page 3 of 16 Issue date: 2017-08-18 Revision New Print date: 2017-08-21 Disposal Dispose of contents/container in accordance with local/regional/national/international regulations Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS CAS Component Name Percent 64742-89-8 Solvent naphtha, petroleum, light aliphatic 10-30 Trade Secret Isophorone Diisocyanate 0.5-1.5 108-88-3 Toluene 3-7 Trade Secret Chlorinated polypropylene 0.1-1 98-56-6 PCBTF 60-100 67-63-0 Anhydrous Isopropanol 0.1-1 Section 4 - FIRST AID MEASURES Description of Necessary Measures IF exposed or concerned: Get medical advice/attention. Inhalation Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. Skin Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Eyes Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Ingestion If swallowed, get medical attention. Safety Data Sheet Material Name: Low VOC EPDM/TPO Primer Product #: 329161 ____________________________________________________________ Page 4 of 16 Issue date: 2017-08-18 Revision New Print date: 2017-08-21 Indication of any immediate medical attention and special treatment needed Treat symptomatically and supportively. Most Important Symptoms/Effects Acute Causes skin irritation. Causes serious eye irritation. May cause allergic skin reaction. May cause drowsiness or dizziness. Delayed May cause allergic skin reaction. Suspected of causing cancer. May cause liver and kidney damage. Note to Physicians Contains: toluene, isopropanol. Section 5 - FIRE FIGHTING MEASURES Extinguishing Media Suitable Extinguishing Media Dry chemical, foam or carbon dioxide. Water may be ineffective. Unsuitable Extinguishing Media Do not use high-pressure water streams. Special Hazards Arising from the Chemical Flammable liquid and vapor. Hazardous Combustion Products Oxides of carbon, oxides of nitrogen Advice for firefighters Wear full protective fire fighting gear including self contained breathing apparatus (SCBA) for protection against possible exposure. Fire Fighting Measures Move container from fire area if it can be done without risk. Section 6 - ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures Wear personal protective clothing and equipment, see Section 8. Methods and Materials for Containment and Cleaning Up Remove all sources of ignition. Avoid breathing vapors. Ventilate the area. Use non-sparking tools. Use clean non-sparking tools to collect absorbed material and place it into loosely-covered metal or plastic containers for later disposal. Large spills: Dike for later disposal. Prevent entry into waterways, sewers, basements, or confined areas. Safety Data Sheet Material Name: Low VOC EPDM/TPO Primer Product #: 329161 ____________________________________________________________ Page 5 of 16 Issue date: 2017-08-18 Revision New Print date: 2017-08-21 Environmental Precautions Avoid release to the environment. Collect spillage. Section 7 - HANDLING AND STORAGE Precautions for Safe Handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat and ignition sources. When using do not smoke. Use non-sparking tools. Ground any equipment used in handling. Wash with plenty of soap and water. Wash contaminated clothing before reuse. KEEP OUT OF REACH OF CHILDREN. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Take precautionary measures against static discharge. Do not breathe gas, fumes, vapor, or spray. Contaminated work clothing should not be allowed out of the workplace. Conditions for Safe Storage, Including any Incompatibilities Keep container tightly closed Store in a well-ventilated place. Keep cool Store locked up Keep away from heat, sparks and flame. Do not cut, puncture, or weld on or near this container. Empty containers may contain product residue. Keep away from incompatible materials. Incompatible Materials Strong oxidizing agents, acids, bases Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION Component Exposure Limits Toluene 108-88-3 ACGIH: 20 ppm TWA NIOSH: 100 ppm TWA; 375 mg/m3 TWA 150 ppm STEL; 560 mg/m3 STEL 500 ppm IDLH Europe: 50 ppm TWA; 192 mg/m3 TWA 100 ppm STEL; 384 mg/m3 STEL Possibility of significant uptake through the skin OSHA (US): 200 ppm TWA 300 ppm Ceiling Mexico: 50 ppm TWA LMPE-PPT; 188 mg/m3 TWA LMPE-PPT Safety Data Sheet Material Name: Low VOC EPDM/TPO Primer Product #: 329161 ____________________________________________________________ Page 6 of 16 Issue date: 2017-08-18 Revision New Print date: 2017-08-21 Skin - potential for cutaneous absorption Safety Data Sheet Material Name: Low VOC EPDM/TPO Primer Product #: 329161 ____________________________________________________________ Page 7 of 16 Issue date: 2017-08-18 Revision New Print date: 2017-08-21 Anhydrous isopropanol 67-63-0 ACGIH: 200 ppm TWA NIOSH: 400 ppm TWA; 980 mg/m3 TWA 400 ppm STEL 2000 ppm IDLH (10% LEL) 500 ppm STEL; 1225 mg/m3 STEL OSHA (US): 400 ppm TWA; 980 mg/m3 TWA Mexico: 400 ppm TWA LMPE-PPT; 980 mg/m3 TWA LMPE-PPT 500 ppm STEL [LMPE-CT]; 1225 mg/m3 STEL [LMPE-CT] PCBTF 98-56-6 ACGIH: 2.5 mg/m3 TWA as F (related to Fluorides) OSHA (US): 2.5 mg/m3 TWA as F; 2.5 mg/m3 TWA dust (related to Fluorides) Mexico: 2.5 mg/m3 TWA LMPE-PPT as F (related to Fluorides) Biological limit value There are no biological limit values for any of this product's components. Engineering Controls Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. Individual Protection Measures, such as Personal Protective Equipment Eye/face protection Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Skin Protection Wear appropriate chemical resistant clothing. Wear protective shoes. Respiratory Protection A NIOSH approved air-purifying respirator with an appropriate cartridge or canister may be appropriate under certain circumstances where airborne concentrations are expected to exceed exposure limits. Glove Recommendations Wear appropriate chemical resistant gloves. Safety Data Sheet Material Name: Low VOC EPDM/TPO Primer Product #: 329161 ____________________________________________________________ Page 8 of 16 Issue date: 2017-08-18 Revision New Print date: 2017-08-21 Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance thin green liquid Physical State liquid Odor Naphthenic distillate Color green Odor Threshold Not available pH Not available Melting Point -95 - -33 °C(-139 - 27°F) Boiling Point 111 - 139 °C(232 -282°F) Freezing point Not available Evaporation Rate 1.4 Boiling Point Range Not available Flammability (solid, gas) Not available Autoignition 246 °C(475°F) Flash Point 4 °C(40°F) Lower Explosive Limit 0.9 Decomposition Not available Upper Explosive Limit 10.5 Vapor Pressure 7.4 mmHg Vapor Density (air=1) 5.7 Specific Gravity (water=1) Not available Water Solubility insoluble Partition coefficient: n- octanol/water Not available Viscosity <200 cps Solubility (Other) Not available Density 1.177 VOC <250 g/L Section 10 - STABILITY AND REACTIVITY Reactivity No reactivity hazard is expected. Chemical Stability Stable under normal conditions of use. Possibility of Hazardous Reactions Safety Data Sheet Material Name: Low VOC EPDM/TPO Primer Product #: 329161 ____________________________________________________________ Page 9 of 16 Issue date: 2017-08-18 Revision New Print date: 2017-08-21 Will not polymerize. Conditions to Avoid Keep away from heat/sparks/open flame/hot surfaces - No smoking. Take action to prevent static discharges. Avoid contact with incompatible materials. Incompatible Materials Strong oxidizing agents, acids, bases Hazardous decomposition products Oxides of carbon, oxides of nitrogen Section 11 - TOXICOLOGICAL INFORMATION Information on Likely Routes of Exposure Inhalation May cause drowsiness or dizziness. Skin Contact Causes skin irritation. Eye Contact Causes serious eye irritation. Ingestion No information on significant adverse effects. Acute and Chronic Toxicity Component Analysis - LD50/LC50 The components of this material have been reviewed in various sources and the following selected endpoints are published: Solvent naphtha, petroleum, light aliphatic (64742-89-8) Oral LD50 Rat >2000 mg/kg Dermal LD50 Rat >2000 mg/kg Inhalation Rat >5000 ppm 1 hour Isophorone Diisocyanate (Trade Secret) Oral LD50 Rat >20000 mg/kg Dermal LD50 Rabbit 4000 mg/kg Inhalation LC50 Rat 5 mg/l 4 h Toluene (108-88-3) Oral LD50 >7000 mg/kg Dermal LD50 12 - 14 g/kg Inhalation LC50 30 mg/L chlorinated homopolymer (Trade Secret) Oral Rat 5000 mg/kg Safety Data Sheet Material Name: Low VOC EPDM/TPO Primer Product #: 329161 ____________________________________________________________ Page 10 of 16 Issue date: 2017-08-18 Revision New Print date: 2017-08-21 PCBTF (98-56-6) Oral LD50 Rat 13 g/kg Dermal LD50 Rabbit >2 mL/kg Inhalation LC50 Rat 33 mg/L 4 h Anhydrous isopropanol (67-63-0) Oral LD50 Rat 1870 mg/kg Dermal LD50 Rabbit 4059 mg/kg Inhalation LC50 Rat 72600 mg/m3 4 h Immediate Effects Causes skin irritation. Causes serious eye irritation. May cause allergic skin reaction. May cause drowsiness or dizziness. Delayed Effects May cause allergic skin reaction. Suspected of causing cancer. May cause liver and kidney damage. Irritation/Corrosivity Data Causes skin and eye irritation. Respiratory Sensitization No information available for the product. Dermal Sensitization May cause allergic skin reaction. Component Carcinogenicity Toluene 108-88-3 ACGIH: A4 - Not Classifiable as a Human Carcinogen IARC: Monograph 71 [1999]; Monograph 47 [1989] (Group 3 (not classifiable)) PCBTF 98-56-6 ACGIH: A4 - Not Classifiable as a Human Carcinogen (related to Fluorides) Anhydrous isopropanol 67-63-0 ACGIH: A4 - Not Classifiable as a Human Carcinogen Safety Data Sheet Material Name: Low VOC EPDM/TPO Primer Product #: 329161 ____________________________________________________________ Page 11 of 16 Issue date: 2017-08-18 Revision New Print date: 2017-08-21 IARC: Monograph 71 [1999]; Supplement 7 [1987]; Monograph 15 [1977] (Group 3 (not classifiable)) Germ Cell Mutagenicity No information available for the product. Tumorigenic Data No data available Reproductive Toxicity No information available for the product. Specific Target Organ Toxicity - Single Exposure central nervous system Specific Target Organ Toxicity - Repeated Exposure Prolonged exposure may cause liver and kidney damage. Aspiration hazard No information available for the product. Medical Conditions Aggravated by Exposure May cause allergic skin reaction. Section 12 - ECOLOGICAL INFORMATION Component Analysis - Aquatic Toxicity Solvent naphtha, petroleum, light aliphatic 64742-89-8 Algae: EC50 72 h Pseudokirchneriella subcapitata 4700 mg/L IUCLID Isophorone Diisocyanate Trade Secret Fish: LC50 96 h Oncorhynchus mykiss 9.22 mg/L Invertebrate: EC50 48 h Daphnia magna 6.14 mg/L IUCLID Toluene 108-88-3 Fish: LC50 96 h Pimephales promelas 15.22 - 19.05 mg/L [flow-through] (1 day old); LC50 96 h Pimephales promelas 12.6 mg/L [static]; LC50 96 h Oncorhynchus mykiss 5.89 - 7.81 mg/L [flow-through]; Safety Data Sheet Material Name: Low VOC EPDM/TPO Primer Product #: 329161 ____________________________________________________________ Page 12 of 16 Issue date: 2017-08-18 Revision New Print date: 2017-08-21 LC50 96 h Oncorhynchus mykiss 14.1 - 17.16 mg/L [static]; LC50 96 h Oncorhynchus mykiss 5.8 mg/L [semi-static]; LC50 96 h Lepomis macrochirus 11 - 15 mg/L [static]; LC50 96 h Oryzias latipes 54 mg/L [static]; LC50 96 h Poecilia reticulata 28.2 mg/L [semi-static]; LC50 96 h Poecilia reticulata 50.87 - 70.34 mg/L [static] Algae: EC50 96 h Pseudokirchneriella subcapitata >433 mg/L IUCLID; EC50 72 h Pseudokirchneriella subcapitata 12.5 mg/L [static] EPA Invertebrate: EC50 48 h Daphnia magna 5.46 - 9.83 mg/L [static] EPA; EC50 48 h Daphnia magna 11.5 mg/L IUCLID PCBTF 98-56-6 Invertebrate: EC50 48 h Daphnia magna 3.68 mg/L IUCLID Anhydrous isopropanol 67-63-0 Fish: LC50 96 h Pimephales promelas 9640 mg/L [flow-through]; LC50 96 h Pimephales promelas 11130 mg/L [static]; LC50 96 h Lepomis macrochirus >1400000 µg/L Algae: EC50 96 h Desmodesmus subspicatus >1000 mg/L IUCLID; EC50 72 h Desmodesmus subspicatus >1000 mg/L IUCLID Invertebrate: EC50 48 h Daphnia magna 13299 mg/L IUCLID Section 13 - DISPOSAL CONSIDERATIONS Disposal Methods Dispose of contents/container in accordance with local/regional/national/international regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. Section 14 - TRANSPORT INFORMATION US DOT Information: Shipping Name:ADHESIVES Safety Data Sheet Material Name: Low VOC EPDM/TPO Primer Product #: 329161 ____________________________________________________________ Page 13 of 16 Issue date: 2017-08-18 Revision New Print date: 2017-08-21 Hazard Class: 3 UN/NA #: UN1133 Packing Group: II Required Label(s): 3 IATA Information: Shipping Name:ADHESIVES Hazard Class: 3 UN#: UN1133 Packing Group: II Required Label(s): 3 TDG Information: Shipping Name:ADHESIVES Hazard Class: 3 UN#: UN1133 Packing Group: II Section 15 - REGULATORY INFORMATION U.S. Federal Regulations This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), and/or require an OSHA process safety plan. Toluene 108-88-3 SARA 313: 1 % de minimis concentration CERCLA: 1000 lb final RQ; 454 kg final RQ TSCA 12b: Section 4 , 1 % de minimus concentration (related to Hydrocarbons, C>4) PCBTF 98-56-6 TSCA 12b: Section 4 , 1 % de minimus concentration Anhydrous isopropanol 67-63-0 Safety Data Sheet Material Name: Low VOC EPDM/TPO Primer Product #: 329161 ____________________________________________________________ Page 14 of 16 Issue date: 2017-08-18 Revision New Print date: 2017-08-21 SARA 313: 1 % de minimis concentration (only if manufactured by the strong acid process, no supplier notification) SARA Section 311/312 (40 CFR 370 Subparts B and C) Acute Health: Yes Chronic Health: Yes Fire: Yes Pressure: No Reactivity: No U.S. State Regulations The following components appear on one or more of the following state hazardous substances lists: Component CAS CA MA MN NJ PA Toluene 108-88-3 Yes Yes Yes Yes Yes PCBTF 98-56-6 Yes No Yes Yes Yes Anhydrous isopropanol 67-63-0 Yes Yes Yes Yes Yes The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): WARNING! This product contains a chemical known to the state of California to cause reproductive/developmental effects Toluene 108-88-3 Repro/Dev. Tox developmental toxicity , 1/1/1991 Canadian WHMIS Ingredient Disclosure List (IDL) Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL Toluene 108-88-3 1 % Anhydrous isopropanol 67-63-0 1 % Component Analysis - Inventory Solvent naphtha, petroleum, light aliphatic (64742-89-8) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes Yes No No Yes No Yes Yes Yes Isophorone Diisocyanate (Trade Secret) Safety Data Sheet Material Name: Low VOC EPDM/TPO Primer Product #: 329161 ____________________________________________________________ Page 15 of 16 Issue date: 2017-08-18 Revision New Print date: 2017-08-21 US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes Yes No No Yes No Yes Yes Yes Anhydrous isopropanol (67-63-0) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes Yes Yes Yes Yes No Yes Yes Yes Toluene (108-88-3) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes Yes Yes No Yes No Yes Yes Yes chlorinated homopolymer (Trade Secret) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL No Yes Yes Yes No Yes No Yes Yes No PCBTF (98-56-6) US CA EU AU PH JP - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX Yes DSL EIN Yes Yes Yes Yes Yes No Yes Yes No Section 16 - OTHER INFORMATION HMIS Rating Health: 2 Fire: 3 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard NFPA Ratings Health: 2 Fire: 3 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe Safety Data Sheet Material Name: Low VOC EPDM/TPO Primer Product #: 329161 ____________________________________________________________ Page 16 of 16 Issue date: 2017-08-18 Revision New Print date: 2017-08-21 Summary of Changes New SDS: 8/18/2017 Key / Legend ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CLP - Classification, Labelling, and Packaging; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSD - Dangerous Substance Directive; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LLV - Level Limit Value; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; REACH- Registration, Evaluation, Authorisation, and restriction of Chemicals; RID - European Rail Transport; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States. Other Information Disclaimer: The information contained herein is based upon data and information available to us, and reflects our best professional judgment. This product may be formulated in part with components purchased from other companies. No warranty of merchantability, fitness for any use, or any other warranty is expressed or implied regarding the accuracy of such data or information. The results to be obtained from the use thereof, or that any such use does not infringe any patent, since the information contained herein may be applied under conditions of use beyond our control and with which we may be unfamiliar, we do not assume responsibility for the results of such application. This information is furnished upon the condition that the person receiving it shall make his own determination of the suitability of the material for his particular use.